The atomic weight which we have hitherto found less important than the atomic number, is of course of the greatest significance when we are considering the structure of the nucleus. The weight of an electron is so small as to be negligible in comparison with that of the nucleus, even in the case of hydrogen, so that the weight of the atom is, to all intents and purposes, the weight of the nucleus. If we take the weight of the helium atom to be 4, the weight of the hydrogen atom is just over 1. The explanation of the fact that it is not exactly 1 is very interesting, and we shall return to it shortly. The weight of every other atom, in view of Aston’s work on isotopes, is apparently a whole number, as nearly as our measurements can determine. Roughly speaking, the atomic weight is about double the atomic number. This is true exactly in the following cases (making, in some cases, inferences allowed by Aston’s work):
| Helium | Carbon | Oxygen | Neon | Sulphur | Calcium | |
|---|---|---|---|---|---|---|
| Atomic number | 2 | 6 | 8 | 10 | 16 | 20 |
| Atomic weight | 4 | 12 | 16 | 20 | 32 | 40 |
After this, the atomic weight is always more than double the atomic number. It will be seen that the above elements all have even atomic numbers and have atomic weights which divide by 4. We may therefore regard their nuclei as composed wholly of helium nuclei.
In the case of elements which have odd atomic numbers, there is only one instance, nitrogen, in which the atomic weight (14) is just double the atomic number (7). In this case, we may suppose that the nucleus consists of three helium nuclei and two hydrogen nuclei. In other cases, in the early part of the periodic table, the atomic weight is greater by one than the double of the atomic number. Thus phosphorus has the atomic number 15, and the atomic weight 31. The same is true of the other early elements with odd atomic numbers, except nitrogen. (From the
element onward the atomic weight is larger than it would be by this rule.) The inference is that the nuclei of atoms which have odd atomic numbers usually consist of an adequate number of helium nuclei together with three hydrogen nuclei. The peculiarity of nitrogen is perhaps connected with the fact that Rutherford found it the easiest element from which to detach hydrogen nuclei.
The fact that the atomic weights are whole numbers, together with the facts of radio-activity and of Rutherford’s bombardment, lead irresistibly to the conclusion that the weight of an atom is due to helium nuclei and hydrogen nuclei which exist together in its nucleus. The overcrowding in the nucleus of a heavy atom must be something fearful. Radium C, which emits the
-particles that Rutherford used in his experiments, has a nucleus whose radius is about three million-millionths of a centimetre (about one million-millionth of an inch). Its atomic number is 83 and its atomic weight is 214. This means that in this tiny space it must contain 53 helium nuclei and 2 hydrogen nuclei; it must also (as we shall see in a moment) contain 131 electrons. It is no wonder that helium nuclei and electrons move fast when radio-activity liberates them from this slum.
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