FRANCE.
Water that has been used to wash frozen beets contains a small percentage of sugar. As the washing period, in such cases, is longer than with normal beets, the sugar in beet cells has time to pass through the outer walls by osmosis. The sugar loss is said to be 0.66 per cent. (?) of the weight of beets washed.
Well conducted experiments show that in small but well ventilated silos, beets lose considerable weight, but very little sugar. On the other hand, in large silos with poor ventilation, the sugar loss frequently represents four to six per cent. When fermentation commences, the mass of roots is almost ruined.
Sodic nitrate, if used upon soil late in the season, may overcome a difficulty that has been recently noticed. Beet fields located near swamps that are dry a portion of the year have suffered from a malady that turns leaves from green to yellow, even before harvesting period; such beets have lost a considerable amount of sugar.
A new method for the analysis of saccharose and raffinose, when in the presence of inverted sugar, is said to give accurate results. The process consists in adding sulphate of copper and lime to hot molasses, so that the oxide of copper is changed to a protoxide, and the invert sugar becomes water and carbonic acid. The whole is neutralized with phosphoric acid. There follow a great number of precipitates; the exact volume of liquid in which these are found is determined after two polariscopic observations.
It has been constantly noticed that samples of carbonatated juice vary in composition with the part of tank from which they are taken. If some arrangement could be made assuring a thorough mixing during the passage of carbonic acid, results would be more satisfactory than they now are. If gas could be distributed in every part of the tank, the lime combination could be made perfect.
Notwithstanding the new law regulating quantity of sugar to be used in wines, ciders, etc., there has been, during 1890, an increase of nearly 13,000 tons, as compared with 1889. Consumption of sugar for these special industries was 33,000 tons; alcohol thus added to wine was about 71,000,000 gallons.
Beets cultivated without extra fertilizers, and that are regular in shape and in good condition, without bruises, are the ones which give the best results in silos. It is recommended to construct silos of two types; one which is to be opened before first frost, the other where beets remain for several months and are protected against excessive cold. Great care should be taken that a thorough ventilation be given in the first mentioned type. In the other, more substantial silos, ventilation must be watched,and all communication with the exterior closed as soon as the temperature falls to or near freezing.
During the last campaign many manufacturers experienced great difficulty in keeping the blades of slicers sufficiently sharp to work frozen beets. Sharpening of blades is an operation attended to by special hands at the factory; and under ordinary circumstances there need be no difficulty. However, it is now proposed to have central stations that will make a specialty of blade sharpening. Under these circumstances manufacturers located in certain districts need give the matter no further thought, let the coming winter be as severe as it may.
Some success has been obtained by the use of sulphurous acid in vacuum pans. Great care is required; the operation cannot be done by an ordinary workman. It is claimed that graining thereby is more rapid and better than is now possible. Chemists agree that the operation is more effectual by bringing sulphurous acid in contact with sirups rather than juices; it is in the sirups that the coloring pigments are found. Sulphurous acid is run into the pan until the sirups cover the second coil. In all cases the work must be done at a low temperature.
Height of juice in carbonatating tanks is only three feet in France, while in Austria it is frequently twelve feet. The question of a change in existing methods is being discussed; it necessitates an increase in the blowing capacity of machine; since carbonic acid gas has a greater resistance to overcome in Austrian than in French methods. Longer the period juices are in contact with carbonic acid, greater will be the effect produced.
Ferric sulphate has been very little used for refuse water purification, owing to cost of its manufacture. If roasted pyrites, a waste product of certain chemical factories, are sprinkled with sulphuric acid of 66° B., and thoroughly mixed for several hours, at a temperature of 100° to 156° F., the pyrites will soon be covered with a white substance which is ferric sulphate. Precipitates from ferric sulphate, unlike calcic compounds, do not subsequently enter into putrefaction.
Efforts are being made to convince manufacturers of the mistake in using decanting vats, in connection with first and second carbonatation. In Germany filter presses are used, decanting vats are obsolete. The main objection to them is cooling of saccharine liquors, which means an ultimate increase in fuel. Cooling is frequently followed by partial fermentation.
