The combinations of the elements which are of most importance in the constitution of the terrestrial crust consist of oxides. From the mean of a large number of analyses of the rocks of the lower or primitive portion of the crust, it has been ascertained that silica (SiO2) forms almost 60% and alumina (Al2O3) upwards of 15% of the whole. The other combinations in order of importance are lime (CaO) 4.90%, magnesia (MgO) 4.36, soda (Na2O) 3.55, ferrous oxide (FeO) 3.52, potash (K2O) 2.80, ferric oxide (Fe2O3) 2.63, water (H2O) 1.52, titanium oxide (TiO2) 0.60, phosphoric acid (P2O5) 0.22; the other combinations of elements thus form less than 1% of the crust.

These different combinations of the elements enter into further combinations with each other so as to produce the wide assortment of simple minerals (see [Mineralogy]). Thus, silica and alumina are combined to form the aluminous silicates, which enter so largely into the composition of the crust of the earth. The silicates of magnesia, potash and soda constitute other important families of minerals. A mass of material composed of one, but more usually of more than one mineral, is known as a rock. Under this term geologists are accustomed to class not only solid stone, such as granite and limestone, but also less coherent materials such as clay, peat and even loose sand. The accessible portion of the earth’s crust consists of various kinds of rocks, which differ from each other in structure, composition and origin, and are therefore susceptible of diverse classifications according to the point of view from which they are considered. The details of this subject will be found in the article [Petrology].

Classification of Rocks.—Various systems of classification of rocks have been proposed, but none of them is wholly satisfactory. The most useful arrangement for most purposes of the geologist is one based on the broad differences between them in regard to their mode of origin. From this point of view they may be ranged in three divisions:

1. In the first place, a large number of rocks may be described as original or underived, for it is not possible to trace them back to any earlier source. They belong to the primitive constitution of the planet, and, as they have all come up from below through the crust, they serve to show the nature of the material which lies immediately below the outer parts of that crust. They include the numerous varieties of lava, which have been poured out in a molten state from volcanic vents, also a great series of other rocks which, though they may never have been erupted to the surface, have been forced upward in a melted condition into the other rocks of the crust and have solidified there. From their mode of origin this great class of rocks has been called “igneous” or “eruptive.” As they generally show no definite internal structure save such as may result from joints, they have been termed “massive” or “unstratified,” to distinguish them from those of the second division which are strongly marked out by the presence of a stratified structure. The igneous rocks present a considerable range of composition. For the most part they consist mainly of aluminous silicates, some of them being highly acid compounds with 75% or more of silica. But they also include highly basic varieties wherein the proportion of silica sinks to 40%, and where magnesia greatly predominates over alumina. The textures of igneous rocks likewise comprise a wide series of varieties. On the one hand, some are completely vitreous, like obsidian, which is a natural glass. From this extreme every gradation may be traced through gradual increase of the products of devitrification, until the mass may become completely crystalline. Again, some crystalline igneous rocks are so fine in grain as not to show their component crystals save under the microscope, while in others the texture is so coarse as to present the component minerals in separate crystals an inch or more in length. These differences indicate that, at first, the materials of the rock may have been as completely molten as artificial glass, and that the crystalline condition has been subsequently developed by cooling, and the separation of the chemical constituents into definite crystalline minerals. Many of the characters of igneous rocks have been reproduced experimentally by fusing together their minerals, or the constituents of their minerals, in the proper proportion. But it has not yet been found possible to imitate the structure of such rocks as granite. Doubtless these rocks consolidated with extreme slowness at great depths below the surface, under vast pressures and probably in the presence of water or water-vapour—conditions which cannot be adequately imitated in a laboratory.

Though the igneous rocks occupy extensive areas in some countries, they nevertheless cover a much smaller part of the whole surface of the land than is taken up by the second division or stratified rocks. But they increase in quantity downwards and probably extend continuously round the globe below the other rocks. This important series brings before us the relations of the molten magma within the earth to the overlying crust and to the outer surface. On the one hand, it includes the oldest and most deep-seated extravasations of that magma, which have been brought to light by ruptures and upheavals of the crust and prolonged denudation. On the other, it presents to our study the varied outpourings of molten and fragmentary materials in the discharges of modern and ancient volcanoes. Between these two extremes of position and age, we find that the crust has been, as it were, riddled with injections of the magma from below. These features will be further noticed in Part V. of this article.

