The great number of volcanoes which have thus become extinct form what are called solfataras. The sulphuretted hydrogen, which is given out through the fissures in the ground, is decomposed by contact with the air, water being formed by the action of the oxygen of the atmosphere, and sulphur deposited in considerable quantities on the walls of the crater, and in the cracks of the ground. Such is the geological source of the sulphur which is collected at Pozzuoli, near Naples, and in many other similar regions—a substance which plays a most important part in the industrial occupations of the world. It is, in fact, from sulphur extracted from the ground about the mouths of extinct volcanoes, that is to say from the products of solfataras, that sulphuric acid is frequently made—sulphuric acid being the fundamental agent, one of the most powerful elements, of the manufacturing productions of both worlds.
The last phase of volcanic activity is the disengagement of carbonic acid gas without any increase of temperature. In places where these continued emanations of carbonic acid gas manifest themselves, the existence of ancient volcanoes may be recognised, of which these discharges are the closing phenomenon. This is seen in a most remarkable manner in Auvergne, where there are a multitude of acidulated springs, that is to say, springs charged with carbonic acid. During the time when he was opening the mines of Pontgibaud, M. Fournet had to contend with emanations which sometimes exhibited themselves with explosive power. Jets of water were thrown to great heights in the galleries, roaring with the noise of steam when escaping from the boiler of a locomotive engine. The water which filled an abandoned mine-shaft was, on two separate occasions, upheaved with great violence—half emptying the pit—while vast volumes of the gas overspread the whole valley, suffocating a horse and a flock of geese. The miners were compelled to fly in all haste at the moment when the gas burst forth, holding themselves as upright as possible, to avoid plunging their heads into the carbonic acid gas, which, from its low specific gravity, was now filling the lower parts of the galleries. It represented on a small scale the effect of the Grotto del Cane, which excites such surprise among the ignorant near Naples; passing, also, for one of the marvels of Nature all over the world. M. Fournet states that all the minute fissures of the metalliferous gneiss near Clermont are quite saturated with free carbonic acid gas, which rises plentifully from the soil there, as well as in many parts of the surrounding country. The components of the gneiss, with the exception of the quartz, are softened by it; and fresh combinations of the acid with lime, iron, and manganese are continually taking place. In short, long after volcanoes have become extinct, hot springs, charged with mineral ingredients, continue to flow in the same area.
The same facts as those of the Grotto del Cane manifest themselves with even greater intensity in Java, in the so-called Valley of Poison, which is an object of terror to the natives. In this celebrated valley the ground is said to be covered with skeletons and carcases of tigers, goats, stags, birds, and even of human beings; for asphyxia or suffocation, it seems, strikes all living things which venture into this desolate place. In the same island a stream of sulphurous water, as white as milk, issues from the crater of Mount Idienne, on the east coast; and on one occasion, as cited by Nozet in the Journal de Géologie, a great body of hot water, charged with sulphuric acid, was discharged from the same volcano, inundating and destroying all the vegetation of a large tract of country by its noxious fumes and poisonous properties.
V.—Great Geyser of Iceland.
It is known that the alkaline waters of Plombières, in the Vosges, have a temperature of 160° Fahr. For 2,000 years, according to Daubrée, through beds of concrete, of lime, brick, and sandstone, these hot waters have percolated until they have originated calcareous spar, aragonite, and fluor spar, together with siliceous minerals, such as opal, which are found filling the interstices of the bricks and mortar. From these and other similar statements, “we are led,” says Sir Charles Lyell,[26] “to infer that when in the bowels of the earth there are large volumes of molten matter, containing heated water and various acids, under enormous pressure, these subterraneous fluid masses will gradually part with their heat by the escape of steam and various gases through fissures producing hot springs, or by the passage of the same through the pores of the overlying and injected rocks.” “Although,” he adds,[27] “we can only study the phenomena as exhibited at the surface, it is clear that the gaseous fluids must have made their way through the whole thickness of the porous or fissured rocks, which intervene between the subterraneous reservoirs of gas and the external air. The extent, therefore, of the earth’s crust which the vapours have permeated, and are now permeating, may be thousands of fathoms in thickness, and their heating and modifying influence may be spread throughout the whole of this solid mass.”
The fountains of boiling water, known under the name of Geysers, are another emanation connected with ancient craters. They are either continuous or intermittent. In Iceland we find great numbers of these gushing springs—in fact, the island is one entire mass of eruptive rock. Nearly all the volcanoes are situated upon a broad band of trachyte, which traverses the island from south-west to north-east. It is traversed by immense fissures, and covered with masses of lava, such as no other country presents. The volcanic action, in short, goes on with such energy that certain paroxysms of Mount Hecla have lasted for six years without interruption. But the Great Geyser, represented on the opposite page ([Plate V.]), is, perhaps, even more an object of curiosity. This water-volcano projects a column of boiling water, eight yards in diameter, charged with silica, to the height, it has been said, of about 150 feet, depositing vast quantities of silica as it cools after reaching the earth.