2d. Dissolve 560 grains of Rochelle salt in two or three ounces of water and filter. Dissolve 800 grains of nitrate of silver in four ounces of water. Take an ounce of strong ammonia of commerce, and add nitrate solution to it until a brown precipitate remains undissolved. Then add more ammonia and again nitrate of silver solution. This alternate addition is to be carefully continued until the silver solution is exhausted, when some of the brown precipitate should remain in suspension. The mixture then contains an undissolved excess of oxide of silver. Filter. Just before using, mix with the Rochelle salt solution, and add water enough to make 22 ounces.
Fig. 1.
The Silvering Vessel.
The vessel in which the silvering is to be performed may be a circular dish (Fig. 1) of ordinary tinplate, 16 1/2 inches in diameter, with a flat bottom and perpendicular sides one inch high, and coated inside with a mixture of beeswax and rosin (equal parts), At opposite ends of one diameter two narrow pieces of wood, a a′, 1/8 of an inch thick, are cemented. They are to keep the face of the mirror from the bottom of the vessel, and permit of a rocking motion being given to the glass. Before using such a vessel, it is necessary to touch any cracks that may have formed in the wax with a hot poker. A spirit lamp causes bubbles and holes through to the tin. The vessel too must always, especially if partly silvered, be cleaned with nitric acid and water, and left filled with cold water till needed. Instead of the above, India-rubber baths have been occasionally used.
3d. In order to secure fine and hard deposits in the shortest time and with weak solutions, it is desirable, though not necessary, to warm the glass slightly. This is best done by putting it in a tub or other suitably sized vessel, and pouring in water enough to cover the glass. Then hot water is gradually stirred in, till the mixture reaches 100° F. It is also advantageous to place the vessels containing the ingredients for the silvering solution in the same bath for a short time.
4th. On taking the glass out of the warm water, carry it to the silvering vessel—into which an assistant has just previously poured the mixed silvering solution—and immediately immerse it face downwards, dipping in first one edge and then quickly letting down the other till the face is horizontal. The back of course is not covered with the fluid. The same precautions are necessary to avoid streaks in silvering as in the case of putting a collodion plate in the bath. Place the whole apparatus before a window. Keep up a slow rocking motion of the glass, and watch for the appearance of the bright silver film. The solution quickly turns brown, and the silver soon after appears, usually in from three to five minutes. Leave the mirror in the liquid about six times as long. At the expiration of the twenty minutes or half hour lift it out, and look through it at some very bright object. If the object is scarcely visible, the silver surface must then be washed with plenty of water, and set on edge on bibulous paper to dry. If, on the contrary, it is too thin, put it quickly back, and leave it until thick enough. When polished the silver ought, if held between the eye and the sun, to show his disk of a light blue tint. On coming out of the bath the metallic surface should have a rosy golden color by reflected light.
5th. When the mirror is thoroughly dry, and no drops of water remain about the edges, lay it upon its back on a thoroughly dusted table. Take a piece of the softest thin buckskin, and stuff it loosely with cotton to make a rubber. Avoid using the edge pieces of a skin, as they are always hard and contain nodules of lime.
Go gently over the whole silver surface with this rubber in circular strokes, in order to commence the removal of the rosy golden film, and to condense the silver. Then having put some very fine rouge on a piece of buckskin laid flat on the table, impregnate the rubber with it. The best stroke for polishing is a motion in small circles, at times going gradually round on the mirror, at times across on the various chords (Fig. 2). At the end of an hour of continuous gentle rubbing, with occasional touches on the flat rouged skin, the surface will be polished so as to be perfectly black in oblique positions, and, with even moderate care, scratchless. The process is like a burnishing. Put the rubber carefully away for another occasion.
Fig. 2.