Experiments and Considerations Touching Colours (1664)

by Robert Boyle

drops of good Oyl of Tartar, per Deliquium; well Filtred that it may likewise be without Colour, these two Limpid Liquors will in the twinkling of an Eye turn into an Opacous mixture of a deep Orange Colour, which by keeping the Glass continually shaking in your hand, you must preserve from setling too soon to the Bottom; And when the Spectators have a little beheld this first Change, then you must presently drop in about four or five drops of Oyl of Vitriol, and continuing to shake the Glass pretty strongly, that it may the Nimbler diffuse it self, the whole Colour, if you have gone Skilfully to work, will immediately disappear, and all the Liquor in the Glass will be Clear and Colourless as before, without so much as a Sediment at the Bottom. But for the more gracefull Trial of this Experiment, 'twill not be amiss to observe, First, That there should not be taken too much of the Solution of Sublimate, nor too much of the Oyl of Tartar drop'd in, to avoid the necessity of putting in so much Oyl of Vitriol as may make an Ebullition, and perhaps run over the Glass. Secondly, That 'tis convenient to keep the Glass always a little shaking, both for the better mixing of the Liquors, and to keep the Yellow Substance from Subsiding, which

else it would in a short time do, though when 'tis subsided it will retain its Colour, and also be capable of being depriv'd of it by the Oyl newly mention'd. Thirdly, That if any Yellow matter stick at the sides of the Glass, 'tis but inclining the Glass, till the clarify'd Liquor can wash alongst it, and the Liquor will presently imbibe it, and deprive it of its Colour.

Many have somewhat wondred, how I came to light upon this Experiment, but the Notions or Conjectures I have about the differing Natures of the Several Tribes of Salts, having led me to devise the Experiment, it will not be difficult for me to give you the Chymical Reason, if I may so speak, of the Phænomenon. Having then observ'd, that Mercury being dissolv'd in Some Menstruums, would yield a dark Yellow Precipitate, and supposing that, as to this, common Water, and the Salts that stick to the Mercury would be equivalent to those Acid Menstruums, which work upon the Quick-silver, upon the account of their Saline particles, I substituted a Solution of Sublimate in fair Water, instead of a Solution of Mercury in Aqua-fortis, or Spirit of Nitre, that simple Solution being both clearer and free from that very offensive Smell, which accompanies the Solutions

of Mercury made with those other corrosive Liquors; then I consider'd, that That, which makes the Yellow Colour, is indeed but a Precipitate made by the means of the Oyl of Tartar, which we drop in, and which, as Chymists know, does generally precipitate Metalline Bodies corroded by Acid Salts; so that the Colour in our case results from the Coalition of the Mercurial particles with the Saline ones, wherewith they were formerly associated, and with the Alcalizate particles of the Salt of Tartar that swim up and down in the Oyl. Wherefore considering also, that very many of the effects of Lixiviate Liquors, upon the Solutions of other Bodies, may be destroy'd by Acid Menstruums, as I elsewhere more particularly declare, I concluded, that if I chose a very potently Acid Liquor, which by its Incisive power might undo the work of the Oyl of Tartar, and disperse again those Particles, which the other had by Precipitation associated, into such minute Corpuscles as were before singly Inconspicuous, they would become Inconspicuous again, and consequently leave the Liquor as Colourless as before the Precipitation was made.

