The name “electron” was given to the small negative particles identified by Thomson. Since the electrons had come from the cathode, it was apparent that the atoms in the cathode must contain electrons. Thomson reasoned that electric current in a wire is a stream of electrons passing successively from atom to atom and that the difference between an electrically charged atom and a neutral atom is that the charged one has gained or lost one or more electrons.

Radioactive Atoms Discovered

Henri Becquerel
Courtesy Journal of Chemical Education, Discovery of the Elements, Mary Elvira Weeks.

In 1896 the French physicist Henri Becquerel was investigating the relation between fluorescence and X rays, a puzzling kind of penetrating radiation discovered a few months earlier by the German, Wilhelm Roentgen. Various chemical compounds fluoresce, or glow, when exposed to ultraviolet rays and other types of radiation. While experimenting with a large number of chemicals, Becquerel discovered, quite by accident, that a compound containing the element uranium can, without being exposed to any kind of radiation, darken a photographic plate completely wrapped in heavy black paper.

Although no one realized it at the time, Becquerel had discovered that atoms of some elements will at random times transform themselves into atoms of a different element by emitting certain extremely high-speed charged particles. Atoms that can do this are said to be radioactive, and it was the radiation from transforming uranium atoms that darkened Becquerel’s photographic plate.

Rutherford Finds the Atomic Nucleus

Ernest Rutherford, 1871-1937
Courtesy Nobelstiftelsen

We are greatly indebted to the imagination and experimental skill of the British physicist Ernest Rutherford for the interpretation of radioactivity in terms of the structure of atoms.