Buffon's Natural History. Volume 10 (of 10) / Containing a Theory of the Earth, a General History of Man, of the Brute Creation, and of Vegetables, Minerals, &c. &c

by comte de Georges Louis Leclerc Buffon

Secondly, By means of my mirror we shall have the true scale of the augmentation of heat, and make a real thermometer, whose divisions will be no longer arbitrary, from the temperature of the air to what degree of heat we chuse, by letting fall, successively, the images of the sun one on the other, and by graduating the intervals, whether by means of an expansive liquor, or a machine of dilatation, and from that we shall know, in fact, what a double, treble, quadruple, &c. augmentation of heat is, and shall find out matters whose expansion, or other effects, will be the most suitable to measure the augmentations of heat.

Thirdly, We shall exactly know how many times is required for the heat of the sun to burn, melt, or calcine different matters, which was hitherto only known in a vague and very indefinite manner; and shall be in a state to make precise comparisons of the activity of our fires with that of the sun, and have exact relations and fixed and invariable measures. In short, those who examine my theory, and shall have seen the effect of my mirror, I think will be convinced the mode I have used was the only one possible to succeed to burn far off, for, independant of the physical difficulty of making large concave, spherical, parybolical mirrors, or of any other curvature whatsoever, regular enough to burn at 150 feet distance, we shall easily be convinced that they would not produce but nearly as much effect as mine, because the focus would be almost as broad; that besides, these curved mirrors, if even it should be possible to make them, would have the very great disadvantage to burn only at a nigh distance, whereas mine burns at all distances; and, consequently, we shall abandon the scheme of making mirrors to burn at a great distance by means of curves, which has uselessly employed a great number of mathematicians and artists, who were always deceived, because they considered the rays of the sun as parallel, whereas they should be considered as they are, namely, as forming angles of all sizes, from 0 to 32 minutes, which makes it impossible, whatsoever curve is given to a mirror, to render the diameter of the focus smaller than the chord, which measures 32 minutes. Thus, even if we could make a concave mirror to burn at a great distance; for example, at 150 feet, by employing all its points on a sphere of 600 feet diameter, and by employing an uncommon mass of glass or metal, it is evident that we shall have a little more advantage than by using, as I have done, only small plane mirrors.

On the whole, although this mirror is susceptible of a very great perfection, both for the adjustment, and many other particulars, and though I think I shall be able to make another, whose effects will be superior, yet, as every thing has its limits, it must not be expected that every one can be formed to burn at extreme distances; to burn, for example, at the distance of half a mile, a mirror 200 times larger would be required; and I am of opinion that more will never be effected than to burn at the distance of 8 or 900 feet. The focus, whose motion is always correspondent to that of the sun, moves so much the quicker as it is farther distant from the mirror; and at 90 feet it would move about six feet a minute.

However, as I have given an account of my discovery, and the success of my experiments, I should render to Archimedes, and the ancients, the glory that is their due. It is certain that Archimedes could perform with metal mirrors what I have done with glass, and that, consequently, I cannot refuse him the title of the first inventor of these mirrors, and the opportunity he had of using them rendered him, without doubt, more celebrated than the merit of the thing itself.

Many advantages may be derived from the use of these mirrors; by an assemblage of small mirrors, with hexagonal planes, and polished steel, which will have more solidity than glasses, and which would not be subject to the alterations which the light of the sun may cause, we may produce very useful effects, and which would amply repay the expences of the construction of the mirror.

