About the year 1832 it was proposed in America to apply pyroligneous acid to the surface of wood, or introduce it by fumigation.
Biot (who has written an excellent life of Sir Isaac Newton) remarked, in 1831, that wood could be soaked by pressure; but his process of penetrating it with liquids was imperfect, and his discovery remains unapplied.
A Frenchman, of the name of Bréant, made about this time a discovery which preceded Boucherie’s method, which is adopted to a great extent in France. Bréant’s apparatus consisted of a very ingenious machine, which, acting by pressure, caused liquids to penetrate to all points of a mass of wood of great diameter and considerable length. He may therefore be regarded as having solved the problem of penetration in a scientific, though not in a practically applied, point of view. Dr. Boucherie testified before the Académie des Sciences, in 1840, to the merit of Bréant’s invention, which, with modifications by Payne, Brochard, and Gemini, has been worked in France and England. This process was recommended by Payne in 1840 and 1844, and imitated by him in France, and later on by Yengat and Bauner, who used both an air pump and a forcing pump. Bréant obtained three patents, viz. 1st, in 1831, to act by pressure; 2nd, in 1837, by vital suction: and 3rd, in 1838, vacuum by steam. A mixture of linseed oil and resin succeeded best with him. He attached more importance to the thorough penetration of the wood than to the choice of the penetrating substances. He borrowed his process from Du Hamel, but to make the necessary suction in the pores he produces a partial vacuum in the impregnating cylinder by filling it with steam, and condensing the steam.
Previous to Boucherie’s method, a German, Frantz Moll, in 1835, proposed to introduce into wood creosote in a state of vapour, but the process was found to be too expensive. This was a modification of Maconochie and Lukin’s trials in 1805 and 1811.[11] A similar process has since arisen in New York: we believe Mr. Renwick, of that place, suggested it.
Such were the known labours, when Dr. Boucherie, in December, 1837, devoted his time to a series of experiments upon timber, with a view to discover some preservative process which should answer the following requirements: First, for protecting wood from dry rot or wet rot; second, for increasing its hardness; third, for preserving and developing its flexibility and elasticity; fourth, for preventing its decay, and the fissures that result from it, when, after having been used in construction, it is left exposed to the variations of the atmosphere; fifth, for giving it various and enduring colours and odours; and sixth and last, for greatly reducing its inflammability.
It is a curious coincidence that at Bordeaux, in 1733, the Academy received a memoir relative to the circulation of the sap and coloured liquids in plants; and it was at Bordeaux, a century afterwards, viz. 1837, that M. Boucherie first mentioned his method.
M. Boucherie’s process was first discussed in Paris in June, 1840. It consists in causing a solution of sulphate of copper to penetrate to the interior of freshly cut woods, to preserve them from decay; he occasionally used the chloride of calcium, the pyrolignite of iron (pyrolignite brut de fer), prussiate of iron, prussiate of copper, and various other metallic salts. As a general rule sulphate of copper is used; but when the hardness of the wood is desired to be increased, pyrolignite of iron is taken (1 gallon of iron to 6 gallons of water); and when the object is to render the wood flexible, elastic, and at the same time uninflammable, chloride of calcium is used. The liquid is taken up by the tree either whilst growing in the earth or immediately after it has been felled. Not more than two or three months should be allowed to elapse before the timber is operated upon, but the sooner it undergoes the process after being felled the better.
Sulphate of copper is said to be superior to corrosive sublimate. Dr. Boucherie’s process of the injection of wood with the salts of copper is as simple as it is easy. For those woods intended for poles it consists in plunging the base of a branch, furnished with leaves, into a tub containing the solution. The liquid ascends into the branches by the action of the leaves, and the wood is impregnated with the preservative salt. As for logs, the operation consists in cutting down the tree to be operated upon; fixing at its base a plank, which is fixed by means of a screw placed in the centre, and which can be tightened at will when placed in the centre of the tree. This plank has, on the side to be applied to the bottom of the tree, a rather thick shield of leather, cloth, pasteboard, or some other substance, intended to establish a space between it and the wood, sufficient for the preserving fluid to keep in contact with the freshly cut surface of the tree. The liquid is brought there from a tub or other reservoir, by the help of a slanting pole made on the upper surface of the tree, and in which is put a tube, adapted at its other extremity to a spigot in the upper reservoir which contains the solution. A pressure of 5 mètres suffices; so that the instant the sap of the tree is drawn away it escapes, and is replaced by the liquid saturated with sulphate of copper. The proportion of sulphate of copper in the solution should be 1 lb. of the salt to 12½ gallons of water. As soon as the operation terminates (and it lasts for some hours for the most difficult logs), the wood is ready for use.
For various practical reasons, the first invention of impregnating the wood of the tree whilst still in a growing state, causing it to suck up various solutions by means of the absorbing power of the leaves themselves, was subsequently abandoned; and at the present time a cheap, simple, and effective process is adopted for impregnating the felled timbers with the preserving liquid, designated in France “trait de scie, et la cuisse foulante.” The trunk of a newly felled tree is cut into a length suitable for two railway sleepers; a cross cut is made on the prostrate timber to nearly nine-tenths of its diameter; a wedge is then inserted, and a cord is wound round on the cut surface, leaving a shallow chamber in the centre, when it is then closed by withdrawing the wedge. A tube is then inserted through an auger hole into this chamber, and to this tube is attached an elastic connecting tube from a reservoir placed some 20 or 30 feet above the level on which the wood lies, and a stream of the saturating fluid with this pressure passes into the chamber, presses on the sap in the sap tubes, expels it at each end of the tree, and itself supplies its place. The fluid used is a solution of copper in water, in the proportion of 10 or 12 per cent., and a chemical test that ascertains the pressure of the copper solution is applied at each end of the tree from which the sap exudes, by which the operator ascertains when the process is completed.