The properties of paramagnetism and diamagnetism are not possessed by solids only, but exist also in liquids and gases. When experimenting with liquids, they were placed in suitable glass vessels, such as watch crystals, supported on pole pieces properly shaped to receive them. Under these circumstances paramagnetic liquids, such as salts of iron or cobalt dissolved in water, underwent curious contortions in shape, the tendency being to arrange the greater part of their mass in the direction in which the flux passed; namely, directly between the poles. Diamagnetic liquids, such as solutions of salts of bismuth and antimony, in a similar manner, arranged the greater part of their mass in positions at right angles to this direction, or equatorially.
At first Faraday attributed the repulsion of diamagnetic substances to a polarity, separate and distinct from ordinary magnetic polarity, for which he proposed the name, diamagnetic polarity. He believed that when a diamagnetic substance is brought near to the north pole of a magnet, a north pole was developed in its approached end, and that therefore repulsion occurred. He afterwards rejected this view, though it has been subsequently adopted by Weber and Tyndall, the latter of whom conducted an extended series of experiments on the subject. The majority of physicists, however, at the present time, do not believe in the existence of a diamagnetic polarity. They point out that the apparent repulsion of diamagnetic substances is due to the fact that they are less paramagnetic than the oxygen of the air in which they are suspended.
During this investigation Faraday observed some phenomena that led him to a belief in the existence of another form of force, distinct from either paramagnetic or diamagnetic force, which he called the magne-crystallic force. He had been experimenting with some slender needles of bismuth, suspending them horizontally between the poles of an electro-magnet. Taking a few of these cylinders at random from a greater number, he was much perplexed to find that they did not all come to rest equatorially, as well-behaved bars of diamagnetic bismuth should do, though, if subjected to the action of a single magnetic pole, they did show this diamagnetic character by their marked repulsion. After much experimentation, he ascribed this phenomenon to the crystalline condition of the cylinder. By experimenting with carefully selected groups of crystals of bismuth, he believed he could trace the cause of the phenomenon to the action of a force which he called the magne-crystallic force.
Extended experiments carried on by Plücker on the influence of magnetism on crystalline substances led him to believe that a close relation exists between the ultimate forms of the particles of matter and their magnetic behavior. This subject is as yet far from being fully understood.
There was another series of investigations made by Faraday between the years 1831 and 1840, that has been wonderfully utilized, and may properly be ranked among his great discoveries. We allude to his researches on the laws which govern the chemical decomposition of compound substances by electricity. The fact that the electric current possesses the power of decomposing compound substances was known as early as 1800, when Carlisle and Nicholson separated water into its constituent elements, by the passage of a voltaic current. Davy, too, in 1806, had delivered his celebrated discourse "On Some Chemical Agencies of Electricity," and in 1807, had announced his great discovery of the decomposition of the fixed alkalies.
Faraday showed that the amount of chemical action produced by electricity is fixed and definite. In order to be able to measure the amount of this action, he invented an instrument which he called a voltameter, or a volta-electrometer. It consisted of a simple device for measuring the amount of hydrogen and oxygen gases liberated by the passage of an electric current through water acidulated with sulphuric acid. He showed, by numerous experiments, that the decomposition effected is invariably proportional to the amount of electricity passing; that variations in the size of the electrodes, in the pressure, or in the degree of dilution of the electrolyte, had nothing to do with the result, and that therefore a voltameter could be employed to determine the amount of electricity passing in a given circuit. He also demonstrated that when a current is passed through different electrolytes (compound substances decomposed by the passage of electricity), the amount of the decompositions are chemically equivalent to each other.
The extent of Faraday's work in the electro-chemical field may be judged by considering some of the terms he proposed for its phenomena, most of which, with some trifling exceptions, are still in use. It was he who gave the name electrolysis to decomposition by the electric current; he also proposed to call the wires, or conductors connected with the battery, or other electric source, the electrodes, naming that one which was connected with the positive terminal, the anode, and that one connected with the negative terminal, the cathode. He called the separate atoms or groups of atoms into which bodies undergoing electrolysis are separated, the radicals, or ions, and named the electro-positive ions, which appear at the cathode, the kathions, and the electro-negative radicals which appear at the anode, the anions.
There were many other researches made by Faraday, such as his experiments on disruptive electric discharges, his investigations on the electric eel, his many researches on the phenomena both of frictional electricity and of the voltaic pile, his investigations on the contact and chemical theories of the voltaic pile, and those on chemical decomposition by frictional electricity; these are but some of the mere important of them. Those we have already discussed will, however, amply suffice to show the value of his work. Rather than take up any others, let us inquire what influence, if any, the various groups of discoveries we have already discussed have exerted on the electric arts and sciences in our present time. What practical results have attended these discoveries? What actual, useful, commercial machines have been based on them? What useful processes or industries have grown out of them?
And, first, as to actual commercial machines. These researches not only led to the production of dynamo-electric machines, but, in point of fact, Faraday actually produced the first dynamo. A dynamo-electric machine, as is well known, is a machine by means of which mechanical energy is converted into electrical energy, by causing conductors to cut through, or be cut through by, lines of magnetic force; or, briefly, it is a machine by means of which electricity is readily obtained from magnetism.
Faraday's invention of the first dynamo is interesting because at the same time he made the invention he solved a problem which up to his time had been the despair of the ablest physicists and mathematicians. This was the phenomenon of Arago's rotating disc. It was briefly as follows: If a copper disc be rotated above a magnet, the needle tends to follow the plate in its rotation; or, if a copper plate be placed at rest above or below an oscillating magnet, it tends to check its oscillations and bring the needle quickly to rest. Faraday investigated these phenomena and soon discovered that a copper disc rotated below two magnet poles had electric currents generated in it, which flowed radially through the disc between its circumference and centre. By placing one end of a conducting circuit on the axis of the disc, and the other end on its circumference, he succeeded in drawing off a continuous electric current generated from magnetism, and thus produced the first dynamo. This was in 1831. Faraday produced many other dynamos besides this simple disc machine.