2. The “sedimentary” or “stratified rocks” form by much the larger part of the dry land of the globe, and they are prolonged to an unknown distance from the shores under the bed of the sea. They include those masses of mineral matter which, unlike the igneous rocks, can be traced back to a definite origin on the surface of the earth. Three distinct types may be recognized among them: (a) By far the largest proportion of them consists of different kinds of sediment derived from the disintegration of pre-existing rocks. In this “fragmental” group are placed all the varieties of shingle, gravel, sand, clay and mud, whether these materials remain in a loose incoherent condition, or have been compacted into solid stone. (b) Another group consists of materials that have been deposited by chemical precipitation from solution in water. The white sinter laid down by calcareous springs is a familiar example on a small scale. Beds of rock-salt, gypsum and dolomite have, in some regions, been accumulated to a thickness of many thousand feet, by successive precipitations of the salt contained in the water of inland seas. (c) An abundant and highly important series of sedimentary formations has been formed from the remains of plants and animals. Such accumulations may arise either from the transport and deposit of these remains, as in the case of sheets of drift-wood, and banks of drifted sea-shells, or from the growth and decay of the organisms on the spot, as happens in peat bogs and in coral-reefs.

As the sedimentary rocks have for the most part been laid down under water, and more especially on the sea-floor, they are often spoken of as “aqueous,” in contradistinction to the igneous rocks. Some of them, however, are accumulated by the drifting action of wind upon loose materials, and are known as “aeolian” formations. Familiar instances of such wind-formed deposits are the sand-dunes along many parts of the sea coast. Much more extensive in area are the sands of the great deserts in the arid regions of the globe.

It is from the sedimentary rocks that the main portion of geological history is derived. They have been deposited one over another in successive strata from a remote period in the development of the globe down to the present time. From this arrangement they have been termed “stratified,” in contrast to the unstratified or igneous series. They have preserved memorials of the geographical revolutions which the surface of the earth has undergone; and above all, in the abundant fossils which they have enclosed, they furnish a momentous record of the various tribes of plants and animals which have successively flourished on land and sea. Their investigation is thus the most important task which devolves upon the geologist.

3. In the third place comes a series of rocks which are not now in their original condition, but have undergone such alteration as to have acquired new characters that more or less conceal their first structures. Some of them can be readily recognized as altered igneous masses; others are as manifestly of sedimentary origin; while of many it is difficult to decide what may have been their pristine character. To this series the term “metamorphic” has been applied. Its members are specially distinguished by a prevailing fissile, or schistose, structure which they did not at first possess, and which differs from anything found in unaltered igneous or sedimentary rocks. This fissility is combined with a more or less pronounced crystalline structure. These changes are believed to be the result of movements within the crust of the earth, whereby the most solid rocks were crushed and sheared, while, at the same time, under the influence of a high temperature and the presence of water, they underwent internal chemical reactions, which led to a rearrangement and recomposition of their mineral constituents and the production of a crystalline structure (see [Metamorphism]).

Among the less altered metamorphic rocks of sedimentary origin, the successive laminae of deposit of the original sediment can be easily observed; but they are also traversed by a new set of divisional planes, along which they split across the original bedding. Together with this superinduced cleavage there have been developed in them minute hairs, scales and rudimentary crystals. Further stages of alteration are marked by the increase of micaceous scales, garnets and other minerals, especially along the planes of cleavage, until the whole rock becomes crystalline, and displays its chief component minerals in successive discontinuous folia which merge into each other, and are often crumpled and puckered. Massive igneous rocks can be observed to have undergone intense crushing and cleavage, and to have ultimately assumed a crystalline foliated character. Rocks which present this aspect are known as schists (q.v.). They range from the finest silky slates, or phyllites, up to the coarsest gneisses, which in hand-specimens can hardly be distinguished from granites. There is indeed every reason to believe that such gneisses were probably originally true granites, and that their foliation and recrystallization have been the result of metamorphism.