Nor is this kind of Grain, as I may call it, peculiar to Glass drops thus quenched; for (not to mention Coperas-stones, and divers other Marchasites and Minerals, which I have often taken notice of to be in the very same manner flaked or grained, with a kind of Pith in the middle) I have observed the same in all manner of cast Iron, especially the coarser sort, such as Stoves, and Furnaces, and Backs, and Pots are made of: For upon the breaking of any of those Substances it is obvious to observe, how from the out-sides towards the middle, there is a kind of Radiation or Grain much resembling this of the Glass-drop; but this Grain is most conspicuous in Iron-bullets, if they be broken: the same Phænomena may be produced by casting regulus of Antimony into a Bullet-mold, as also with Glass of Antimony, or with almost any such kind of Vitrified substance, either cast into a cold Mold or poured into Water.
Others of these Drops I heat red hot in the fire, and then suffered them to cool by degrees. And these I found to have quite lost all their fulminating or flying quality, as also their hard, brittle and springy texture; and to emerge of a much softer temper, and much easier to be broken or snapt with ones finger; but its strong and brittle quality was quite destroyed, and it seemed much of the same consistence with other green Glass well nealed in the Oven.
The Figure and bigness of these for the most part was the same with that of the Figure Z; that is, all the surface of them was very smooth and polisht, and for the most part round, but very rugged or knobbed about D, and all the length of the stem was here and there pitted or flatted. About D, which is at the upper part of the drop under that side of the stem which is concave, there usually was made some one or more little Hillocks or Prominences. The drop it self, before it be broken, appears very transparent, and towards the middle of it, to be very full of small Bubbles, of some kind of aerial substance, which by the refraction of the outward surface appear much bigger then really they are; and this may be in good part removed, by putting the drop under the surface of clear Water, for by that means most part of the refraction of the convex Surface of the drop is destroyed, and the bubbles will appear much smaller. And this, by the by, minds me of the appearing magnitude of the aperture of the iris, or pupil of the eye, which though it appear, and be therefore judged very large, is yet not above a quarter of the bigness it appears of, by the lenticular refraction of the Cornea.
The cause of all which Phænomena I imagine to be no other then this, That the Parts of the Glass being by the excessive heat of the fire kept off and separated one from another, and thereby put into a kind of sluggish fluid Consistence, are suffered to drop off with that heat or agitation remaining in them, into cold Water; by which means the outsides of the drop are presently cool’d and crusted, and are thereby made of a loose texture, because the parts of it have not time to settle themselves leisurely together, and so to lie very close together: And the innermost parts of the drop, retaining still much of their former heat and agitations, remain of a loose texture also, and, according as the cold strikes inwards from the bottom and sides, are quenched, as it were, and made rigid in that very posture wherein the cold finds them. For the parts of the crust being already hardened, will not suffer the parts to shrink any more from the outward Surface inward; and though it shrink a little by reason of the small parcels of some Aerial substances dispersed through the matter of the Glass, yet that is not neer so much as it appears (as I just now hinted;) nor if it were, would it be sufficient for to consolidate and condense the body of Glass into a tuff and close texture, after it had been so excessively rarified by the heat of the glass-Furnace.
But that there may be such an expansion of the aerial substance contained in those little blebbs or bubbles in the body of the drop, this following Experiment will make more evident.
Take a small Glass-Cane about a foot long, seal up one end of it hermetically, then put in a very small bubble of Glass, almost of the shape of an Essence-viol with the open mouth towards the sealed end, then draw out the other end of the Pipe very small, and fill the whole Cylinder with water, then set this Tube by the Fire till the Water begin to boyl, and the Air in the bubble be in good part rarified and driven out, then by sucking at the smalling Pipe, more of the Air or vapours in the bubble may be suck’d out, so that it may sink to the bottom; when it is sunk to the bottom, in the flame of a Candle, or Lamp, nip up the slender Pipe and let it cool: whereupon it is obvious to observe, first, that the Water by degrees will subside and shrink into much less room: Next, that the Air or vapours in the Glass will expand themselves so, as to buoy up the little Glass: Thirdly, that all about the inside of the Glass-pipe there will appear an infinite number of small bubbles, which as the Water grows colder and colder will swell bigger and bigger, and many of them buoy themselves up and break at the top.
From this Disceding of the heat in Glass drops, that is, by the quenching or cooling Irradiations propagated from the Surface upwards and inwards, by the lines CT, CT, DT, DE, &c. the bubbles in the drop have room to expand themselves a little, and the parts of the Glass contract themselves; but this operation being too quick for the sluggish parts of the Glass, the contraction is performed very unequally and irregularly, and thereby the Particles of the Glass are bent, some one way, and some another, yet so as that most of them draw towards the Pith or middle TEEE, or rather from that outward: so that they cannot extricate or unbend themselves, till some part of TEEE be broken and loosened, for all the parts about that are placed in the manner of an Arch, and so till their hold at TEEE be loosened they cannot fly asunder, but uphold, and shelter, and fix each other much like the stones in a Vault, where each stone does concurre to the stability of the whole Fabrick, and no one stone can be taken away but the whole Arch falls. And wheresoever any of those radiating wedges DTD, &c. are removed, which are the component parts of this Arch, the whole Fabrick presently falls to pieces; for all the Springs of the several parts are set at liberty, which immediately extricate themselves and fly asunder every way; each part by its spring contributing to the darting of it self and some other contiguous part. But if this drop be heat so hot as that the parts by degrees can unbend themselves, and be settled and annealed in that posture, and be then suffered gently to subside and cool; The parts by this nealing losing their springiness, constitute a drop of a more soft but less brittle texture, and the parts being not at all under a flexure, though any part of the middle or Pith TEEE be broken, yet will not the drop at all fly to pieces as before.
This Conjecture of mine I shall indeavour to make out by explaining each particular Assertion with analogous Experiments: The Assertions are these.
First, That the parts of the Glass, whilst in a fluid Consistence and hot, are more rarified, or take up more room, then when hard and cold.
Secondly, That the parts of the drop do suffer a two-fold contraction.
Thirdly, That the dropping or quenching the glowing metal in the Water makes it of a hard, springing, and rarified texture.
Fourthly, That there is a flexion or force remaining upon the parts of the Glass thus quenched, from which they indeavour to extricate themselves.
Fifthly, That the Fabrick of the drop, that is able to hinder the parts from extricating themselves, is analogus to that of an Arch.
Sixthly, That the sudden flying asunder of the parts proceeds from their springiness.
Seventhly, That a gradual heating and cooling does anneal or reduce the parts of Glass to a texture that is more loose, and easilier to be broken, but not so brittle.