From this alteration aspect ore-deposits may be considered to have four horizons:—

  1. The zone near the outcrop, where the dominating feature is oxidation and leaching of the soluble minerals.
  2. A lower horizon, still in the zone of oxidation, where the predominant feature is the deposition of metals as native, oxides, and carbonates.
  3. The upper horizon of the sulphide zone, where the special feature is the enrichment due to secondary deposition as sulphides.
  4. The region below these zones of secondary alteration, where the deposit is in its primary state.

These zones are seldom sharply defined, nor are they always all in evidence. How far they are in evidence will depend, among other things, upon the amount and rapidity of erosion, the structure and mineralogical character of the deposit, and upon the enclosing rock.

If erosion is extremely rapid, as in cold, wet climates, and rough topography, or as in the case of glaciation of the Lake copper deposits, denudation follows close on the heels of alteration, and the surface is so rapidly removed that we may have the primary ore practically at the surface. Flat, arid regions present the other extreme, for denudation is much slower, and conditions are most perfect for deep penetration of oxidizing agencies, and the consequent alteration and concentration of the metals.

The migration of metals from the top of the oxidized zone leaves but a barren cap for erosion. The consequent effect of denudation that lags behind alteration is to raise slowly the concentrated metals toward the surface, and thus subject them to renewed attack and repeated migration. In this manner we can account for the enormous concentration of values in the lower oxidized and upper sulphide zones overlying very lean sulphides in depth.

Some minerals are more freely soluble and more readily precipitated than others. From this cause there is in complex metal deposits a rearrangement of horizontal sequence, in addition to enrichment at certain horizons and impoverishment at others. The whole subject is one of too great complexity for adequate consideration in this discussion. No engineer is properly equipped to give judgment on extension in depth without a thorough grasp of the great principles laid down by Van Hise, Emmons, Lindgren, Weed, and others. We may, however, briefly examine some of the theoretical effects of such alteration.

Zinc, iron, and lead sulphides are a common primary combination. These metals are rendered soluble from their usual primary forms by oxidizing agencies, in the order given. They reprecipitate as sulphides in the reverse sequence. The result is the leaching of zinc and iron readily in the oxidized zone, thus differentially enriching the lead which lags behind, and a further extension of the lead horizon is provided by the early precipitation of such lead as does migrate. Therefore, the lead often predominates in the second and the upper portion of the third zone, with the zinc and iron below. Although the action of all surface waters is toward oxidation and carbonation of these metals, the carbonate development of oxidized zones is more marked when the enclosing rocks are calcareous.

In copper-iron deposits, the comparatively easy decomposition and solubility and precipitation of the copper and some iron salts generally result in more extensive impoverishment of these metals near the surface, and more predominant enrichment at a lower horizon than is the case with any other metals. The barren "iron hat" at the first zone, the carbonates and oxides at the second, the enrichment with secondary copper sulphides at the top of the third, and the occurrence of secondary copper-iron sulphides below, are often most clearly defined. In the easy recognition of the secondary copper sulphides, chalcocite, bornite, etc., the engineer finds a finger-post on the road to extension in depth; and the directions upon this post are not to be disregarded. The number of copper deposits enriched from unpayability in the first zone to a profitable character in the next two, and unpayability again in the fourth, is legion.

Silver occurs most abundantly in combination with either lead, copper, iron, or gold. As it resists oxidation and solution more strenuously than copper and iron, its tendency when in combination with them is to lag behind in migration. There is thus a differential enrichment of silver in the upper two zones, due to the reduction in specific gravity of the ore by the removal of associated metals. Silver does migrate somewhat, however, and as it precipitates more readily than copper, lead, zinc, or iron, its tendency when in combination with them is towards enrichment above the horizons of enrichment of these metals. When it is in combination with lead and zinc, its very ready precipitation from solution by the galena leaves it in combination more predominantly with the lead. The secondary enrichment of silver deposits at the top of the sulphide zone is sometimes a most pronounced feature, and it seems to be the explanation of the origin of many "bonanzas."

In gold deposits, the greater resistance to solubility of this metal than most of the others, renders the phenomena of migration to depth less marked. Further than this, migration is often interfered with by the more impervious quartz matrix of many gold deposits. Where gold is associated with large quantities of base metals, however, the leaching of the latter in the oxidized zone leaves the ore differentially richer, and as gold is also slightly soluble, in such cases the migration of the base metals does carry some of the gold. In the instance especially of impregnation or replacement deposits, where the matrix is easily permeable, the upper sulphide zone is distinctly richer than lower down, and this enrichment is accompanied by a considerable increase in sulphides and tellurides. The predominant characteristic of alteration in gold deposits is, however, enrichment in the oxidized zone with the maximum values near the surface. The reasons for this appear to be that gold in its resistance to oxidation and wholesale migration gives opportunities to a sort of combined mechanical and chemical enrichment.