A fourth form of iron ore, quite common in the soils of some regions, is
Magnetite or magnetic iron ore, also known as lodestone. This mineral, the oxygen-compound of iron corresponding to “blacksmith’s scale,” also occurs in large masses and is an important and usually a very pure iron ore. It occurs very commonly disseminated through certain rocks, and in their weathering it remains unattacked and thus passes unchanged into the soils and sands, constituting the “black sand” so well known to gold miners and almost universally present in the alluvial soils of the Pacific coast. These black grains are of course attracted by the magnet and can thus be easily recognized and extracted. In soils they are simply inert, like quartz sand.
But while the ore is of little interest to the farmer, it is quite otherwise with the compound of this oxid with water, the ferroso-ferric hydrate; intermediate in composition between the white ferrous and the brown ferric hydrates. As mentioned above, the black silicate minerals, such as hornblende and pyroxene, are bottle-green when seen in thin sections. Nearly the same color, with modifications running toward blue and bright green, is often seen in natural clays and rocks, and is almost always caused by the ferroso-ferric hydrate. Such materials always become red or reddish when heated by the formation of red ferric oxid; while when exposed to damp air, they assume the rust color of ferric hydrate.
Reduction of ferric hydrate in ill-drained soils.—When such oxidized, rust-colored clays or soils are exposed to the action of fermenting organic matter, the first effect observed is the change of color from rusty to bluish or greenish, by the reduction of the ferric to ferroso-ferric hydrate. Afterward, if the action is continued, the solution of ferrous carbonate (see above) may be formed, and the greenish or bluish color may disappear.
The importance of this reaction to farming practice lies in the fact that the blue or green tint, wherever it occurs, indicates a lack of aeration, usually by the stagnation of water, in consequence of imperfect drainage. Such a condition, always injurious to plants, becomes doubly so when it is associated with the formation of a metallic solution, such as ferrous carbonate, and promptly results in the languishing or death of plants in consequence of the poisoning of their roots. In the presence of sulfates such as gypsum, the formation of iron pyrite (ferric bisulfid) and sulfuretted hydrogen, is likely to take place. Moreover, under the same conditions the phosphoric acid of the soil may be concentrated into ferrous or ferric phosphate, which pass into deposits of bog ore in the subsoil.
CHAPTER IV.
THE VARIOUS ROCKS AS SOIL-FORMERS.
Rock-weathering in arid and humid Climates.—From what has been said in the preceding chapters of the physical and chemical agencies concerned in rock-weathering, it is obvious that climatic differences may materially influence the character of the soils formed from one and the same kind of rock. Since kaolinization is also a process of hydration, the presence of water must greatly influence its intensity, and especially the subsequent formation of colloidal clay; so that rocks forming clay soils in the region of summer rains may in the arid regions form merely pulverulent soil materials. Many striking examples of these differences may be observed, e. g., in comparing the outcome of the weathering of granitic rocks in the southern Alleghenies with that of the same rocks in the Rocky Mountains and westward, especially in California and Arizona. The sharpness of the ridges of the Sierra Madre, and the roughness of the hard granitic surfaces, contrasts sharply with the rounded ranges formed by the “rotten” granites of the Atlantic slope, where sound, unaltered rock can sometimes not be found at a less depth than forty feet; while at the foot of the Sierra Madre ridges, thick beds of sharp, fresh granitic sand, too open and pervious to serve as soils, cover the upper slopes and the “washes” of the streams, causing the latter to sink out of sight. A general discussion of the kinds of soils formed from the various rocks must, therefore, take these differences into due consideration.
GENERAL CLASSIFICATION OF ROCKS.
Rocks may be broadly classified into three categories, viz:
1. Sedimentary rocks, formed by deposition in water and hence more or less distinctly stratified.