Were the nuclei single particles—a different one for every isotope of every element? Or were they all built up out of numbers of still smaller particles of a very limited number of varieties? Might it be that the nuclei owed their positive electrical charge to the fact that they contained particles just like the electron, but ones that carried a positive charge rather than a negative one?
All attempts to discover this “positive electron” in the nuclei failed, however. The smallest nucleus found was that produced by knocking the single electron off a hydrogen atom in one way or another. This hydrogen nucleus had a single positive charge, one that was exactly equal in size to the negative charge on the electron. The hydrogen nucleus, however, was much more massive than an electron. The hydrogen nucleus with its single positive charge was approximately 1837 times as massive as the electron with its single negative charge.
Was it possible to knock the positive charge loose from the mass of the hydrogen nucleus? Nothing physicists did could manage to do that. In 1914 Rutherford decided the attempt should be given up. He suggested that the hydrogen nucleus, for all its high mass, should be considered the unit of positive electrical charge, just as the electron was the unit of negative electrical charge. He called the hydrogen nucleus a “proton” from the Greek word for “first” because it was the nucleus of the first element.
One proton balances 1837 electrons.
Why the proton should be so much more massive than the electron is still one of the unanswered mysteries of physics.
The Proton-Electron Theory
What about the nuclei of elements other than hydrogen?
All the other elements had nuclei more massive than that of hydrogen and the natural first guess was that these were made up of some appropriate number of protons closely packed together. The helium nucleus, which had a mass four times as great as that of hydrogen, might be made up of 4 protons; the oxygen nucleus with a mass number of 16 might be made up of 16 protons and so on.
This guess, however, ran into immediate difficulties. A helium nucleus might have a mass number of 4 but it had an electric charge of +2. If it were made up of 4 protons, it ought to have an electric charge of +4. In the same way, an oxygen nucleus made up of 16 protons ought to have a charge of +16, but in actual fact it had one of +8.