A Third Argument may be drawn from the way of producing a crack in a sound piece or plate of Glass, which is done two wayes, either First, by suddenly heating a piece of Glass in one place more then in another. And by this means chymists usually cut off the necks of Glass-bodies, by two kinds of Instruments, either by a glowing hot round Iron-Ring, which just incompasses the place that is to be cut, or else by a Sulphur’d Threed, which is often wound about the place where the separation is to be made, and then fired. Or Secondly, A Glass may be cracked by cooling it suddenly in any place with Water, or the like, after it has been all leisurely and gradually heated very hot. Both which Phænomena seem manifestly to proceed from the expansion and contraction of the parts of the Glass, which is also made more probable by this circumstance which I have observed, that a piece of common window-glass being heated in the middle very suddenly with a live Coal or hot Iron, does usually at the first crack fall into pieces, whereas if the Plate has been gradually heated very hot, and a drop of cold Water and the like be put on the middle of it, it only flaws it, but does not break it asunder immediately.
A Fourth Argument may be drawn from this Experiment; Take a Glass-pipe, and fit into a solid stick of Glass, so as it will but just be moved in it. Then by degrees heat them whilst they are one within another, and they will grow stiffer, but when they are again cold, they will be as easie to be turned as before. This Expansion of Glass is more manifest in this Experiment.
Take a stick of Glass of a considerable length, and fit it so between the two ends or screws of a Lath, that it may but just easily turn, and that the very ends of it may be just toucht and susteined thereby; then applying the flame of the Candle to the middle of it, and heating it hot, you will presently find the Glass to stick very fast on those points, and not without much difficulty to be convertible on them, before that by removing the flame for a while from it, it be suffered to cool, and when you will find it as easie to be turned round as at the first.
From all which Experiments it is very evident, that all those Bodies, and particularly Glass, suffers an Expansion by Heat, and that a very considerable one, whilst they are in a state of Fusion. For Fluidity, as I elsewhere mention, being nothing but an effect of very strong and quick shaking motion, whereby the parts are, as it were, loosened from each other, and consequently leave an interjacent space or vacuity; it follows, that all those shaken Particles must necessarily take up much more room then when they were at rest, and lay quietly upon each other. And this is further confirmed by a Pot of boyling Alabaster, which will manifestly rise a sixth or eighth part higher in the Pot, whilst it is boyling, then it will remain at, both before and after it be boyled. The reason of which odd Phænomenon (to hint it here only by the way) is this, that there is in the curious powder of Alabaster, and other calcining Stones, a certain watery substance, which is so fixt and included with the solid Particles, that till the heat be very considerable they will not fly away; but after the heat is increased to such a degree, they break out every way in vapours, and thereby so shake and loosen the small corpuscles of the Powder from each other, that they become perfectly of the nature of a fluid body, and one may move a stick to and fro through it, and stir it as easily as water, and the vapours burst and break out in bubbles just as in boyling water, and the like; whereas, both before those watery parts are flying away, and after they are quite gone; that is, before and after it have done boyling, all those effects cease, and a stick is as difficultly moved to and fro in it as in sand, or the like. Which Explication I could easily prove, had I time; but this is not a fit place for it.
To proceed therefore, I say, that the dropping of this expanded Body into cold Water, does make the parts of the Glass suffer a double contraction: The first is, of those parts which are neer the Surface of the Drop. For Cold, as I said before, contracting Bodies, that is, by the abatement of the agitating faculty the parts falling neerer together; the parts next adjoyning to the Water must needs lose much of their motion, and impart it to the Ambient water (which the Ebullition and commotion of it manifests) and thereby become a solid and hard crust, whilst the innermost parts remain yet fluid and expanded; whence, as they grow cold also by degrees, their parts must necessarily be left at liberty to be condensed, but because of the hardness of the outward crust, the contraction cannot be admitted that way; but there being many very small, and before inconspicuous, bubbles in the substance of the Glass, upon the subsiding of the parts of the Glass, the agil substance contained in them has liberty of expanding it self a little, and thereby those bubbles grow much bigger, which is the second Contraction. And both these are confirmed from the appearance of the Drop it self: for as for the outward parts, we see, first, that it is irregular and shrunk, as it were, which is caused by the yielding a little of the hardened Skin to a Contraction, after the very outmost Surface is settled; and as for the internal parts, one may with ones naked Eye perceive abundance of very conspicuous bubbles, and with the Microscope many more.
The Consideration of which Particulars will easily make the Third Position probable, that is, that the parts of the drop will be of a very hard, though of a rarified Texture; for if the outward parts of the Drop, by reason of its hard crust, will indure very little Contraction, and the agil Particles, included in those bubbles, by the losing of their agitation, by the decrease of the Heat, lose also most part of their Spring and Expansive power; it follows (the withdrawing of the heat being very sudden) that the parts must be left in a very loose Texture, and by reason of the implication of the parts one about another, which from their sluggishnes and glutinousness I suppose to be much after the manner of the sticks in a Thorn-bush, or a Lock of Wool; it will follow, I say, that the parts will hold each other very strongly together, and indeavour to draw each other neerer together, and consequently their Texture must be very hard and stiff, but very much rarified.
And this will make probable my next Position, That the parts of the Glass are under a kind of tension or flexure, out of which they indeavour to extricate and free themselves, and thereby all the parts draw towards the Center or middle, and would, if the outward parts would give way, as they do when the outward parts cool leisurely (as in baking of Glasses) contract the bulk of the drop into a much less compass. For since, as I proved before, the Internal parts of the drop, when fluid, were of a very rarified Texture, and, as it were, tos’d open like a Lock of Wool, and if they were suffered leisurely to cool, would be again prest, as it were, close together: And since that the heat, which kept them bended and open, is removed, and yet the parts not suffered to get as neer together as they naturally would; It follows, that the Particles remain under a kind of tension and flexure, and consequently have an indeavour to free themselves from that bending and distension, which they do, as soon as either the tip be broken, or as soon as by a leisurely heating and cooling, the parts are nealed into another posture.
And this will make my next Position probable, that the parts of the Glass drops are contignated together in the form of an Arch, cannot any where yield or be drawn inwards, till by the removing of some one part of it (as it happens in the removing one of the stones of an Arch) the whole Fabrick is shatter’d, and falls to pieces, and each of the Springs is left at liberty, suddenly to extricate it self: for since I have made it probable, that the internal parts of the Glass have a contractive power inwards, and the external parts are incapable of such a Contraction, and the figure of it being spherical; it follows, that the superficial parts must bear against each other, and keep one another from being condens’d into a less room, in the same manner as the stones of an Arch conduce to the upholding each other in that Figure. And this is made more probable by another Experiment which was communicated to me by an excellent Person, whose extraordinary Abilities in all kind of Knowledg, especially in that of Natural things, and his generous Disposition in communicating, incouraged me to have recourse to him on many occasions. The Experiment was this: Small Glass-balls (about the bigness of that represented in the Figure &.) would, upon rubbing or scratching the inward Surface, fly all insunder, with a pretty brisk noise; whereas neither before nor after the inner Surface had been thus scratcht, did there appear any flaw or crack. And putting the pieces of one of those broken ones together again, the flaws appeared much after the manner of the black lines on the Figure, &. These Balls were small, but exceeding thick bubbles of Glass, which being crack’d off from the Puntilion whilst very hot, and so suffered to cool without nealing them in the Oven over the Furnace, do thereby (being made of white Glass, which cools much quicker then green Glass, and is thereby made much brittler) acquire a very porous and very brittle texture: so that if with the point of a Needle or Bodkin, the inside of any of them be rubbed prety hard, and then laid on a Table, it will, within a very little while, break into many pieces with a brisk noise, and throw the parts above a span asunder on the Table: Now though the pieces are not so small as those of a fulminating drop, yet they as plainly shew, that the outward parts of the Glass have a great Conatus to fly asunder, were they not held together by the tenacity of the parts of the inward Surface: for we see as soon as those parts are crazed by hard rubbing, and thereby their tenacity spoiled, the springiness of the more outward parts quickly makes a divulsion, and the broken pieces will, if the concave Surface of them be further scratcht with a Diamond, fly again into smaller pieces.
From which preceding considerations it will follow Sixthly, That the sudden flying asunder of the parts as soon as this Arch is any where disordered or broken, proceeds from the springing of the parts; which, indeavouring to extricate themselves as soon as they get the liberty, they perform it with such a quickness, that they throw one another away with very great violence: for the Particles that compose the Crust have a Conatus to lye further from one another, and therefore as soon as the external parts are loosened they dart themselves outward with great violence, just as so many Springs would do, if they were detained and fastened to the body, as soon as they should be suddenly loosened; and the internal parts drawing inward, they contract so violently; that they rebound back again and fly into multitude of small shivers or sands. Now though they appear not, either to the naked Eye, or the Microscope, yet I am very apt to think there may be abundance of small flaws or cracks, which, by reason the strong reflecting Air is not got between the contiguous parts, appear not. And that this may be so, I argue from this, that I have very often been able to make a crack or flaw, in some convenient pieces of Glass, to appear and disappear at pleasure, according as by pressing together, or pulling asunder the contiguous parts, I excluded or admitted the strong reflecting Air between the parts: And it is very probable, that there may be some Body, that is either very rarified Air, or something analogous to it, which fills the bubbles of these drops; which I argue, first, from the roundness of them, and next, from the vivid reflection of Light which they exhibite: Now though I doubt not, but that the Air in them is very much rarified, yet that there is some in them, to such as well consider this Experiment of the disappearing of a crack upon the extruding of the Air, I suppose it will seem more then probable.
The Seventh and last therefore that I shall prove, is, That the gradual heating and cooling of these so extended bodies does reduce the parts of the Glass to a looser and softer temper. And this I found by heating them, and keeping them for a prety while very red hot in a fire; for thereby I found them to grow a little lighter, and the small Stems to be very easily broken and snapt any where, without at all making the drop fly; whereas before they were so exceeding hard, that they could not be broken without much difficulty; and upon their breaking the whole drop would fly in pieces with very great violence. The Reason of which last seems to be, that the leisurely heating and cooling of the parts does not only wast some part of the Glass it self, but ranges all the parts into a better order, and gives each Particle an opportunity of relaxing its self, and consequently neither will the parts hold so strongly together as before, nor be so difficult to be broken: The parts now more easily yielding, nor will the other parts fly in pieces, because the parts have no bended Springs. The relaxation also in the temper of hardned Steel, and hammered Metals, by nealing them in the fire, seems to proceed from much the same cause. For both by quenching suddenly such Metals as have vitrified parts interspers’d, as Steel has, and by hammering of other kinds that do not so much abound with them, as Silver, Brass, &c. the parts are put into and detained in a bended posture, which by the agitation of Heat are shaken, and loosened, and suffered to unbend themselves.