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[12. Aqueous Vapour in relation to the Terrestrial Temperatures.]
We are now fully prepared for a result which, without such preparation, might appear. incredible. Water is, to some extent, a volatile body, and our atmosphere, resting as it does upon the surface of the ocean, receives from it a continual supply of aqueous vapour. It would be an error to confound clouds or fog or any visible mist with the vapour of water, which is a perfectly impalpable gas, diffused, even on the clearest days, throughout the atmosphere. Compared with the great body of the air, the aqueous vapour it contains is of almost infinitesimal amount, 99.5 out of every 100 parts of the atmosphere being composed of oxygen and nitrogen. In the absence of experiment, we should never think of ascribing to this scant and varying constituent any important influence on terrestrial radiation; and yet its influence is far more potent than that of the great body of the air. To say that on a day of average humidity in England, the atmospheric vapour exerts 100 times the action of the air itself, would certainly be an understatement of the fact. Comparing a single molecule of aqueous vapour with an atom of either of the main constituents of our atmosphere, I am not prepared to say how many thousand times the action of the former exceeds that of the latter.
But it must be borne in mind that these large numbers depend, in part, on the extreme feebleness of the air; the power of aqueous vapour seems vast, because that of the air with which it is compared is infinitesimal. Absolutely considered, however, this substance, notwithstanding its small specific gravity, exercises a very potent action. Probably from 10 to 15 per cent. of the heat radiated from the earth is absorbed within 10 or 20 feet of the earth's surface. This must evidently be of the utmost consequence to the life of the world. Imagine the superficial molecules of the earth agitated with the motion of heat, and imparting it to the surrounding aether; this motion would be carried rapidly away, and lost for ever to our planet, if the waves of aether had nothing but the air to contend with in their outward course. But the aqueous vapour takes up the motion, and becomes hereby heated, thus wrapping the earth like a warm garment, and protecting its surface from the deadly chill which it would otherwise sustain. Various philosophers have speculated on the influence of an atmospheric envelope. De Saussure, Fourier, M. Pouillet, and Mr. Hopkins have, one and all, enriched scientific literature with contributions on this subject, but the considerations which these eminent men have applied to atmospheric air, have, if my experiments be correct, to be transferred to the aqueous vapour.
The observations of meteorologists furnish important, though hitherto unconscious evidence of the influence of this agent. Wherever the air is dry we are liable to daily extremes of temperature. By day, such places, the sun's heat reaches the earth unimpeded, and renders the maximum high; by night, on the other hand, the earth's heat escapes unhindered to space, and renders the minimum low. Hence the difference between the maximum and minimum is greatest where the air is driest. In the plains of India, the heights of the Himalaya, in central Asia, in Australia — wherever drought reigns, we have the heat of day forcibly contrasted with the chill of night. In the Sahara itself, when the sun's rays cease to impinge on the burning soil, the temperature runs rapidly down to freezing, because there is no vapour overhead to check the calorific drain. And here another instance might be added to the numbers already known, in which nature tends as it were to check her own excess. By nocturnal refrigeration, the aqueous vapour of the air is condensed to water on the surface of the earth; and, as only the superficial portions radiate, the act of condensation makes water the radiating body. Now experiment proves that to the rays emitted by water, aqueous vapour is especially opaque. Hence the very act of condensation, consequent on terrestrial cooling, becomes a safeguard to the earth, imparting to its radiation that particular character which renders it most liable to be prevented from escaping into space.
It might however be urged that, inasmuch as we derive all our heat from the sun, the selfsame covering which protects the earth from chill must also shut out the solar radiation. This is partially true, but only partially; the sun's rays are different in quality from the earth's rays, and it does not at all follow that the substance which absorbs the one must necessarily absorb the other. Through a layer of water, for example, one tenth of an inch in thickness, the sun's rays are transmitted with comparative freedom; but through a layer half this thickness, as Melloni has proved, no single ray from the warmed earth could pass. In like manner, the sun's rays pass with comparative freedom through the aqueous vapour of the air: the absorbing power of this substance being mainly exerted upon the invisible heat that endeavours to escape from the earth. In consequence of this differential action upon solar and terrestrial heat, the mean temperature of our planet is higher than is due to its distance from the sun.
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[13. Liquids and their Vapours in relation to Radiant Heat.]
The deportment here assigned to atmospheric vapour has been established by direct experiments on it taken from the streets and parks of London, from the downs of Epsom, from the hills and sea-beach of the Isle of Wight, and also by experiments on air in the first instance dried, and afterwards rendered artificially humid by pure distilled water. It has also been established in the following way: Ten volatile liquids were taken at random and the power of these ;liquids, at a common thickness, to intercept the waves of heat, was carefully determined. The vapours of the liquids were next taken, in quantities proportional to the quantities of liquid, and the power of the vapours intercept the waves of heat was also determined.