The minerals of this group are generally associated with feldspars, and make the dark-colored component of granites, gneisses and lavas. This is especially true of those which have some iron in the crystal. Pyroxenes are salts of metasilicic acid (H₂SiO₃), in which the hydrogen (H) has been replaced by calcium, magnesium, iron, etc. The commoner minerals are orthorhombic or monoclinic, and all agree in their crystal habit, being short stout prisms, with the vertical edges so beveled that a cross section is eight-sided. The cleavage is good in two directions, parallel to the beveling faces (m in figure b, [Plate 36]), and they intersect at an angle of 87°. This is very characteristic, and if one has a crystal broken across, it is easy to see and measure this angle of intersection. These pyroxenes have the same chemical composition as the corresponding series of amphiboles, but the two are distinguished by several features. Pyroxenes are short and stout crystals, while amphiboles are long and either blade- or needle-like; pyroxenes are eight-sided in cross section, while amphiboles are six-sided; in pyroxenes the cleavage planes intersect at 87°, while in amphiboles they intersect at 55°. The minerals of this group are most frequently one of the components of a lava or granite, and are less frequently associated with metamorphic rocks. Three are common; enstatite, hypersthene, and augite.

[Enstatite]
MgSiO₃

Usually occurs in lamellar or fibrous-lamellar masses in dark lavas; hardness, 5.5; specific gravity, 3.3; color gray, bronze or brown; luster vitreous, translucent on thin edges.

Enstatite rarely occurs in crystals, but when it does they are orthorhombic. Usually it is in irregular masses with the cleavage angles, typical of pyroxene. The color is light, that is gray or brownish, and the streak white or nearly so. In most respects it is similar to hypersthene, which has the same composition, except that a large part of the magnesium is replaced by iron, and there are all sorts of gradations between the two minerals. When some iron takes the place of magnesium, the color darkens to, or towards bronze, until when about a third of the magnesium is so replaced, and the color is fully bronze, this variety is called bronzite. Bronzite is present in some of the dark lavas like gabbro and peridotite. Enstatite is found in the Adirondack Mountains, at Brewster and Edwards, N. Y., etc.

[Hypersthene]
(MgFe)SiO₃

Occurs in cleavable masses in dark lavas; hardness, 5.5; specific gravity, 3.4; color dark-brown or greenish-brown; luster vitreous; translucent on thin edges.

Hypersthene is a pyroxene in which magnesium and iron are present in about equal quantities. It is similar to enstatite, except that the color is darker, and the streak gray or brownish-gray in color. These two minerals grade into each other, so that there are cases where it is simply a matter of preference as to which name should be given to the mineral. This form is associated with dark lavas, of the gabbro or peridotite type, in such places as the Adirondack Mountains, Mount Shasta in California, Buffalo Peaks, Colo., etc.

[Augite]
CaMg(SiO₃)₂, MgAlSiO₆ + Fe₂O₃
[Pl. 36]

Usually occurs in short stout monoclinic crystals; hardness, 5.5; specific gravity, 3.3; color dark-green to black; luster vitreous; translucent on thin edges.

Augite is a complex pyroxene having some iron and aluminum always present in it, but the amount not a fixed quantity. It is by far the commonest of the pyroxenes and has a wide distribution, both in the sorts of lavas in which it appears, and in the world. It is commonly the dark component of such lavas, as gabbros and peridotites, and also is common in metamorphic rocks, especially impure crystalline limestones. It is found at Raymond and Mumford, Me., Thetford, Vt., Canaan, Conn., in Westchester, Orange, Lewis and St. Lawrence Counties of N. Y., in Chester Co., Penn., at Ducktown, Tenn., Templeton, Canada, etc.