Phosphorus occurs in very small quantities, though in the form of phosphates we are acquainted with it pretty generally, and as such it is absorbed by plants, and is useful in agricultural operations. In our organization—in the brain, the nerves, flesh, and particularly in bones—phosphorus is present, and likewise in all animals. Nevertheless it is highly poisonous. It is usually obtained from the calcined bones of mammalia by obtaining phosphoric acid by means of acting upon the bone-ash with sulphuric acid. Phosphorus when pure is colourless, nearly transparent, soft, and easily cut. It has a strong affinity for oxygen. It evolves white vapour in atmospheric air, and is luminous; to this element is attributable the luminosity of bones of decaying animal matter. It should be kept in water, and handled—or indeed not handled—but grasped with a proper instrument.
Phosphorus is much used in the manufacture of lucifer matches, and we are all aware of the ghastly appearance and ghostly presentment it gives when rubbed upon the face and hands in the dark. In the ripples of the waves and under the counter of ships at sea, the phosphorescence of the ocean is very marked. In Calais harbour we have frequently noticed it of a very brilliant appearance as the mail steamer slowly came to her moorings. This appearance is due to the presence of phosphorus in the tiny animalculæ of the sea. It is also observable in the female glow-worm, and the “fire-fly.” Phosphorus was discovered by Brandt in 1669.
Fig. 386.—Manufacture of sulphuric acid.
It forms two compounds with oxygen-phosphorous acid, H2PO4, and phosphoric acid, H3PO4. The compound with hydrogen is well marked as phosphuretted hydrogen, and is a product of animal and vegetable decomposition. It may frequently be observed in stagnant pools, for when emitted it becomes luminous by contact with atmospheric air. There is a very pretty but not altogether safe experiment to be performed when phosphuretted hydrogen has been prepared in the following manner. Heat small pieces of phosphorus with milk of lime or a solution of caustic potash; or make a paste of quick-lime and phosphorus, and put into the flask with some quick-lime powdered. Fix a tube to the neck, and let the other end be inserted in a basin of water. (See illustration, fig. 388.) Apply heat; the phosphuretted hydrogen will be given off, and will emerge from the water in the basin in luminous rings of a very beautiful appearance. The greatest care should be taken in the performance of this very simple experiment. No water must on any account come in contact with the mixture in the flask. If even a drop or two find its way in through the bent tube a tremendous explosion will result, and then the fire generated will surely prove disastrous. The experiment can be performed in a cheaper and less dangerous fashion by dropping phosphate of lime into the basin. We strongly recommend the latter course to the student unless he has had some practice in the handling of these inflammable substances, and learnt caution by experience. The effect when the experiment is properly performed is very good, the smoke rising in a succession of coloured rings.
Fig. 387.—(Phosphuretted hydrogen and marsh gas) Will-o’-the-Wisp.
Silicon is not found in a free state in nature, but, combined with oxygen, as Silica it constitutes the major portion of our earth, and even occurs in wheat stalks and bones of animals. As flint or quartz (see Mineralogy) it is very plentiful, and in its purest form is known as rock crystal, and approaches the form of carbon known as diamond. When separated from oxygen, silicon is a powder of greyish-brown appearance, and when heated in an atmosphere of oxygen forms silicic “acid” again, which, however, is not acid to the taste, and is also termed “silica,” or “silex.” It is fused with great difficulty, but enters into the manufacture of glass in the form of sand. The chemical composition of glass is mixed silicate of potassium or sodium, with silicates of calcium, lead, etc. Ordinary window-glass is a mixture of silicates of sodium and calcium; crown glass contains calcium and silicate of potassium. Crystal glass is a mixture of the same silicate and lead. Flint glass is of a heavier composition. Glass can be coloured by copper to a gold tinge, blue by cobalt, green by chromium, etc. Glass made on a large scale is composed of the following materials, according to the kind of glass that is required.
Flint glass (“crystal”) is very heavy and moderately soft, very white and bright. It is essentially a table-glass, and was used in the construction of the Crystal Palace. Its composition is—pure white sea-sand, 52 parts, potash 14 parts, oxide of lead, 34 parts = 100.
| Plate Glass. | Crown Glass. | Green (Bottle) Glass. | |||
|---|---|---|---|---|---|
| Pure white sand | 55 parts. | Fine sand | 63 parts. | Sea sand | 80 parts. |
| Soda | 35 ” | Chalk | 7 ” | Salt | 10 ” |
| Nitre | 8 ” | Soda | 30 ” | Lime | 10 ” |
| Lime | 2 ” | ||||
| 100 ” | 100 ” | 100 ” | |||