A large (12-inch) mass spectrometer (at left) in use. Electronic equipment (right) charts results (see [page 21]).
Essential parts of a mass spectrometer. Atoms to be analyzed are changed to ions in the source. Then the ions are accelerated by high voltage, deflected in a magnetic field according to their mass, and the intensity of the separated beams is measured in the collector.
Mass Spectrometry
The mass spectrometer measures isotopic abundances using a magnetic field to sort electrically charged particles into groups according to their masses. It works this way: A small drop of material to be analyzed is placed on a metal filament and dried. The filament, in its holder, is placed inside the mass spectrometer, and heated electrically in a vacuum, like the filament in a light bulb. As the wire begins to glow, some of the sample begins to radiate, or “boil off”, losing an electron or two in the process. In other words, some of the atoms will be changed into positive [IONS].
An alternative method is to introduce the sample material into the vacuum chamber in the form of a gas (like argon, for example), and then bombard the gas with electrons streaming from a hot filament. The electron stream will knock some electrons off the gas molecules and this also will produce positive ions. Either process of ion production is satisfactory, depending on the problem to be tackled, but the mass spectrometers for the two methods are naturally quite different.
Whichever way the ions were produced, they are next exposed to a strong electric field, accelerated, and electrostatically focused into a beam. These charged particles are directed into a magnetic field between the pole faces of an electromagnet. The magnet does the analyzing by the principle of magnetic deflection that was known to André Ampere and Michael Faraday more than a century ago. Any moving electric charge has a magnetic field associated with it. This field interacts with the field of the analyzing magnet to impress a deflecting force on the charge. The force acts at right angles to the direction the charge travels and also at right angles to the direction of the impressed magnetic field. The pull of this force depends only on the electric charge and the speed of each particle: A light single-charged particle will be deflected more than a heavier particle with the same charge. In this way, the ions in the beam are sorted out into a number of separate beams, each made up of particles of the same charge/mass ratio. Each beam contains one isotope of the original material, because isotopes differ on the basis of their mass. By adjusting the current in the electromagnet we can direct these separate beams into a “collector” and electrically measure their intensity one by one. This gives the relative abundance of the separate isotopes in the sample.
Minerals That Can Be Dated
Measuring age by one of the long-lived radioisotopes requires a closed system. Usually this is some kind of crystal formed in a period of time that is short, compared to the time that has elapsed since, and that has remained unchanged since it formed. Specifically, neither the parent isotopes can have been added nor the daughter isotopes removed by any process other than radioactive decay.