We have frequently mentioned “combustion,” and as under ordinary circumstances such effects cannot take place without atmospheric air, we will consider it. Combustion is chemical action accompanied by light and heat. Chemical union is always attended by the development of heat, not always by light, because the union varies in intensity and quickness. But when a candle is burning we can study all the interesting phenomena of combustion. We have already spoken of Heat and Light, so we need only refer the readers to those subjects in the former parts of this volume. Heat is referable to chemical action, and varies according to the energy of union. Heat is always present, remember, in a greater or less degree; and when visible combustion takes place we see light. Invisible combustion goes on in our bodies, and we feel heat; when we get cold we feed the fire by eating, or blow it by exercise and air in our lungs.
Fig. 328.—Gas evolved from flame.
We shall speak, however, of combustion now as it affects us in daily life; our fires, our candles, gas, etc., and under these ordinary circumstances hydrogen and carbon are present. (We shall hear more about carbon presently.) These unite with the oxygen to form water and carbonic acid; the water being visible as we first put the cold shade upon the lighted lamp, and the carbonic acid renders the air impure.
In the case of a common candle, or lamp, combustion takes place in the same way. The wick is the intermediary. The oil mounts in the lamp wick, where it is converted into a gas by heat; it then “takes fire,” and gives us light and heat. The candle-flame is just the same with one exception: the burning material is solid, not liquid, though the difference is only apparent, for the wax is melted and goes up as gas. The burning part of the wick has a centre where there is no combustion, and contains carbon. We can prove this by placing a bent tube, as in the illustration (fig. 326), one end in the unburning part of the flame. We shall soon see a dark vapour come over into the receiver. This is combustible, for if we raise the tube without the glass we can light the gas (fig. 327). If we insert the end of the tube into the brilliant portion of the flame we shall perceive a black vapour, which will extinguish the combustion, for it is a mixture of carbonic acid gas and aqueous vapour, in which (fig. 328) particles of carbon are floating.
Fig. 329.—Davy’s safety lamp.
Fig. 330.—Davy lamp (section).