In dry climates, especially, the gentleness of erosion allows of more thorough decomposition of the outcroppings, and a mechanical separation of the gold from the detritus. It remains on or near the deposit, ready to be carried below, mechanically or otherwise. In wet climates this is less pronounced, for erosion bears away the croppings before such an extensive decomposition and freeing of the gold particles. The West Australian gold fields present an especially prominent example of this type of superficial enrichment. During the last fifteen years nearly eight hundred companies have been formed for working mines in this region. Although from four hundred of these high-grade ore has been produced, some thirty-three only have ever paid dividends. The great majority have been unpayable below oxidation,—a distance of one or two hundred feet. The writer's unvarying experience with gold is that it is richer in the oxidized zone than at any point below. While cases do occur of gold deposits richer in the upper sulphide zone than below, even the upper sulphides are usually poorer than the oxidized region. In quartz veins preëminently, evidence of enrichment in the third zone is likely to be practically absent.
Tin ores present an anomaly among the base metals under discussion, in that the primary form of this metal in most workable deposits is an oxide. Tin in this form is most difficult of solution from ground agencies, as witness the great alluvial deposits, often of considerable geologic age. In consequence the phenomena of migration and enrichment are almost wholly absent, except such as are due to mechanical penetration of tin from surface decomposition of the matrix akin to that described in gold deposits.
In general, three or four essential facts from secondary alteration must be kept in view when prognosticating extensions.
Oxidation usually alters treatment problems, and oxidized ore of the same grade as sulphides can often be treated more cheaply. This is not universal. Low-grade ores of lead, copper, and zinc may be treatable by concentration when in the form of sulphides, and may be valueless when oxidized, even though of the same grade.
Copper ores generally show violent enrichment at the base of the oxidized, and at the top of the sulphide zone.
Lead-zinc ores show lead enrichment and zinc impoverishment in the oxidized zone but have usually less pronounced enrichment below water level than copper. The rearrangement of the metals by the deeper migration of the zinc, also renders them metallurgically of less value with depth.
Silver deposits are often differentially enriched in the oxidized zone, and at times tend to concentrate in the upper sulphide zone.
Gold deposits usually decrease in value from the surface through the whole of the three alteration zones.
Size of Deposits.—The proverb of a relation between extension in depth and size of ore-bodies expresses one of the oldest of miners' beliefs. It has some basis in experience, especially in fissure veins, but has little foundation in theory and is applicable over but limited areas and under limited conditions.
From a structural view, the depth of fissuring is likely to be more or less in proportion to its length and breadth and therefore the volume of vein filling with depth is likely to be proportional to length and width of the fissure. As to the distribution of values, if we eliminate the influence of changing wall rocks, or other precipitating agencies which often cause the values to arrange themselves in "floors," and of secondary alteration, there may be some reason to assume distribution of values of an extent equal vertically to that displayed horizontally. There is, as said, more reason in experience for this assumption than in theory. A study of the shape of a great many ore-shoots in mines of fissure type indicates that when the ore-shoots or ore-bodies are approaching vertical exhaustion they do not end abruptly, but gradually shorten and decrease in value, their bottom boundaries being more often wedge-shaped than even lenticular. If this could be taken as the usual occurrence, it would be possible (eliminating the evident exceptions mentioned above) to state roughly that the minimum extension of an ore-body or ore-shoot in depth below any given horizon would be a distance represented by a radius equal to one-half its length. By length is not meant necessarily the length of a horizontal section, but of one at right angles to the downward axis.