Edison: His Life and Inventions

by Frank Lewis Dyer; Thomas Commerford Martin

GENERICALLY considered, a "battery" is a device which generates electric current. There are two distinct species of battery, one being known as "primary," and the other as "storage," although the latter is sometimes referred to as a "secondary battery" or "accumulator." Every type of each of these two species is essentially alike in its general make-up; that is to say, every cell of battery of any kind contains at least two elements of different nature immersed in a more or less liquid electrolyte of chemical character. On closing the circuit of a primary battery an electric current is generated by reason of the chemical action which is set up between the electrolyte and the elements. This involves a gradual consumption of one of the elements and a corresponding exhaustion of the active properties of the electrolyte. By reason of this, both the element and the electrolyte that have been used up must be renewed from time to time, in order to obtain a continued supply of electric current.

The storage battery also generates electric current through chemical action, but without involving the constant repriming with active materials to replace those consumed and exhausted as above mentioned. The term "storage," as applied to this species of battery, is, however, a misnomer, and has been the cause of much misunderstanding to nontechnical persons. To the lay mind a "storage" battery presents itself in the aspect of a device in which electric energy is STORED, just as compressed air is stored or accumulated in a tank. This view, however, is not in accordance with facts. It is exactly like the primary battery in the fundamental circumstance that its ability for generating electric current depends upon chemical action. In strict terminology it is a "reversible" battery, as will be quite obvious if we glance briefly at its philosophy. When a storage battery is "charged," by having an electric current passed through it, the electric energy produces a chemical effect, adding oxygen to the positive plate, and taking oxygen away from the negative plate. Thus, the positive plate becomes oxidized, and the negative plate reduced. After the charging operation is concluded the battery is ready for use, and upon its circuit being closed through a translating device, such as a lamp or motor, a reversion ("discharge") takes place, the positive plate giving up its oxygen, and the negative plate being oxidized. These chemical actions result in the generation of an electric current as in a primary battery. As a matter of fact, the chemical actions and reactions in a storage battery are much more complex, but the above will serve to afford the lay reader a rather simple idea of the general result arrived at through the chemical activity referred to.

The storage battery, as a commercial article, was introduced into the market in the year 1881. At that time, and all through the succeeding years, until about 1905, there was only one type that was recognized as commercially practicable—namely, that known as the lead-sulphuric-acid cell, consisting of lead plates immersed in an electrolyte of dilute sulphuric acid. In the year last named Edison first brought out his new form of nickel-iron cell with alkaline electrolyte, as we have related in the preceding narrative. Early in the eighties, at Menlo Park, he had given much thought to the lead type of storage battery, and during the course of three years had made a prodigious number of experiments in the direction of improving it, probably performing more experiments in that time than the aggregate of those of all other investigators. Even in those early days he arrived at the conclusion that the lead-sulphuric-acid combination was intrinsically wrong, and did not embrace the elements of a permanent commercial device. He did not at that time, however, engage in a serious search for another form of storage battery, being tremendously occupied with his lighting system and other matters.

It may here be noted, for the information of the lay reader, that the lead-acid type of storage battery consists of two or more lead plates immersed in dilute sulphuric acid and contained in a receptacle of glass, hard rubber, or other special material not acted upon by acid. The plates are prepared and "formed" in various ways, and the chemical actions are similar to those above stated, the positive plate being oxidized and the negative reduced during "charge," and reversed during "discharge." This type of cell, however, has many serious disadvantages inherent to its very nature. We will name a few of them briefly. Constant dropping of fine particles of active material often causes short-circuiting of the plates, and always necessitates occasional washing out of cells; deterioration through "sulphation" if discharge is continued too far or if recharging is not commenced quickly enough; destruction of adjacent metalwork by the corrosive fumes given out during charge and discharge; the tendency of lead plates to "buckle" under certain conditions; the limitation to the use of glass, hard rubber, or similar containers on account of the action of the acid; and the immense weight for electrical capacity. The tremendously complex nature of the chemical reactions which take place in the lead-acid storage battery also renders it an easy prey to many troublesome diseases.

In the year 1900, when Edison undertook to invent a storage battery, he declared it should be a new type into which neither sulphuric nor any other acid should enter. He said that the intimate and continued companionship of an acid and a metal was unnatural, and incompatible with the idea of durability and simplicity. He furthermore stated that lead was an unmechanical metal for a battery, being heavy and lacking stability and elasticity, and that as most metals were unaffected by alkaline solutions, he was going to experiment in that direction. The soundness of his reasoning is amply justified by the perfection of results obtained in the new type of storage battery bearing his name, and now to be described.

The essential technical details of this battery are fully described in an article written by one of Edison's laboratory staff, Walter E. Holland, who for many years has been closely identified with the inventor's work on this cell The article was published in the Electrical World, New York, April 28, 1910; and the following extracts therefrom will afford an intelligent comprehension of this invention:

"The 'A' type Edison cell is the outcome of nine years of costly experimentation and persistent toil on the part of its inventor and his associates....

"The Edison invention involves the use of an entirely new voltaic combination in an alkaline electrolyte, in place of the lead-lead-peroxide combination and acid electrolyte, characteristic of all other commercial storage batteries. Experience has proven that this not only secures durability and greater output per unit-weight of battery, but in addition there is eliminated a long list of troubles and diseases inherent in the lead-acid combination....

"The principle on which the action of this new battery is based is the oxidation and reduction of metals in an electrolyte which does not combine with, and will not dissolve, either the metals or their oxides; and an electrolyte, furthermore, which, although decomposed by the action of the battery, is immediately re-formed in equal quantity; and therefore in effect is a CONSTANT element, not changing in density or in conductivity.

"A battery embodying this basic principle will have features of great value where lightness and durability are desiderata. For instance, the electrolyte, being a constant factor, as explained, is not required in any fixed and large amount, as is the case with sulphuric acid in the lead battery; thus the cell may be designed with minimum distancing of plates and with the greatest economy of space that is consistent with safe insulation and good mechanical design. Again, the active materials of the electrodes being insoluble in, and absolutely unaffected by, the electrolyte, are not liable to any sort of chemical deterioration by action of the electrolyte—no matter how long continued....