“For all evaporations of salt waters, where great quantities of wood and coal are consumed, or structures raised for the purpose of carrying the waters off, which cost more than the construction of many mirrors, such as I mention; for the evaporation of salt waters, only an assemblage of twelve plane mirrors of a square foot each is necessary. The heat reflected by their focuses, although directed below their level, and at fifteen or sixteen feet distance, will be still great enough to boil water, and consequently produce a quick evaporation: for the heat of boiling water is only treble the heat of the sun in summer; and as the reflection of a well polished plane surface only diminishes the heat one half, only six mirrors are required to produce at the focus a heat equal to boiling water; but I shall double the number to make the heat communicate quicker; and likewise by reason of the loss occasioned by the obliquity, under which the light falls on the surface of the water to be evaporated, and because salt water heats slower than fresh. This mirror, whose assemblage would form only a square four feet broad by three high, would be easy to be managed; and if it were required to double or treble the effects in the same time, it would be better to make so many similar mirrors, than to augment the scale of them; for water can only receive a certain quantity of heat, and we should not gain any thing by increasing this degree; whereas, by making two focuses with two equal mirrors, we should double the effect of the evaporation, and treble it by three mirrors, whose focuses would fall separately one from the other on the surface of the water to be evaporated. We cannot avoid the loss caused by the obliquity; nor can it be remedied but by suffering a still greater, that is, by receiving the rays of the sun on a large glass, which would reflect them broken on the mirror; for then it would burn at bottom instead of the top, but it would lose half the heat by the first reflection, and half of the remainder by the second; so that instead of six small mirrors, it would require a dozen to obtain a heat equal to boiling water. For the evaporation to be made with more success, we ought to diminish the thickness of the water as much as possible; a mass of water a foot deep will not evaporate nearly so quick as the same mass reduced to six inches, and increased to double the superfices. Besides, the bottom being nearer the surface, it heats quicker, and this heat, which the bottom of the vessel receives, contributes still more to the celerity of the evaporation.

2. These mirrors may be used with advantage to calcine plaisters, and even calcareous stones, but they would require to be larger, and the matters placed in an elevated situation, that nothing might be lost by the obliquity of the light. It has already been observed that gypsum heats as soon again as soft calcareous stone, and nearly twice as quick as marble, or hard calcareous stone; their calcination, therefore, must be in a respective ratio. I have found by an experiment repeated three times, that very little more heat is required to calcine white gypsum, called alabaster, than to melt lead. Now the heat necessary to melt lead is, according to the experiments of Newton, eight times stronger than the heat of the summer sun; it therefore would require at least sixteen small mirrors to calcine gypsum; and because of the losses thereby occasioned, as well by the obliquity of the light as by the inequality of the focus, which is not removed above fifteen feet, I presume it would require twenty, and perhaps twenty-four mirrors of a foot square each, to calcine gypsum in a short time, consequently it would require an assemblage of forty-eight small mirrors to calcine the softest calcareous stone, and seventy-two of a foot square to calcine hard calcareous stones. Now a mirror twelve feet broad by six feet high, would be a large and cumbersome machine; yet we might conquer these difficulties if the product of the calcination were considerable enough to surpass the expense of the consumption of wood. To ascertain this, we ought to begin by calcining plaister with a mirror of twenty-four pieces, and if that succeeded, to make two other similar mirrors, instead of making a large one of seventy-two pieces; for by coinciding the focuses of these three mirrors of twenty-four pieces, we should produce an equal heat, strong enough to calcine marble or hard stone.

But a very essential matter remains doubtful, that is, to know how much time would be requisite, for example, to calcine a cubical foot of matter, especially if that foot were struck with the heat only in one part. Some time would pass before the heat penetrated its thickness; during this time, a great part of the heat would be lost, and which would issue from this piece of matter after it had entered it. I fear, therefore, much that the stone not being touched by the heat on every side at once, the calcination would be slower, and the produce less. Experience alone can decide this, but it would be at least necessary to attempt it on gypsous matters, whose calcination is as quick again as calcareous stone.

By concentrating this heat of the sun in a kiln, which has no other opening than what admits the light, a great part of the heat would be prevented from flying off, and by mixing with calcareous stone a small quantity of coal dust, which is the cheapest of all combustible matters, this slight supply of food would suffice to feed and augment the quantity of heat, which would produce a more ample and quick calcination, and at very little expense.