Pressure facilitates evaporation, and on more closely examining this reaction we arrive at the conclusion that vapour can never spontaneously condense itself when liquid drops already formed are not present, unless forces of another nature intervene to diminish the effect of the capillary forces. In the most frequent cases, these forces come from the dust which is always in suspension in the air, or which exists in any recipient. Grains of dust act by reason of their hygrometrical power, and form germs round which drops presently form. It is possible to make use, as did M. Coulier as early as 1875, of this phenomenon to carry off the germs of condensation, by producing by expansion in a bottle containing a little water a preliminary mist which purifies the air. In subsequent experiments it will be found almost impossible to produce further condensation of vapour.
But these forces may also be of electrical origin. Von Helmholtz long since showed that electricity exercises an influence on the condensation of the vapour of water, and Mr C.T.R. Wilson, with this view, has made truly quantitative experiments. It was rapidly discovered after the apparition of the X rays that gases that have become conductors, that is, ionised gases, also facilitate the condensation of supersaturated water vapour.
We are thus led by a new road to the belief that electrified centres exist in gases, and that each centre draws to itself the neighbouring molecules of water, as an electrified rod of resin does the light bodies around it. There is produced in this manner round each ion an assemblage of molecules of water which constitute a germ capable of causing the formation of a drop of water out of the condensation of excess vapour in the ambient air. As might be expected, the drops are electrified, and take to themselves the charge of the centres round which they are formed; moreover, as many drops are created as there are ions. Thereafter we have only to count these drops to ascertain the number of ions which existed in the gaseous mass.
To effect this counting, several methods have been used, differing in principle but leading to similar results. It is possible, as Mr C.T.R. Wilson and Professor J.J. Thomson have done, to estimate, on the one hand, the weight of the mist which is produced in determined conditions, and on the other, the average weight of the drops, according to the formula formerly given by Sir G. Stokes, by deducting their diameter from the speed with which this mist falls; or we can, with Professor Lemme, determine the average radius of the drops by an optical process, viz. by measuring the diameter of the first diffraction ring produced when looking through the mist at a point of light.
We thus get to a very high number. There are, for instance, some twenty million ions per centimetre cube when the rays have produced their maximum effect, but high as this figure is, it is still very small compared with the total number of molecules. All conclusions drawn from kinetic theory lead us to think that in the same space there must exist, by the side of a molecule divided into two ions, a thousand millions remaining in a neutral state and intact.
Mr C.T.R. Wilson has remarked that the positive and negative ions do not produce condensation with the same facility. The ions of a contrary sign may be almost completely separated by placing the ionised gas in a suitably disposed field. In the neighbourhood of a negative disk there remain hardly any but positive ions, and against a positive disk none but negative; and in effecting a separation of this kind, it will be noticed that condensation by negative ions is easier than by the positive.
It is, consequently, possible to cause condensation on negative centres only, and to study separately the phenomena produced by the two kinds of ions. It can thus be verified that they really bear charges equal in absolute value, and these charges can even be estimated, since we already know the number of drops. This estimate can be made, for example, by comparing the speed of the fall of a mist in fields of different values, or, as did J.J. Thomson, by measuring the total quantity of electricity liberated throughout the gas.
At the degree of approximation which such experiments imply, we find that the charge of a drop, and consequently the charge borne by an ion, is sensibly 3.4 x 10-10 electrostatic or 1.1 x 10-20 electromagnetic units. This charge is very near that which the study of the phenomena of ordinary electrolysis leads us to attribute to a univalent atom produced by electrolytic dissociation.
Such a coincidence is evidently very striking; but it will not be the only one, for whatever phenomenon be studied it will always appear that the smallest charge we can conceive as isolated is that mentioned. We are, in fact, in presence of a natural unit, or, if you will, of an atom of electricity.
We must, however, guard against the belief that the gaseous ion is identical with the electrolytic ion. Sensible differences between those are immediately apparent, and still greater ones will be discovered on closer examination.