The earth is a dynamic system, however. Things are always changing and moving—not very rapidly, perhaps, but fast enough, in geologic time, to raise mountains and shift oceans. Solutions are moving around, dissolving something here and depositing it again somewhere else. Temperatures are changing as one place is denuded by erosion and another area buried under layers of sediment. Under such conditions, few systems remain closed. It is perhaps surprising that we find any closed systems at all. Let us look at a few that are known to be reliable. (They are listed in Table I on [page 4].)
Potash Feldspar
In the early 1950s, when the potassium-argon (parent-daughter) method was being developed by scientists at the University of Chicago, it was thought that the potash-bearing variety of the mineral feldspar would be an ideal closed system, because it was usually optically clear and free of flaws. This widely shared, logical, and perfectly scientific deduction soon turned out to be quite wrong. The scientific workers discovered that when feldspar and mica from the same rock (and thus of the same age) were analyzed side by side, the mica always came out older! Investigation showed that feldspar “leaked” argon (lost some of its radiogenic argon) even at room temperature, but the mica retained all or nearly all of the argon that had been generated in it.
Mica
With the development of the rubidium-strontium (parent-daughter) method by L. T. Aldrich and his co-workers at the Carnegie Institution of Washington, came the realization that mica was also very useful for this analysis, for it usually contains ample rubidium and not much original strontium that would mask the presence of the radiogenic strontium. As a result, mica, especially black mica (the mineral biotite), has enjoyed great popularity as a good and easy-to-find closed system.
A scientist making adjustments on an “argon train”, a maze of glass tubing in which argon is released from minerals and purified for analysis.
Everything has its limits, and mica is no exception: Even mica tends to leak argon at elevated, but still relatively low (geologically speaking), temperatures. These effects also depend on pressure and other factors, not all of which are well known; these elevated temperatures, pressures and other conditions of course act to some extent on all rocks buried in the earth’s crust. It is known that at only about 300°C at moderate pressures argon is leaked from mica faster than it is being generated in it by the decay of radioactive potassium. The temperature needed to cause the rapid loss of strontium from mica is not much higher. Mica, especially biotite, will recrystallize and lose all its radiogenic constituents (argon and strontium) at temperatures where many other minerals show little or no change.
That means that we cannot always rely on mica to give the date of the original crystallization of a rock—the time when it cooled from a molten state. Instead, mica will tell us when the rock last cooled from, say, several hundred degrees centigrade, regardless of what may have happened to the rock before that. The mica may have been reheated as a result of being buried under a few miles of sediment, for example. The mica will show when the rock last cooled—in other words, when it came up again.