That the first of these is true may be gathered from this, That Heat is a property of a body arising from the motion or agitation of its parts; and therefore whatever body is thereby toucht must necessarily receive some part of that motion, whereby its parts will be shaken and agitated, and so by degrees free and extricate themselves from one another, and each part so moved does by that motion exert a conatus of protruding and displacing all the adjacent Particles. Thus Air included in a vessel, by being heated will burst it to pieces. Thus have I broke a Bladder held over the fire in my hand, with such a violence and noise, that it almost made me deaf for the present, and much surpassed the noise of a Musket: The like have I done by throwing into the fire small glass Bubbles hermetically sealed, with a little drop of Water included in them. Thus Water also, or any other Liquor, included in a convenient vessel, by being warmed, manifestly expands it self with a very great violence, so as to break the strongest vessel, if when heated it be narrowly imprisoned in it. This is very manifest by the Sealed Thermometers, which I have, by several tryals, at last brought to a great certainty and tenderness: for I have made some with stems above four foot long, in which the expanding Liquor would so far vary, as to be very neer the very top in the heat of Summer, and prety neer the bottom at the coldest time of the Winter. The Stems I use for them are very thick, straight, and even Pipes of Glass, with a very small perforation, and both the head and body I have made on purpose at the Glass-house, of the same metal whereof the Pipes are drawn: these I can easily in the flame of a Lamp, urged with the blast of a pair of Bellows, seal and close together, so as to remain very firm, close and even; by this means I joyn on the body first, and then fill both it and a part of the stem, proportionate to the length of the stem and the warmth of the season I fill it in with the best rectified Spirit of Wine highly ting’d with the lovely colour of Cocheneel, which I deepen the more by pouring some drops of common Spirit of Urine, which must not be too well rectified, because it will be apt to make the Liquor to curdle and stick in the small perforation of the stem. This Liquor I have upon tryal found the most tender of any spirituous Liquor, and those are much more sensibly affected with the variations of heat and cold then other more flegmatick and ponderous Liquors, and as capable of receiving a deep tincture, and keeping it, as any Liquor whatsoever; and (which makes it yet more acceptable) is not subject to be frozen by any cold yet known. When I have thus filled it, I can very easily in the forementioned flame of a Lamp seal and joyn on the head of it.
Then, for graduating the stem, I fix that for the beginning of my division where the surface of the liquor in the stem remains when the ball is placed in common distilled water, that is so cold that it just begins to freeze and shoot into flakes; and that mark I fix at a convenient place of the stem, to make it capable of exhibiting very many degrees of cold, below that which is requisite to freeze water: the rest of my divisions, both above and below this (which I mark with a [0] or nought) I place according to the Degrees of Expansion, or Contraction of the Liquor in proportion to the bulk it had when it indur’d the newly mention’d freezing cold. And this may be very easily and accurately enough done by this following way; Prepare a Cylindrical vessel of very thin plate Brass or Silver, ABCD of the figure Z; the Diameter AB of whose cavity let be about two inches, and the depth BC the same; let each end be cover’d with a flat and smooth plate of the same substance, closely soder’d on, and in the midst of the upper cover make a pretty large hole EF, about the bigness of a fifth part of the Diameter of the other; into this fasten very well with cement a straight and even Cylindrical pipe of Glass, EFGH, the Diameter of whose cavity let be exactly one tenth of the Diameter of the greater Cylinder. Let this pipe be mark’d at GH with a Diamant, so that G from E may be distant just two inches, or the same height with that of the cavity of the greater Cylinder, then divide the length EG exactly into 10 parts, so the capacity of the hollow of each of these divisions will be ¹⁄₁₀₀₀ part of the capacity of the greater Cylinder. This vessel being thus prepared, the way of marking and graduating the Thermometers may be very easily thus performed:
Fill this Cylindrical vessel with the same liquor wherewith the Thermometers are fill’d, then place both it and the Thermometer you are to graduate, in water that is ready to be frozen, and bring the surface of the liquor in the Thermometer to the first marke or [0]; then so proportion the liquor in the Cylindrical vessel, that the surface of it may just be at the lower end of the small glass-Cylinder; then very gently and gradually warm the water in which both the Thermometer and this Cylindrical vessel stand, and as you perceive the ting’d liquor to rise in both stems, with the point of a Diamond give several marks on the stem of the Thermometer at those places, which by comparing the expansion in both Stems, are found to correspond to the divisions of the cylindrical vessel, and having by this means marked some few of these divisions on the Stem, it will be very easie by these to mark all the rest of the Stem, and accordingly to assign to every division a proper character.
A Thermometer, thus marked and prepared, will be the fittest Instrument to make a Standard of heat and cold that can be imagined. For being sealed up, it is not at all subject to variation or wasting, nor is it liable to be changed by the varying pressure of the Air, which all other kind of Thermometers that are open to the Air are liable to. But to proceed.
This property of Expansion with Heat, and Contraction with Cold, is not peculiar to Liquors only, but to all kind of solid Bodies also, especially Metals, which will more manifestly appear by this Experiment.
Take the Barrel of a Stopcock of Brass, and let the Key, which is well fitted to it, be riveted into it, so that it may slip, and be easily turned round, then heat this Cock in the fire, and you will find the Key so swollen, that you will not be able to turn it round in the Barrel; but if it be suffered to cool again, as soon as it is cold it will be as movable, and as easie to be turned as before.
This Quality is also very observable in Lead, Tin, Silver, Antimony, Pitch, Rosin, Bees-wax, Butter, and the like; all which, if after they be melted you suffer gently to cool, you shall find the parts of the upper Surface to subside and fall inwards, losing that plumpness and smoothness it had whilst in fusion. The like I have also observed in the cooling of Glass of Antimony, which does very neer approach the nature of Glass,
But because these are all Examples taken from other materials then Glass, and argue only, that possibly there may be the like property also in Glass, not that really there is; we shall by three or four Experiments indeavour to manifest that also.
And the First is an Observation that is very obvious even in these very drops, to wit, that they are all of them terminated with an unequal or irregular Surface, especially about the smaller part of the drop, and the whole length of the stem; as about D, and from thence to A, the whole Surface, which would have been round if the drop had cool’d leisurely, is, by being quenched hastily, very irregularly flatted and pitted; which I suppose proceeds partly from the Waters unequally cooling and pressing the parts of the drop, and partly from the self-contracting or subsiding quality of the substance of the Glass: For the vehemency of the heat of the drop causes such hidden motions and bubbles in the cold Water, that some parts of the Water bear more forcibly against one part then against another, and consequently do more suddenly cool those parts to which they are contiguous.
A Second Argument may be drawn from the Experiment of cutting Glasses with a hot Iron. For in that Experiment the top of the Iron heats, and thereby rarifies the parts of the Glass that lie just before the crack, whence each of those agitated parts indeavouring to expand its self and get elbow-room, thrusts off all the rest of the contiguous parts, and consequently promotes the crack that was before begun.