No instrument known to the chemists of the 19th century could have detected so tiny a loss of mass in such a large total. No wonder, then, that from Lavoisier on, scientists thought that the law of conservation of mass held exactly.
Radioactive changes gave off much more energy per atom than chemical changes did, and the percentage loss in mass was correspondingly greater. The loss of mass in radioactive changes was found to match the production of energy in just the way Einstein predicted.
It was no longer quite accurate to talk about the conservation of mass after 1905 (even though mass was just about conserved in ordinary chemical reactions so that the law could continue to be used by chemists without trouble). Instead, it is more proper to speak of the conservation of energy, and to remember that mass was one form of energy and a very concentrated form.
The mass-energy equivalence fully explained why the atom should contain so great a store of energy. Indeed, the surprise was that radioactive changes gave off as little energy as they did. When a uranium atom broke down through a series of steps to a lead atom, it produced a million times as much energy as that same atom would release if it were involved in even the most violent of chemical changes. Nevertheless, that enormous energy change in the radioactive breakdown represented only about one-half of 1% of the total energy to which the mass of the uranium atom was equivalent.
Once Rutherford worked out the nuclear theory of the atom, it became clear from the mass-energy equivalence that the source of the energy of radioactivity was likely to be in the atomic nucleus where almost all the mass of the atom was to be found.
The attention of physicists therefore turned to the nucleus.
THE STRUCTURE OF THE NUCLEUS
The Proton
As early as 1886 Eugen Goldstein, who was working with cathode rays, also studied rays that moved in the opposite direction. Since the cathode rays (electrons) were negatively charged, rays moving in the opposite direction would have to be positively charged. In 1907 J. J. Thomson called them “positive rays”.
Once Rutherford worked out the nuclear structure of the atom, it seemed clear that the positive rays were atomic nuclei from which a number of electrons had been knocked away. These nuclei came in different sizes.