[93] 861.
Many of the subordinate facts and laws which were brought to light by these researches, clearly point to generalizations, not included in that which we have had to consider, and not yet discovered: such laws do not properly belong to our main plan, which is to make our way up to the generalizations. But there is one which so evidently promises to have an important bearing on future chemical theories, that I will briefly mention it. The class of bodies which are capable of electrical decomposition is limited by a very remarkable law: they are such binary compounds only as consist of single proportionals of their elementary principles. It does not belong to us here to speculate on the possible import of this curious law; which, if not fully established, Faraday has rendered, at least, highly probable:[94] but it is impossible not to see how closely it connects the Atomic with the Electro-chemical Theory; and in the connexion of these two great members of Chemistry, is involved the prospect of its reaching wider generalizations, and principles more profound than we have yet caught sight of.
[94] Art. 697.
As another example of this connexion, I will, finally, notice that Faraday has employed his discoveries in order to decide, in some doubtful cases, what is the true chemical equivalent;[95] “I have such conviction,” he says, “that the power which governs electro-decomposition and ordinary chemical attractions is the same; and such confidence in the overruling influence of those natural laws which render the former definite, as to feel no hesitation in believing that the latter must submit to them too. Such being the case, I can have no doubt that, assuming hydrogen as 1, and dismissing small fractions for the simplicity of expression, the equivalent number or atomic weight of oxygen is 8, of chlorine 36, of bromine 78·4, of lead 103·5, of tin 59, &c.; notwithstanding that a very high authority doubles several of these numbers.”
[95] 851.
Sect. 4.—Reception of the Electro-chemical Theory.
The epoch of establishment of the electro-chemical theory, like other great scientific epochs, must have its sequel, the period of its reception and confirmation, application and extension. In that period we [304] are living, and it must be the task of future historians to trace its course.
We may, however, say a word on the reception which the theory met with, in the forms which it assumed, anterior to the labors of Faraday. Even before the great discovery of Davy, Grotthuss, in 1805, had written upon the theory of electro-chemical decomposition; but he and, as we have seen, Davy, and afterwards other writers, as Riffault and Chompré, in 1807, referred the effects to the poles.[96] But the most important attempt to appropriate and employ the generalization which these discoveries suggested, was that of Berzelius; who adopted at once the view of the identity, or at least the universal connexion, of electrical relations with chemical affinity. He considered,[97] that in all chemical combinations the elements may be considered as electro-positive and electro-negative; and made this opposition the basis of his chemical doctrines; in which he was followed by a large body of the chemists of Germany. He held too that the heat and light, evolved during cases of powerful combination, are the consequence of the electric discharge which is at that moment taking place: a conjecture which Faraday at first spoke of with praise.[98] But at a later period he more sagely says,[99] that the flame which is produced in such cases exhibits but a small portion of the electric power which really acts. “These therefore may not, cannot, be taken as evidences of the nature of the action; but are merely incidental results, incomparably small in relation to the forces concerned, and supplying no information of the way in which the particles are active on each other, or in which their forces are finally arranged.” And comparing the evidence which he himself had given of the principle on which Berzelius’s speculations rested, with the speculations themselves, Faraday justly conceived, that he had transferred the doctrine from the domain of what he calls doubtful knowledge, to that of inductive certainty.
[96] Faraday (Researches, Art. 481, 492).
[97] Ann. Chim. lxxxvi. 146, for 1813.