A full account of this process may be found in the number for June, 1840, of ‘Les Annales de Chimie et de Physique.’ Messrs. de Mirbel, Arago, Poucelet, Andouin, Gambey, Boussingault, and Dumas, on the part of l’Académie des Sciences, made a report upon Dr. Boucherie’s process, confirming the value of the invention. In France, Dr. Boucherie, some years since, relinquished his brévet, and threw the process open to the public, in consideration of a national reward; whilst in England he has obtained two patents (1838 and 1841), which, however, are similar to Bethell’s patent, obtained by him on July 11, 1838: which is the same day and year of Boucherie’s patent. A prize medal was awarded for Dr. Boucherie’s process at the Great Exhibition in London, in 1851, and a grande médaille d’honneur, at the Paris Exhibition of 1855. Many thousands of railway sleepers have been prepared by this process, and laid down on the Great Northern Railway of France, and are at present perfectly sound, whilst others not prepared, on the same line, have rotted. Boucherie’s process was used on Belgium railways up to 1859; and it is to be regretted that the reasons which led to its abandonment have not been given in the reports of the railway administration, as such reasons would have afforded reliable data for future experimentalists to go upon.
Messrs. Légé and Fleury-Pironnet’s patent for the injection of sulphate of copper into beech and poplar is as follows: After the wood is placed, and the opening hermetically sealed, a jet of steam is introduced, intended at first to enter the timber and open its pores for the purpose of obtaining a sudden vacuum, so as to establish at any time a communication between the interior of the cylinder and the cold water condenser; at the same time the air pump is put in action. The vacuum caused is very powerful, and is equal to 25½ ins. of the barometer. Under the double influence of the heat and the vacuum the sap is quickly evaporated from the wood as steam, and ejected from the cylinder by the air pump, so that in a very short time the wood is fully prepared to admit the preserving liquid through the entire bulk.
The use of sulphate of copper for preserving timber has not been, however, confined to France, for about the time Dr. Boucherie brought forward his process, a Mr. Margary took out a patent in England for the use of the same material. His method consists in steeping the substances to be preserved in a solution of sulphate of copper, of the strength of 1 lb. of the sulphate to 8 gallons of water, and leaving them in it till thoroughly saturated. The timber is allowed to remain in the tank two days for every inch of its thickness. Another method is to place the timber in a closed iron vessel of great strength, and it is made to imbibe the solution by exhaustion and pressure, the operation occupying but a short time.
Sulphate of copper is sold in quantities at 4d. per lb.; so that 100l. would buy 6000 lb., and each pound weight is sufficient for 7 or 8 gallons of water, according to Margary; or 12 gallons of water, according to Boucherie.
To preserve railway sleepers, the French railway engineers require ¼ lb. of sulphate of copper per cubic foot, say at least 12 lbs. to the load of 50 feet, to be used in a 2 per cent. solution; so that a load of timber can be rendered imperishable for the sum of four shillings, exclusive of labour, if sulphate of copper be reckoned at 4d. per lb.
With respect to the use of pyrolignite of iron, Mr. Bethell considers it an expensive process, the pyrolignite costing 6d. to 9d. per gallon, whilst the oil of tar can be delivered at from 2d. to 3d. per gallon: the cost of these materials is constantly varying.
A great many sleepers were prepared on the Great Western Railway by pyrolignite of iron, and all have decayed. Their black colour makes them exactly resemble creosoted sleepers, and many mistakes have arisen from this resemblance.
Messrs. Dorsett and Blythé’s (of Bordeaux) patent process of preparing wood by the injection of heated solutions of sulphate of copper is said to have been adopted by French, Spanish, and Italian, as well as other continental railway companies, by the French Government for their navy and other constructions, and by telegraph companies for poles on continental lines. It is as cheap as creosote, and is employed in places where creosote cannot be had. Wood prepared by it is rendered incombustible. Wood for outdoor purposes so prepared has a clean yellowish surface, without odour; it requires no painting, remains unchangeable for any length of time, and can be employed for any purpose, the same as unprepared material, and carried with other cargo without hindrance.[12] Messrs. Dorsett and Blythé’s process is similar to that of Mr. Knab, which consisted of a solution of sulphate of copper, heated to nearly boiling point, and placed in a lead cylinder, protected by wood.
In 1846, 80,000 sleepers, treated with sulphate of copper, were laid down on French railways, and after nine years’ exposure were found to be as perfect as when first laid.
Mr. H. W. Lewis, University of Michigan, U.S., thus writes in the ‘Journal’ of the Franklin Institute, in 1866, with reference to the decay of American railway sleepers: “Allowing 2112 sleepers per mile, at 50 cents each, 1056 dols. per mile of American railroad decay every seven years. Thoroughly impregnate those sleepers with sulphate of copper, at a cost of 5 cents each, and they would last twice as long. Thus would be effected a saving of 880 dols. per mile in the seven years on sleepers alone. In the United States, there are 33,906·6 miles of railroad. The whole saving on these lines would be 29,389,568 dols., or upwards of 4,262,795 dols. per annum.”