If the gas thus ionised be left to itself, in the absence of any electric field, the ions, yielding to their mutual attraction, must finally meet, combine, and reconstitute a neutral molecule, thus returning to their initial condition. The gas in a short while loses the conductivity which it had acquired; or this is, at least, the phenomenon at ordinary temperatures. But if the temperature is raised, the relative speeds of the ions at the moment of impact may be great enough to render it impossible for the recombination to be produced in its entirety, and part of the conductivity will remain.
Every element of volume rendered a conductor therefore furnishes, in an electric field, equal quantities of positive and negative electricity. If we admit, as mentioned above, that these liberated quantities are borne by ions each bearing an equal charge, the number of these ions will be proportional to the quantity of electricity, and instead of speaking of a quantity of electricity, we could use the equivalent term of number of ions. For the excitement produced by a given pencil of X rays, the number of ions liberated will be fixed. Thus, from a given volume of gas there can only be extracted an equally determinate quantity of electricity.
The conductivity produced is not governed by Ohm's law. The intensity is not proportional to the electromotive force, and it increases at first as the electromotive force augments; but it approaches asymptotically to a maximum value which corresponds to the number of ions liberated, and can therefore serve as a measure of the power of the excitement. It is this current which is termed the current of saturation.
M. Righi has ably demonstrated that ionised gas does not obey the law of Ohm by an experiment very paradoxical in appearance. He found that, the greater the distance of the two electrode plates from each, the greater may be, within certain limits, the intensity of the current. The fact is very clearly interpreted by the theory of ionisation, since the greater the length of the gaseous column the greater must be the number of ions liberated.
One of the most striking characteristics of ionised gases is that of discharging electrified conductors. This phenomenon is not produced by the departure of the charge that these conductors may possess, but by the advent of opposite charges brought to them by ions which obey the electrostatic attraction and abandon their own electrification when they come in contact with these conductors.
This mode of regarding the phenomena is extremely convenient and eminently suggestive. It may, no doubt, be thought that the image of the ions is not identical with objective reality, but we are compelled to acknowledge that it represents with absolute faithfulness all the details of the phenomena.
Other facts, moreover, will give to this hypothesis a still greater value; we shall even be able, so to speak, to grasp these ions individually, to count them, and to measure their charge.
§ 2. THE CONDENSATION OF WATER-VAPOUR BY IONS
If the pressure of a vapour—that of water, for instance—in the atmosphere reaches the value of the maximum pressure corresponding to the temperature of the experiment, the elementary theory teaches us that the slightest decrease in temperature will induce a condensation; that small drops will form, and the mist will turn into rain.
In reality, matters do not occur in so simple a manner. A more or less considerable delay may take place, and the vapour will remain supersaturated. We easily discover that this phenomenon is due to the intervention of capillary action. On a drop of liquid a surface-tension takes effect which gives rise to a pressure which becomes greater the smaller the diameter of the drop.