The same occurs on a small scale, when calcareous land is underdrained; the lime carbonate dissolved from the soil is partially deposited in the drain pipes, which it frequently obstructs. Similarly, an impure, porous deposit of calcareous tufa is frequently formed on the surface, at the foot or in rills of calcareous hills. When “hard” water, being usually such as contains lime carbonate dissolved in carbonic acid, is boiled, or long exposed to the air, carbonic gas escapes and the lime salt is deposited partly on the walls of the kettle, partly forming a pellicle on the surface of the water.
Dolomite, or bitter spar, greatly resembles calcite in its aspect and properties, although containing nearly half its weight (47.6%) of magnesic, together with calcic carbonate. It is, however, nearly always whitish-opaque; its crystalline and cleavage surfaces are usually somewhat curved; and its effervescence with acids is much less lively than in the case of calcite. Like the latter it often forms pure granular rock deposits, frequently used instead of marble and limestone, and under that designation. The dolomite rocks, however, are much more subject to weathering than the non-magnesian limestones, and it is a curious fact that in contradistinction to the limestone regions proper, those having strongly magnesian limestones or dolomites as their country rock are frequently remarkably sterile. In some portions of Europe dolomite areas are sandy deserts, whose sand consists of weathered dolomite, so pure as to offer no adequate supply of mineral food to plants. In the United States, magnesian limestones underlie the “barrens” of several States and thus seem to justify their European reputation of being poor soil-formers. The exact cause of this difference is not fully understood, for at first sight it is not clear why the presence of the magnesian carbonate should interfere with the well-known beneficial effects of the lime compound. O. Loew and May[16] and others have, however, shown that a certain excess of lime over magnesia in the soil is necessary to prevent the injurious effects exerted by magnesic compounds on plant nutrition, in the absence of an adequate supply of lime. This point will be discussed more in detail farther on.
Selenite or Gypsum, sulfate of lime with about 14 per cent of water, though not as abundant in nature as the carbonate or limestone, is a very widely disseminated mineral and often occurs in large masses over considerable areas. These are undoubtedly in most cases the result of evaporation of sea water ([see p. 26]), more rarely of the transformation of limestone. In mass it frequently resembles the latter, but is readily distinguished by its softness; it does not grit between the teeth, is readily cut with a knife and does not effervesce with acids. Very commonly it occurs in crystals, which are easily split into thin plates. The crystals are very frequently found imbedded in gray or bluish, tough clays, in rosettes, or flat sheets which mostly show characteristic incurrent angles (caused by twinning), and are hence known as “swallowtail” crystals. Such sheets of selenite are popularly called “isinglass,” which name however is equally applied to the mineral mica ([see p. 35]).
Gypsum is only exceptionally an abundant ingredient of soils; yet such soils prevail quite extensively on the upper Rio Grande, in New Mexico and adjacent portions of Chihuahua, Coahuila, and on the Staked Plains of Texas. Here whole ranges of hills are sometimes composed of gypseous sand, bear a scanty, peculiar vegetation, and are ill adapted to agricultural use. It may be said in general that few naturally gypseous soils are very productive. This is largely because of the very heavy clays which commonly accompany it, as the compound itself is not only not hostile to plant life but is in extended use as a valuable fertilizer (“land plaster”) for special purposes. From causes not fully understood as yet, it particularly promotes the growth of leguminous plants, notably the clovers; and as stated in [chapter 9], it also specially favors nitrification in soils. In the arid region it renders important service in the neutralization of “black alkali” or carbonate of soda in alkali soils. Being soluble in 400 parts of water, it easily penetrates downward in most soils, and in doing so effects changes in the zeolitic portions, setting free potash from silicates and thus indirectly supplying plants with this essential ingredient in a soluble form. About 200 pounds per acre is an ordinary dose.
For agricultural use the rock gypsum is ground in mills so as to be easily distributed, and dissolved by the soil water. Frequently, however, it occurs in the soft granular form (gypseous marl) requiring only light crushing; thus in the hills bordering the Great Valley of California, and in parts of New Mexico and Texas.
Iron Minerals.—In connection with calcite and dolomite, the several minerals constituting the common iron ores require mention. One of these is:
Iron Spar or siderite; carbonate of iron, corresponds in composition to calcite and dolomite and crystallizes in the same form. It sometimes occurs in large masses and is an important iron ore, brownish-white in color, and when compact resists the attack of atmospheric oxygen remarkably well. Like the carbonates of lime and magnesia, it is soluble in carbonated water, and its deposits are undoubtedly formed from such solutions. The latter are copiously formed wherever fermenting or decaying organic matter is in contact with iron-bearing materials, such as rust-colored sands or clays; and if the solution so formed can percolate without coming in contact with air, iron spar is formed. But whenever the solution comes in contact with air, it absorbs oxygen and the ferrous carbonate is converted into ferric hydrate or rust, mineralogically known as:
Limonite or brown iron ore. This ore is frequently found deposited on the upper surface of clay layers traversing sandy strata, the clay having arrested the carbonate solution and thus given time to the air to effect the change. Sometimes such deposits form great masses in rock-caves, fissure-veins, or crevices; and like siderite, it is an important iron ore, though frequently quite impure, as in the case of bog ore, which is formed in ill-drained subsoils. It is also sometimes found as the residue from the weathering of rocks rich in hornblende or pyroxene, and in this, as well as in other cases, is pulverulent, constituting yellow ochre. It makes a rust-colored streak on biscuit porcelain or unglazed queensware. It is the coloring material of all yellow or “red” soils and clays, as well as of brown sandstones, which are cemented by it.
As is well known, such clays and sandstones become dark red by heating or “burning,” as in the case of common brick clays; the brown or yellow ferric hydrate losing its water and becoming red ferric oxid. The latter sometimes occurs in nature in the impure, pulverulent condition, constituting “red ochre”; but more commonly and abundantly it is found in the form of
Hematite or red iron ore, which is sometimes formed in nature by limonite losing its water, but more commonly in different ways. It is but rarely found in soils and is of no special interest in that connection.