This, as I said, Pyrophilus, seems to be the Chymical reason of this Experiment, that

is such a reason, as, supposing the truth of those Chymical Notions I have elsewhere I hope evinc'd, may give such an account of the Phænomena as Chymical Notions can supply us with; but I both here and elsewhere make use of this way of speaking, to intimate that I am sufficiently aware of the difference betwixt a Chymical Explication of a Phænomenon, and one that is truly Philosophical or Mechanical; as in our present case, I tell you something, when I tell you that the Yellowness of the Mercurial Solution and the Oyl of Tartar is produc'd by the Precipitation occasion'd by the affusion of the latter of those Liquors, and that the destruction of the Colour proceeds from the Dissipation of that Curdl'd matter, whose Texture is destroy'd, and which is dissolv'd into Minute and Invisible particles by the potently Acid Menstruum, which is the reason, why there remains no Sediment in the Bottom, because the infused Oyl takes it up, and resolves it into hidden or invisible Parts, as Water does Salt or Sugar. But when I have told you all this, I am far from thinking I have told all that such an Inquisitive Person as your self would know, for I presume you would desire as well as I to learn (at least) why the Particles of the

Mercury, of the Tartar, and of the Acid Salts convening together, should make rather an Orange Colour than a Red, or a Blew, or a Green, for 'tis not enough to say what I related a little before, that divers Mercurial Solutions, though otherwise made, would yield a Yellow precipitate, because the Question will recurr concerning them; and to give it a satisfactory answer, is, I freely acknowledge, more than I dare as yet pretend to.

But to confirm my conjecture about the Chymical reason of our Experiment, I may add, that as I have (viz. pag. 34^th. of this Treatise) elsewhere (on another occasion) told you, with Saline Liquors of another kind and nature than Salt of Tartar, (namely, with Spirit of Urine, and Liquors of kin to that) I can make the Mercury precipitate out of the first simple Solution quite of another Colour than that hitherto mention'd; Nay, if instead of altering the Precipitating liquor, I alter'd the Texture of the Sublimate in such a way as my Notions about Salt requir'd, I could produce the same Phænomenon. For having purposely Sublim'd together Equal parts (or thereabout) of Sal-Armoniack and Sublimate, first diligently Mix'd, the ascending Flowers being diffolv'd in fair Water,

and Filtred, gave a Solution Limpid and Colourless, like that of the other Sublimates, and yet an Akaly drop'd into this Liquor did not turn it Yellow but White. And upon the same Grounds we may with Quick-silver, without the help of common Sublimate, prepare another sort of Flowers dissoluble in Water without Discolouring it, with which I could likewise do what I newly mention'd; to which I shall add, (what possibly you'l somewhat wonder at) That so much does the Colour depend upon the Texture resulting from the Convention of the several sorts of Corpuscles, that though in out Experiment, Oyl of Vitriol destroys the Yellow Colour, yet with Quick-silver and fair Water, by the help of Oyl of Vitriol alone, we may easily make a kind of Precipitate of a fair and permanent Yellow, as you will e're long (in the forty second Expement of this third Part) be taught. And I may further add, that I chose Oyl of Vitriol, not so much for any other or peculiar Quality, as for its being, when 'tis well rectify'd, (which 'tis somewhat hazardous to bring it to be) not only devoid of Colour and in Smells, but extremely Strong and Incisive; For though common and undephlegmated Aqua-fortis will not perform

the same thing well, yet that which is made exceeding Strong by being carefully Dephlegm'd, will do it pretty well, though not so well as Oyl of Vitriol which is so Strong, that even without Rectification it may for a need be made use of. I will not here tell you what I have try'd, that I may be able to deprive at pleasure the Precipitate that one of the Sulphureous Liquors had made, by the copious Affusion of the other: Because I found, though this Experiment is too ticklish to let me give a full account of it in few words, I shall therefore tell you, that it is not only for once, that the other above-mention'd Experiment may be made, the same Numerical parcels of Liquor being still imploy'd in it; for after I have Clarify'd the Orange Colour'd Liquor, by the addition of as little of the Oyl of Viriol as will suffice to perform the effect, I can again at pleasure re-produce the Opacous Colour, by the dropping in of fresh Oyl of Tartar, and destroy it again by the Re-affusion of more of the Acid Menstruum; and yet oftner if I please, can I with these two contrariant Liquors recall and disperse the Colour, though by reason of the addition of so much new Liquor, in reference to the Mercurial particles, the Colour will at length appear more dilute and faint.