Harmfulness of Baking Powder Residues.
—The question of the harmfulness of the residues left by the various forms of baking powder is one which has been of much interest to the hygienist and physician. It is not claimed in any case that these residues are beneficial. The principal question which has been discussed is which of them is the least harmful. This is a question which it is not proper to enter into in this manual. It might, however, not be out of place to say that the use of chemical reagents for leavening bread is not as advisable as the use of the ordinary fermentation. It would be better, evidently, if all people used more yeast bread and less baking powder rolls. At the same time the utility and convenience of baking powder cannot be denied, and this is a factor which must be taken into consideration in the general discussion and final resolution of the question.
Character of Alum Residues.
—Every one is agreed that the substance known as alum, namely, the sulfate of alumina in conjunction with another mineral or base, such as soda, potash, or ammonia, is not a desirable constituent of food products. In the manufacture of baking powders containing alum an effort is made to so balance the constituents that when the reaction is completed no undecomposed alum remains. If this condition is secured in every instance the materials which remain in the bread are not alum but the residues above mentioned, consisting of aluminium hydrate, and sulfates of soda, potash, or ammonia.
The residue of chief importance is the hydroxid or hydrate of alumina, which is the form in which the alumina itself should appear when a complete reaction like that defined above takes place. When the hydroxid of alumina is dried and especially when ignited it is converted into an oxid of alumina which is highly insoluble in water and only slightly soluble in a very dilute acid solution. The claim is made by the manufacturer of alum powders that the aluminium residue which is formed is insoluble in the digestive juices and therefore cannot produce any effect usually ascribed to the soluble salts of aluminium. It is important that the conditions which are found in the baking of a loaf are such as to produce this highly desirable result. The temperature of the interior of the loaf during baking does not rise much above that of boiling water, although the exterior temperature, which is sufficient to produce the browning of the crust, is very much above that temperature. It is evident that as long as any considerable proportion of water remains in the loaf it will be difficult to raise the interior of the loaf to the temperature just mentioned, and if this were done the caramelization would take place throughout the whole loaf. Unfortunately, from a scientific point of view the investigation of this subject has not been always undertaken under conditions which are wholly beyond criticism. Many of the investigations have been in the interest of rival baking powder companies, and it is very desirable that this matter should be undertaken in a wholly unbiased way and conducted in such a manner as to lead to results which all will accept. Chemical and physiological investigations, which have even as a remote object the promotion of the sale of one compound and the repression of the sale of another, lose at the outset much of that claim upon the public confidence which such investigations made from a purely scientific point of view should have.
General Statement.
—In respect of the use of chemical leavening agents in general it may be said that they introduce an extraneous product into the bread which is not likely to promote the health and which, therefore, on general principles should be excluded. On the other hand, large experience has shown that the consumption of bread made by these leavening agents does not produce any general effect upon the public health which is noticeable. This, it is understood, is not any valid argument in favor of the process. It must also be acknowledged that a fermentation of a bread with yeast also introduces extraneous matter into the food, viz., alcohol and congeneric products of fermentation, and hence this process may be open to a certain extent to the same objection as the one above. It is too early yet to formulate definite principles either of inclusion or exclusion of these products, and the purpose of this manual is secured when the general character and effects thereof are briefly outlined.
Composition of Bread.
—Because of the many different methods of bread making which are practised it is not possible to give in a chemical form an analysis which would do more than represent in general the character of the bread in common use. For instance, the quantity of water which is found in bread varies greatly and the nature of bread itself must be influenced by the character of the flour from which it is made. The flour depends upon the quality of the wheat used in its manufacture. Hence the same brand of bread prepared in the same way and baked in the same manner must necessarily vary in composition from season to season and even from day to day. It must be understood also that it is a very common custom in the United States to use milk in the mixing of dough, and thus a food product is introduced which of itself is not of constant character. Some bakers use whole milk, others skimmed, and others sour milk.
A very good formula for mixing dough for bread making consists in using the following proportions of ingredients mentioned: