Most lodes are perpendicular to the horizon, or nearly so; but some of them have a considerable inclination or "hade," as it is termed, the angles of dip varying from 15° to 45°. The course of a vein is frequently very straight; but if tortuous, it is found to be choked up with clay, stones, and pebbles, at points where it departs most widely from verticality. Hence at places, such as a, [fig. 520.], the miner complains that the ores are "nipped," or greatly reduced in quantity, the space for their free deposition having been interfered with in consequence of the pre-occupancy of the lode by earthy materials. When lodes are many fathoms wide, they are usually filled for the most part with earthy matter, and fragments of rock, through which the ores are much disseminated. The metallic substances frequently coat or encircle detached pieces of rock, which our miners call "horses" or "riders." That we should find some mineral veins which split into branches is also natural, for we observe the same in regard to open fissures.
Chemical deposits in veins.—If we now turn from the mechanical to the chemical agencies which have been instrumental in the production of mineral veins, it may be remarked that those parts of fissures which were not choked up with the ruins of fractured rocks must always have been filled with water; and almost every vein has probably been the channel by which hot springs, so common in countries of volcanos and earthquakes, have made their way to the surface. For we know that the rents in which ores abound extend downwards to vast depths, where the temperature of the interior of the earth is more elevated. We also know that mineral veins are most metalliferous near the contact of plutonic and stratified formations, especially where the former send veins into the latter, a circumstance which indicates an original proximity of veins at their inferior extremity to igneous and heated rocks. It is moreover acknowledged that even those mineral and thermal springs which, in the present state of the globe, are far from volcanos, are nevertheless observed to burst out along great lines of upheaval and dislocation of rocks.[496-A] It is also ascertained that all the substances with which hot springs are impregnated agree with those discharged in a gaseous form from volcanos. Many of these bodies occur as veinstones; such as silex, carbonate of lime, sulphur, fluor-spar, sulphate of barytes, magnesia, oxide of iron, and others. I may add that, if veins have been filled with gaseous emanations from masses of melted matter, slowly cooling in the subterranean regions, the contraction of such masses as they pass from a plastic to a solid state would, according to the experiments of Deville on granite (a rock which may be taken as a standard), produce a reduction in volume amounting to 10 per cent. The slow crystallization, therefore, of such plutonic rocks supplies us with a force not only capable of rending open the incumbent rocks by causing a failure of support, but also of giving rise to faults whenever one portion of the earth's crust subsides slowly while another contiguous to it happens to rest on a different foundation, so as to remain unmoved.
Although we are led to infer, from the foregoing reasoning, that there has often been an intimate connection between metalliferous veins and hot springs holding mineral matter in solution, yet we must not on that account expect that the contents of hot springs and mineral veins would be identical. On the contrary, M. E. de Beaumont has judiciously observed that we ought to find in veins those substances which, being least soluble, are not discharged by hot springs,—or that class of simple and compound bodies which the thermal waters ascending from below would first precipitate on the walls of a fissure, as soon as their temperature began slightly to diminish. The higher they mount towards the surface, the more will they cool, till they acquire the average temperature of springs, being in that case chiefly charged with the most soluble substances, such as the alkalis, soda and potash. These are not met with in veins, although they enter so largely into the composition of granitic rocks.[496-B]
To a certain extent, therefore, the arrangement and distribution of metallic matter in veins may be referred to ordinary chemical action, or to those variations in temperature, which waters holding the ores in solution must undergo, as they rise upwards from great depths in the earth. But there are other phenomena which do not admit of the same simple explanation. Thus, for example, in Derbyshire, veins containing ores of lead, zinc, and copper, but chiefly lead, traverse alternate beds of limestone and greenstone. The ore is plentiful where the walls of the rent consist of limestone, but is reduced to a mere string when they are formed of greenstone, or "toadstone," as it is called provincially. Not that the original fissure is narrower where the greenstone occurs, but because more of the space is there filled with veinstones, and the waters at such points have not parted so freely with their metallic contents.
"Lodes in Cornwall," says Mr. Robert W. Fox, "are very much influenced in their metallic riches by the nature of the rock which they traverse, and they often change in this respect very suddenly, in passing from one rock to another. Thus many lodes which yield abundance of ore in granite, are unproductive in clay-slate, or killas, and vice versâ. The same observation applies to killas and the granitic porphyry called elvan. Sometimes, in the same continuous vein, the granite will contain copper, and the killas tin, or vice versâ."[497-A] Mr. Fox, after ascertaining the existence at present of electric currents in some of the metalliferous veins in Cornwall, has speculated on the probability of the same cause having acted originally on the sulphurets and muriates of copper, tin, iron, and zinc, dissolved in the hot water of fissures, so as to determine the peculiar mode of their distribution. After instituting experiments on this subject, he even endeavoured to account for the prevalence of an east and west direction in the principal Cornish lodes by their position at right angles to the earth's magnetism; but Mr. Henwood and other experienced miners have pointed out objections to the theory; and it must be owned that the direction of veins in different mining districts varies so entirely that it seems to depend on lines of fracture, rather than on the laws of voltaic electricity. Nevertheless, as different kinds of rock would be often in different electrical conditions, we may readily believe that electricity must often govern the arrangement of metallic precipitates in a rent.
"I have observed," says Mr. R. Fox, "that when the chloride of tin in solution is placed in the voltaic circuit, part of the tin is deposited in a metallic state at the negative pole, and part at the positive one, in the state of a peroxide, such as it occurs in our Cornish mines. This experiment may serve to explain why tin is found contiguous to, and intermixed with, copper ore, and likewise separated from it, in other parts of the same lode."[497-B]
Relative age of the different metals.—After duly reflecting on the facts above described, we cannot doubt that mineral veins, like eruptions of granite or trap, are referable to many distinct periods of the earth's history, although it may be more difficult to determine the precise age of veins; because they have often remained open for ages, and because, as we have seen, the same fissure, after having been once filled, has frequently been re-opened or enlarged. But besides this diversity of age, it has been supposed by some geologists that certain metals have been produced exclusively in earlier, others in more modern times,—that tin, for example, is of higher antiquity than copper, copper than lead or silver, and all of them more ancient than gold. I shall first point out that the facts once relied upon in support of some of these views are contradicted by later experience, and then consider how far any chronological order of arrangement can be recognized in the position of the precious and other metals in the earth's crust. In the first place, it is not true that veins in which tin abounds are the oldest lodes worked in Great Britain. The government survey of Ireland has demonstrated, that in Wexford veins of copper and lead (the latter as usual being argentiferous) are much older than the tin of Cornwall. In each of the two countries a very similar series of geological changes has occurred at two distinct epochs,—in Wexford, before the Devonian strata were deposited; in Cornwall, after the carboniferous epoch. To begin with the Irish mining district: We have granite in Wexford, traversed by granite veins, which veins also intrude themselves into the Silurian strata, the same Silurian rocks as well as the veins having been denuded before the Devonian beds were superimposed. Next we find, in the same county, that elvans, or straight dikes of porphyritic granite, have cut through the granite and the veins before mentioned, but have not penetrated the Devonian rocks. Subsequently to these elvans, veins of copper and lead were produced, being of a date certainly posterior to the Silurian, and anterior to the Devonian; for they do not enter the latter, and, what is still more decisive, streaks or layers of derivative copper have been found near Wexford in the Devonian, not far from points where mines of copper are worked in the Silurian strata.[498-A]
Although the precise age of such copper lodes cannot be defined, we may safely affirm that they were either filled at the close of the Silurian or commencement of the Devonian period. Besides copper, lead, and silver, there is some gold in these ancient or primary metalliferous veins. A few fragments also of tin found in Wicklow in the drift are supposed to have been derived from veins of the same age.[498-B]
Next, if we turn to Cornwall, we find there also the monuments of a very analogous sequence of events. First the granite was formed; then, about the same period, veins of fine-grained granite, often tortuous (see [fig. 496.], [p. 445.]), penetrating both the outer crust of granite and the adjoining fossiliferous or primary rocks, including the coal-measures; thirdly, elvans, holding their course straight through granite, granitic veins, and fossiliferous slates; fourthly, veins of tin also containing copper, the first of those eight systems of fissures of different ages already alluded to, [p. 491.] Here, then, the tin lodes are newer than the elvans. It has indeed been stated by some Cornish miners that the elvans are in some few instances posterior to the oldest tin-bearing lodes, but the observations of Sir H. De la Beche during the survey led him to an opposite conclusion, and he has shown how the cases referred to in corroboration can be otherwise interpreted.[499-A] We may, therefore, assert that the most ancient Cornish lodes are younger than the coal-measures of that part of England, and it follows that they are of a much later date than the Irish copper and lead of Wexford and some adjoining counties. How much later it is not so easy to declare, although probably they are not newer than the beginning of the Permian period, as no tin lodes have been discovered in any red sandstone of the Poikilitic group, which overlies the coal in the south-west of England.