Incidentally, Dalton mistakenly thought that one atom of oxygen was eight times as heavy as one atom of hydrogen instead of 16 times as heavy. He assumed a water molecule to be HO instead of H₂O.
Cathode Rays Show Atoms Contain Smaller Parts
Curiosity about the fundamental nature of matter was matched by equally avid curiosity about the fundamental nature of electricity. Before 1850 much had been learned about the behavior of electric charge and electric currents flowing through solids and liquids. Real progress in understanding electric charge, however, had to wait for the development of highly efficient vacuum pumps.
About 1854 Heinrich Geissler, a German glassblower, developed an improved suction pump, and also succeeded in sealing into a glass tube two wires attached to metal electrodes inside the tube. Experimenters were then able to study the flow of electricity through a near-vacuum. A Geissler tube is diagramed in [Figure 1].
By the 1890s it had become clear that the flow of electricity through a highly evacuated tube consisted of a negative electric charge moving at a very high speed along straight lines between sealed-in electrodes. Since it originated at the negative electrode, or cathode, the invisible stream of charge was named “cathode rays.”
Figure 1 Geissler Tube.
CURRENT SOURCE CATHODE (-) STREAM OF ELECTRONS VACUUM PUMP ANODE (+)
Although many investigators contributed to knowledge about cathode rays, the experiments of Joseph J. Thomson, a British physicist, are generally considered to have been the most enlightening. Thomson arranged a cathode-ray tube so that the rays could be deflected by magnets and by electrically charged metal plates. By applying certain well-known principles of physics, he was able to confirm an impression already held by physical chemists, namely, that electric charge, like matter, was “atomized”—the stream of charge consisted of a swarm of very small particles, all alike. He succeeded also in determining that the speed of the particles was about one-tenth the speed of light.
Probably Thomson’s most significant result was determining the ratio of the charge of each little particle to its weight. He was able to do this by measuring the magnetic force required to divert a stream of charged particles. (You can do this experiment yourself with relatively simple equipment.) This charge-to-weight ratio proved to be nearly 2000 times greater than the already known charge-to-weight ratio for a positively charged hydrogen atom, or ion, which until then was thought to be the lightest constituent of matter. It remained to be determined whether charge or weight caused the difference. Further experimentation showed that the charges were approximately the same amount in the two cases. It was therefore proven that the weight of the hydrogen atom, lightest of all the atoms, was nearly 2000 times as great as the weight of one of the little negative particles.