An improvement of the fortieth Experiment.
And, Pyrophilus, to confirm yet further the Notions that led me to think on the propos'd Experiment, I shall acquaint you with another, which when I had conveniency I have sometimes added to it, and which has to the Spectators appear'd little less Odd than the first; And though because the Liquor, requisite to make the Trial succeed well, must be on purpose prepar'd anew a while before, because it will not long retain its fitness for this work, I do but seldome annex this Experiment to the other, yet I shall tell you how I devis'd it, and how I make it. If you boyl Crude Antimony in a strong and clear Lixivium, you shall separate a Substance from it, which some Modern Chymists are pleas'd to call its Sulphur, but how deservedly I shall not here examine, having elsewhere done it in an Opportune place; wherefore I shall now but need to take notice, that when this suppos'd Sulphur (not now to call it rather a kind of Crocus) is let fall by the Liquor upon its Refrigeration, it often settles in Flakes, or such like parcels of a Yellow Substance, (which being by the precedent
dissolution reduc'd into Minute parts, may peradventure be made to take Fire much more easily than the Grosser Powder of unprepar'd Antimony would have done.) Considering therefore, that common Sulphur boyl'd in a Lixivium may be Precipitated out of it by Rhenish-wine or White-wine, which are Sowrish Liquors, and have in them, as I elsewhere shew, an Acid Salt; and having found also by Trial, that with other Acid Liquors I could Precipitate out of Lixiviate Solvents some other Mineral concretions abounding with Sulphureous parts, of which sort is crude Antimony, I concluded it to be easie to Precipitate the Antimony dissolv'd, as was lately mention'd, with the Acid Oyl of Vitriol; and though common Sulphur yields a White Precipitate, which the Chymists call Lac Sulphuris, yet I suppos'd the Precipitated Antimony would be of a deep Yellow Colour, as well, if made with Oyl of Vitriol, as if made only by Refrigeration and length of Time. From this 'twas easie to deduce this Experiment, that if you put into one Glass some of the freshly Impregnated and Filtrated Solution of Antimony, and into another some of the Orange-Colour'd Mixture, (which I formerly shew'd you how to make with a
Mercurial Solution and Oyl of Tartar) a few drops of Oyl of Vitriol dropp'd into the last mention'd Glass, would, as I told you before, turn the Deep Yellow mixture into a Cleer Liquor; whereas a little of the same Oyl dropp'd out of the same Viol into the other Glass would presently (but not without some ill sent) turn the moderately cleer Solution into a Deep Yellow Substance, But this, as I Said, succeeds not well, unless you employ a Lixivium that has but newly dissolv'd Antimony, and has not yet let it fall. But yet in Summer time, if your Lixivium have been duly Impregnated and well Filtred after it is quite cold, it will for some dayes (perhaps much longer than I had occasion to try) retain Antimony enough to exhibit, upon the Affusion of the Corrosive Oyl, as much of a good Yellow Substance as is necessary to satisfie the Beholders of the Possibility of the Experiment.
Reflections upon the XL. Experiment Compared with the X. and XX.
The Knowledge of the Distinction of Salts which we have propos'd, whereby they are discriminated into Acid, Volatile,
or Salfuginous (if I may for Distinction sake so call the Fugitive Salts of Animal Substances) and fix'd or Alcalizate, may possibly (by that little part which we have already deliver'd, of what we could say of its Applicableness) appear of so much Use in Natural Philosophy (especially in the Practick part of it) that I doubt not but it will be no Unwelcome Corollary of the Preceding Experiment, if by the help of it I teach you to distinguish, which of those Salts is Predominant in Chymical Liquors, as well as whether any of them be so or not. For though in our Notes upon the X. and XX. Experiments I have shown you a way by means of the Tincture of Lignum Nephriticum, or of Syrrup of Violets, to discover whether a propounded Salt be Acid or not, yet you can thereby only find in general that such and such Salts belong not to the Tribe of Acids, but cannot determine whether they belong to the Tribe of Urinous Salts (under which for distinction sake I comprehend all those Volatile Salts of Animal or other Substances that are contrary to Acids) or to that of Alcalies. For as well the one as the other of these Salino-Sulphurous Salts will restore the Cæruleous Colour to the Tincture of Lignum Nephriticum, and turn that of Syrrup of Violets
into Green. Wherefore this XL. Experiment does opportunely supply the deficiency of those. For being sollicitous to find out some ready wayes of discriminating the Tribes of Chymical Salts, I found that all those I thought fit to make Tryal of, would, if they were of a Lixiviate Nature, make with Sublimate dissolv'd in Fair Water an Orange Tawny Precipitate; whereas if they were of an Urinous Nature the Precipitate would be White and Milky. So that having alwayes by me some Syrrup of Violets and some Solution of Sublimate, I can by the help of the first of those Liquors discover in a trice, whether the propounded Salt or Saline Body be of an Acid Nature or no, if it be I need (you know) inquire no further; but if it be not, I can very easily, and as readily distinguish between the other two kinds of Salts, by the White or Orange-Colour that is immediately produc'd, by letting fall a few Drops or Grains of the Salt to be examin'd, into a spoonfull of the cleer Solution of Sublimate. For Example, it has been suppos'd by some eminently Learned, That when Sal Armoniack being mingled with an Alcaly is forc'd from it by the Fire in close Vessels, the Volatile Salt that will thereby be obtain'd (if the Operation be skilfully perform'd,)
is but a more fine and subtile sort of Sal Armoniack, which, 'tis presum'd, this Operation do's but more exquisitely purifie, than common Solutions, Filtrations, and Coagulations. But this Opinion may be easily shown to be Erroneous, as by other Arguments, so particularly by the lately deliver'd Method of distinguishing the Tribes of Salts. For the Saline Spirit of Sal Armoniack, as it is in many other manifest Qualities very like the Spirit of Urine, so like, that it will in a trice make Syrrup of Violets of a Lovely Green, turn a Solution of good Verdigrease into an Excellent Azure, and make the Solution of a Sublimate yield a White Precipitate, insomuch that in most (for I say not all of the Experiments) where I Aim onely at producing a sudden change of Colour, I scruple not to use Spirit of Sal Armoniack when it is at hand, instead of Spirit of Urine, as indeed it seems chiefly to consist (besides the flegm that helps to make it fluid) of the Volatile Urinous Salt (yet not excluding that of Soot) that abounds in the Sal Armoniack and is set at liberty from the Sea Salt wherewith it was formerly associated, and clogg'd, by the Operation of the Alcaly, that divides the Ingredients of Sal Armoniack, and retains that Sea Salt with it self. What use may be