11. Fat.—Fat is present in the milk in the form of suspended small transparent globules (as an emulsion). These globules vary in size with the breed and individuality of the cow and in color from a very light yellow to a deep yellow shade as sought in butter. Milk with small fat globules is preferred for cheese-making, because these are not so easily lost in the process. Milk-fat is made up of several different compounds called glycerids,[4] which are formed by the union of an organic acid with glycerine as a base.
Fat is important in cheese-making for two reasons: (1) Its influence on the yield of cheese; (2) its effect on the quality of the cheese. Many of the details of cheese-making processes have been developed to prevent the loss of fat in manufacture. The yield of cheese is almost directly in proportion to the amount of fat in the milk; nevertheless, because the solids not fat do not increase exactly in proportion to the fat, the cheese yield is not exactly in proportion to the fat. The fat, however, is a good index of the cheese-producing power of the milk.
12. Casein.—Cheese-making is possible because of the peculiar properties of casein. This is the fundamental substance of cheese-making because it has the capacity to coagulate or curdle under the action of acid and rennet enzymes. Casein is an extremely complex organic compound.[5] Authorities disagree regarding its exact composition, but it contains varying amounts of carbon, oxygen, nitrogen, hydrogen, phosphorus and sulfur, and it usually is combined with some form of lime or calcium phosphate. It belongs to the general class of nitrogen-containing compounds called proteins. It is present in milk in the form of extremely minute gelatinous particles in suspension. Casein is insoluble in water and dilute acids. The acids, when added, cause a heavy, white, more or less flocculent precipitate. Rennet (Chapter III) causes the casein to coagulate (curdle), forming a jelly-like mass called curd, which is the basis of manufacture in most types of cheese. In the formation of this coagulum (curd), the fat is imprisoned and held. The casein compounds in the curd hold the moisture and give firmness and solidity of body to the cheese. Casein contains the protein materials in which important ripening changes take place. These changes render the casein more soluble, and are thought to be the source of certain characteristic cheese flavors.
13. Milk-sugar.—Milk-sugar (lactose) is present in solution in the watery part of the milk. It forms on the average about 5 per cent of cow's milk. Since it is in solution, cheese retains the aliquot part of the total represented by the water-content of the cheese, plus any part of the sugar which has entered into combination with the milk solids during the souring process. The larger part of the lactose passes off with the whey. Lactose[6] is attacked by the lactic-acid bacteria and by them is changed to lactic acid. Cheeses in which this souring process goes on quickly, soon contain a large enough percentage of acid to check the rotting of the cheese by decay organisms. Without this souring, most varieties of cheese will begin to spoil quickly. For each variety there is a proper balance between the souring, which interrupts the growth of many kinds of putrefactive bacteria, and the development of the forms which are essential to proper ripening.
14. Albumin.—This is a form of protein which is in solution in the milk. Albumin forms about 0.7 per cent of cow's milk. It is not coagulated by rennet. Most rennet cheeses, therefore, retain only that portion of the total albumin held in solution in the water retained, as in the case of milk-sugar. Albumin is coagulated by heat, forming a film or membrane upon the surface. There are certain kinds of cheese, such as Ricotte, made by the recovery of albumin by heating.
15. Ash.—The ash or mineral constituents make up about 0.7 per cent of cow's milk. This total includes very small amounts of a great many substances. The exact form of some of the substances is still unknown. Of these salts, the calcium or lime and phosphorus salts are most important in cheese-making. They are partially or completely precipitated by pasteurization. After such precipitation rennet fails to act[7] or acts very slowly; hence pasteurized milk cannot be used for making rennet cheese unless the lost salts are replaced, or the condition of the casein is changed by the addition of some substance, before curdling is attempted.
16. Enzymes.—Milk also contains enzymes. These are chemical ferments secreted by the udder. They have the power to produce changes in organic compounds without themselves undergoing any change. Minute amounts of several enzymes are found in milk as follows: Diastase, galactase, lipase, catalase, peroxidase and reductase. Just what part they play in cheese-making is not definitely known.
17. The flavor of feeds eaten by the cow.—Undesirable flavors in the milk are due many times to the use of feed with very pronounced flavors. The most common of these feeds are onions, garlic, turnips, cabbage, decayed ensilage, various weeds and the like. These undesirable flavors reach the milk because the substances are volatile and are able to pass through the tissues of the animal. While feed containing these flavors is being digested, these volatile substances are not only present in the milk, but in all the tissues of the animal. By the time the process of digestion is completed, the volatile flavors have largely passed away. Therefore, if the times of milking and feeding are properly regulated, a dairy-man may feed considerable quantities of strong-flavored products, such as turnip, cabbage and others, without any appreciable effect on the flavor of the milk. To accomplish this successfully, the cows should be fed immediately before or immediately after milking, preferably after milking. This allows time for the digestive process to take place and for the volatile substances to disappear. If, however, milking is performed three or four hours after feeding, these volatile substances are present in the milk and flavor it.[8]
In the case of those plants which grow wild in the pasture, and to which the cows have continued access, it is more difficult to prevent bad flavor in the milk. The cows may be allowed to graze for a short time only, and that immediately after milking, without affecting the flavor of the milk. This will make it necessary to supplement the pasture with dry feed, or to have another pasture where these undesirable plants do not grow.
Undesirable flavors are usually noticeable in the milk when the cows are turned out to pasture for the first time in the spring; and when they are pastured on rank fall feed, such as second growth clover.