Rutherford, born and educated in New Zealand, moved to England to work under Thomson at Cambridge University in 1895. Shortly afterward, Wilhelm Roentgen in Germany discovered X rays, Becquerel in France discovered radioactivity, and Thomson proved the existence of the electron.
During the next few years, curiosity about the fundamental nature of radioactivity led a number of people to do a great deal of work. The element thorium was found to be radioactive, and Marie and Pierre Curie discovered two new elements, polonium and radium, that were also radioactive. The radiation from radioactive materials was found to be of three kinds called alpha rays, beta rays, and gamma rays. Alpha rays were first detected by Rutherford, who later identified them as positively charged helium atoms. Becquerel demonstrated that beta rays, like cathode rays, consist of negatively charged electrons. The highly penetrating gamma rays were proved by Rutherford and E. N. da C. Andrade to be electromagnetic radiation similar to X rays.
Rutherford, in collaboration with the English chemist Frederick Soddy, brought order out of a chaos of puzzling discoveries by establishing the general behavior of radioactive atoms. He determined that certain naturally occurring atoms of high atomic weight can spontaneously emit an alpha or a beta particle and thereby convert themselves into new atoms. These new atoms, being also radioactive, sooner or later convert themselves into still different atoms, and so on. Each time an alpha particle is emitted in this sequence, the new atom is lighter by the weight of the alpha particle, or helium atom. The disintegration process proceeds from stage to stage until at last a stable atom is produced. The end product in this “decay” process in naturally occurring radioactive elements is lead.
One experiment by Rutherford and his co-workers had a most profound effect on the understanding of atomic structure. What they did was to direct a stream of alpha particles at a thin piece of gold foil. The results were astonishing. Almost all the particles passed straight through the foil without changing direction. Of the few particles that did ricochet in new directions, however, some were deflected at very sharp angles. (See [Figure 2].)
Figure 2 Rutherford’s most famous experiment, which led him to the concept of the nucleus.
As a result of this experiment, Rutherford proposed a concept of the atom entirely different from the one which prevailed at this time. The prevailing notion was one advanced by Thomson which conceived of an atom as a blob of positive electric charge in which were imbedded, in much the same way as plums are in a pudding, enough electrons to neutralize the positive charge. Rutherford’s concept, which quickly set aside Thomson’s “plum pudding” model, was that an atom has all of its positive charge and virtually all of its mass concentrated in a tiny space at its center. (Collisions with this center, which came to be known thereafter as the nucleus, had been responsible for the sharp changes in direction of some of the alpha particles.) The space surrounding this nucleus is entirely empty except for the presence of a number of electrons (79 in the case of the gold atom), each about the same size as the nucleus.
To illustrate Rutherford’s concept, let us imagine a gold atom magnified so that it is as large as a bale of cotton. The nucleus at the center of this large atom would be the size of a speck of black pepper. If this imaginary bale weighed 500 pounds, the little speck at its center would weigh 499¾ pounds; the surrounding cotton (corresponding to empty space in Rutherford’s concept) containing the 79 electrons would weigh but ¼ pound. To express this idea another way, any object such as a gold ring, as dense and solid as it may seem to us, consists almost entirely of nothing!
The Proton Is Recognized
Rutherford’s discovery aroused intense curiosity about the nature and possible structure of this extremely small, but all-important, part of an atom. It was assumed that the positive charge carried by the nucleus must be a whole-number multiple of a small unit equal in size but opposite in sign to the charge of an electron. This conclusion was based on the information that all atoms contain electrons and that an undisturbed atom is electrically neutral. Since it was known that a neutral atom of hydrogen contains just one electron, it appeared that the charge on a hydrogen nucleus must represent the fundamental unit of positive charge, some multiple of which would represent the charge on any other nucleus. Several lines of investigation combined to establish quite firmly that nuclei of atoms occupying adjacent positions on the periodic chart of the elements differed in charge by this fundamental unit. Since the hydrogen nucleus seemed to play such an important role in making up the charges of all other nuclei, it was given the name proton from the Greek “protos,” which means “first.”