Further changes in the proposed combined baryta-soda method for juice purification consist in using powdered soda carbonate 90-92°, upon beet cossettes as they leave the slicer, before entering the diffusor. The quantity of chemical to be used is 1/1000 of weight of beet slices being treated. If a diffusor has a capacity of 2,500 lb., there would be added 2.5 lb. soda carbonate. From the diffusor is subsequently taken 316 gallons juice at 4-5° density, this is rapidly heated to 185°F., then 2.4 of a pure baryta solution is added; temperature is kept at 185° F. for a short time; resulting precipitates fall to bottom of tank; then 13 gallons milk of lime 25° B. are added.
Other operations that follow are as usual. It is contended that the cost of baryta is 10 cents per ton beets worked. The most important advantage is gain in time; a factory working 20,000 during a 100-day campaign, by the foregoing process can accomplish the same work in 80 days, thus decreasing wear and tear of plant and diminishing percentage of sugar lost in badly constructed silos.
The exact influence of a low temperature upon beet cells has never been satisfactorily settled. Considerable light has recently been thrown upon the subject by a well known chemist. It is asserted that living cells containing a saccharine liquid do not permit infiltration from interior to exterior; this phenomenon occurs only when cell and tissue are dead. It is necessary that the degree of cold should be sufficiently intense, or that a thaw take place, under certain conditions, to kill tissue of walls of said cells. An interesting fact is that when cells are broken through the action of freezing, it is not those containing sugar that are the first affected. The outer cells containing very little sugar are the first to expand when frozen, which expansion opens the central cells.
Experiments to determine the action of lime upon soils apparently prove that it does not matter in what form calcic salts are employed; their effect, in all cases, is to increase the yield of roots to the acre. On the other hand, very secondary results were obtained with phosphoric and sulphuric acids.
A micro-mushroom, a parasite that kills a white worm, enemy of the beet, has been artificially cultivated. As soon as the worm is attacked, the ravage continues until the entire body of the insect is one mass of micro-organisms. Spores during this period are constantly formed. If it were possible to spread this disease in districts infected by the white worm, great service could be rendered to beet cultivation.
In sugar refining it is frequently desirable to determine the viscosity of sirups, molasses, etc. Methods founded upon the rapidity of flow through an orifice of a known size are not mathematical in their results. A very simple plan, more accurate than any hitherto thought of, is attracting some attention. Sensitive scales and a thermometer suspended in a glass tube are all the apparatus necessary. The exact weight of thermometer, with tube, is determined; they are immersed in water and weighed for the second time; the difference in weight before and afterward gives the weight of adhering water. If the operation is repeated in molasses, we in the same way obtain the weight of adhering liquid, which, if divided by the weight of adhering water, gives the viscosity as compared with water.
Sugar refineries located at Marseilles claim that it is cheaper for them to purchase sugar in Java than beet sugar of northern Europe. On the other hand, the argument of Paris refiners is just the reverse. The total refined sugar consumed is 375,000 tons, the colonial and indigenous production of raw sugar is nearly 1,000,000 tons more than sufficient to meet the demands of the entire refining industry of the country. There appears to have been considerable manipulation, foreign sugar being imported with the view of producing a panic, followed by a decline of market prices, after which Marseilles refiners would buy. All sound arguments are in favor of protecting the home sugar industry.
It has been suggested that manufacturers weigh the fuel used more carefully than hitherto; the extra trouble would soon lead to economy for all interested in sugar production at ruinous cost. Some chemists advocate that coal be purchased only after having been analyzed. Efforts to have a unification in methods of analysis of all products of factory is a move in the right direction; the Association of Sugar Chemists have adopted a series of methods that are in the future to be considered as standard.
Copper solutions are destined to render great service in the destruction of micro-organisms that attack the beet field. The liquid used should be composed of 3 per cent. copper sulphate and 3 per cent. lime, dissolved in water; fifty gallons are sufficient for one acre; cost per acre, every item included, is 56 cents. The normal vitality of the plant being restored, there follows an increased sugar percentage. Ordinary liquid ammonia may be advantageously used to kill white worms and insects that attack beets; two quarts of the diluted chemical are used per square yard, and the cost is $12 per acre (?)