The only danger of lead-poisoning to which the workmen are exposed occurs in melting the lead and casting it. In this respect the electrolytic process presents a distinct sanitary advance.
For the treatment of slime, the only method in general use consists in suspending the slime in a solution capable of dissolving the impurities and supplying, by a jet of steam and air forced into the solution, the air necessary for its reaction with, and solution of, such an inactive metal as copper. After the impurities have been mostly dissolved, the slime is filtered off, dried and melted, under such fluxes as soda, to a doré bullion.
The amount of power required is calculated thus: Five amperes in 24 hours make 1 lb. of lead per tank. One ton of lead equals 10,000 ampere-days, and at 0.35 volts per tank, 3500 watt-days, or 4.7 electric h.p. days. Allowing 10 per cent. loss of efficiency in the tanks (we always get less lead than the current which is passing would indicate), and of 8 per cent. loss in the generator, increases this to about 5.6 h.p. days, and a further allowance for the electric lights and other applications gives from 7 to 8 h.p. days as about the amount per ton of lead. At $30 per year, this item of cost is something like 65c. per ton of lead. So this is an electro-chemical process not especially favored by water-power.
The cost of labor is not greater than in the zinc-desilverization process. A comparison between this process and the Parkes process, on the assumption that the costs for labor, interest and general expenses are about equal, shows that about $1 worth of zinc and a considerable amount of coal and coke have been done away with, at the expense of power, equal to about 175 h.p. hours, of the average value of perhaps 65c., and a small amount of coal for melting the lead in the electrolytic method.
More important, however, is the greater saving of the metal values by reason of increased yields of gold, silver, lead, antimony and bismuth, and the freedom of the refined lead from bismuth.
Tables II, III, and IV show the composition of bullion, slimes and refined lead.
Tables V, VI, VII, and VIII give the results obtained experimentally in the laboratory on lots of a few pounds up to a few hundred pounds. The results in Tables VI and VII were given me by the companies for which the experiments were made.
TABLE I.—ANALYSES OF DROSS
For analyses of the lead from which this dross was taken, see Table II
| No. | No. in Table II. | Cu. Per Cent. | As. Per Cent. | Sb. Per Cent. | Fe. Per Cent. | Zn. |
|---|---|---|---|---|---|---|
| 1 | 2 | 0.0005 | 0.0003 | 0.0016 | 0.0016 | none |
| 2 | 3 | 0.0010 | 0.0008 | 0.0107 | 0.0011 | " |