François Jean de Beauvoir, Marquis de Chastellux, was a military officer who served during the War of American Independence as a major general in the French expeditionary forces led by general Comte de Rochambeau. Being on general Rochambeau's staff for the duration of the war, Chastellux acted as the principal liaison officer between the French commander in chief and George Washington. However the Chevalier de Chastellux was also widely recognized, at the time of his campaigns in America, as a highly talented man of letters and a member of the Académie Française

François-Joseph de Beaupoil, marquis de Sainte-Aulaire was a French poet and army officer.

François-Joseph de Champagny, 4th Duke of Cadore was a French author and historian. He was the thirteenth member elected to occupy seat 4 of the Académie française in 1869.

François-Joseph-Marie Fayolle was a French writer on music, who was born in Paris and is known by his articles in connection with the Biographie Universelle, having furnished the greater portion of the biographies, and by his joint authorship of Choron's Dictionary of Musicians, to which work Fétis was much indebted for information.

François-Louis Crosnier was a French theatre manager, politician, and playwright, who used the pen name Edmond Crosnier.

François Nicolas Vincent Campenon was a French poet and translator from Latin and English.

François-Noël Babeuf, also known as Gracchus Babeuf, was a French proto-communist, revolutionary, and journalist of the French Revolutionary period. His newspaper Le tribun du peuple was best known for its advocacy for the poor and calling for a popular revolt against the Directory, the government of France. He was a leading advocate for democracy and the abolition of private property. He angered the authorities who were clamping down hard on their radical enemies. In spite of the efforts of his Jacobin friends to save him, Babeuf was executed for his role in the Conspiracy of the Equals.

François-René, vicomte de Chateaubriand was a French writer, politician, diplomat and historian who had a notable influence on French literature of the nineteenth century. Descended from an old aristocratic family from Brittany, Chateaubriand was a royalist by political disposition. In an age when large numbers of intellectuals turned against the Church, he authored the Génie du christianisme in defense of the Catholic faith. His works include the autobiography Mémoires d'Outre-Tombe, published posthumously in 1849–1850.

François-Rodolphe de Weiss (1751–1818) was a Swiss military officer, diplomat, writer, philosopher, and a follower of Jean-Jacques Rousseau.

François-Thomas-Marie de Baculard d'Arnaud was a French writer, playwright, poet and novelist. His series of novellas Les Épreuves du sentiment inspired Bellini's opera Adelson e Salvini.