Figure 14 shows how the zincs are joined "in parallel," the zinc or negative pole of one being connected by wire to the zinc or negative pole of the rest, and all the copper or positive poles together. This arrangement does not increase the electromotive force, but diminishes the resistance. In fact, the battery is equivalent to a single cell having plates equal in area to the total area of all the plates. Although unable to overcome a high resistance, it can produce a large volume or quantity of electricity.
Numerous voltaic combinations and varieties of cell have been found out. In general, where-ever two metals in contact are placed in a liquid which acts with more chemical energy on one than on the other, as sulphuric acid does on zinc in preference to copper, there is a development of electricity. Readers may have seen how an iron fence post corrodes at its junction with the lead that fixes it in the stone. This decay is owing to the wet forming a voltaic couple with the two dissimilar metals and rusting the iron. In the following list of materials, when any two in contact are plunged in dilute acid, that which is higher in the order becomes the positive plate or negative pole to that which is lower:—
POSITIVE Iron Silver
Zinc Nickel Gold
Cadmium Bismuth Platinum
Tin Antimony Graphite
Lead Copper NEGATIVE
There being no chemical union between the hydrogen and copper in the zinc and copper couple, that gas accumulates on the surface of the copper plate, or is liberated in bubbles. Now, hydrogen is positive compared with copper, hence they tend to oppose each other in the combination. The hydrogen diminishes the value of the copper, the current grows weaker, and the cell is said to "polarise." It follows that a simple water cell is not a good arrangement for the supply of a steady current.
The Daniell cell is one of the best, and gives a very constant current. In this battery the copper plate is surrounded by a solution of sulphate of copper (Cu SO4), which the hydrogen decomposes, forming sulphuric acid (H2SO4), thus taking itself out of the way, and leaving pure copper (Cu) to be deposited as a fresh surface on the copper plate. A further improvement is made in the cell by surrounding the zinc plate with a solution of sulphate of zinc (Zn SO4), which is a good conductor. Now, when the oxide of zinc is formed by the oxygen uniting with the zinc, the free sulphuric acid combines with it, forming more sulphate of zinc, and maintaining the CONDUCTIVITY of the cell. It is only necessary to keep up the supply of zinc, water, and sulphate of copper to procure a steady current of electricity.
The Daniell cell is constructed in various ways. In the earlier models the two plates with their solutions were separated by a porous jar or partition, which allowed the solutions to meet without mixing, and the current to pass. Sawdust moistened with the solutions is sometimes used for this porous separator, for instance, on board ships for laying submarine cables, where the rolling of the waves would blend the liquids.
In the "gravity" Daniell the solutions are kept apart by their specific gravities, yet mingle by slow diffusion. Figure 15 illustrates this common type of cell, where Z is the zinc plate in a solution of sulphate of zinc, and C is the copper plate in a solution of sulphate of copper, fed by crystals of the "blue vitriol." The wires to connect the plates are shown at WW. It should be noticed that the zinc is cast like a wheel to expose a larger surface to oxidation, and to reduce the resistance of the cell, thus increasing the yield of current. The extent of surface is not so important in the case of the copper plate, which is not acted on, and in this case is merely a spiral of wire, helping to keep the solutions apart and the crystals down. The Daniell cell is much employed in telegraphy. The Bunsen cell consists of a zinc plate in sulphuric acid, and at carbon plate in nitric acid, with a porous separator between the liquids. During the action of the cell, hydrogen, which is liberated at the carbon plate, is removed by combining with the nitric acid. The Grove cell is a modification of the Bunsen, with platinum instead of carbon. The Smee cell is a zinc plate side by side with a "platinised" silver plate in dilute sulphuric acid. The silver is coated with rough platinum to increase the surface and help to dislodge the hydrogen as bubbles and keep it from polarising the cell. The Bunsen, Grove, and Smee batteries are, however, more used in the laboratory than elsewhere.
The Leclanche is a fairly constant cell, which requires little attention. It "polarises" in action but soon regains its normal strength when allowed to rest, and hence it is useful for working electric bells and telephones. As shown in figure 16, it consists of a zinc rod with its connecting wire Z, and a carbon plate C with its binding screw, between two cakes M M of a mixture of black oxide of manganese, sulphur, and carbon, plunged in a solution of sal-ammoniac. The oxide of manganese relieves the carbon plate of its hydrogen. The strength of the solution is maintained by spare crystals of sal-ammoniac lying on the bottom of the cell, which is closed to prevent evaporation, but has a venthole for the escape of gas.
The Bichromate of Potash cell polarises more than the Leclanche, but yields a more powerful current for a short time. It consists, as shown in figure 17, of a zinc plate Z between two carbon plates C C immersed in a solution of bichromate of potash, sulphuric acid (vitriol), and water. The zinc is always lifted out of the solution when the cell is not in use. The gas which collects in the carbons, and weakens the cell, can be set free by raising the plates out of the liquid when the cell is not wanted. Stirring the solution has a similar effect, and sometimes the constancy of the cell is maintained by a circulation of the liquid. In Fuller's bichromate cell the zinc is amalgamated with mercury, which is kept in a pool beside it by means of a porous pot.
De la Rue's chloride of silver cell (fig. 18) is, from its constancy and small size, well adapted for medical and testing purposes. The "plates" are a little rod or pencil of zinc Z, and a strip or wire of silver S, coated with chloride of silver and sheathed in parchment paper. They are plunged in a solution of ammonium chloride A, contained in a glass phial or beaker, which is closed to suppress evaporation. A tray form of the cell is also made by laying a sheet of silver foil on the bottom of the shallow jar, and strewing it with dry chloride of silver, on which is laid a jelly to support the zinc plate. The jelly is prepared by mixing a solution of chloride of ammonium with "agar-agar," or Ceylon moss. This type permits the use of larger plates, and adapts the battery for lighting small electric lamps. Skrivanoff has modified the De la Rue cell by substituting a solution of caustic potash for the ammonium chloride, and his battery has been used for "star" lights, that is to say, the tiny electric lamps of the ballet. The Schanschieff battery, consisting of zinc and carbon plates in a solution of basic sulphate of mercury, is suitable for reading, mining, and other portable lamps.