The ocean; its size.Like the air, the ocean, which covers three-fourths of the earth's surface, when reduced to a proper standard of measure, loses very much of its imposing aspect. The varnish that covers a twelve-inch globe represents its relative dimension not inadequately.
Tides and currents.On the theory of gravitation, the tides of the ocean were explained as depending on the attractive force of the sun and moon. Its currents, in a general manner, are analogous to those of the air. They originate in the disturbing action of solar heat, the temperature of the sea varying from 85° in the torrid zone to the freezing-point as the poles are approached. Its specific gravity at the equator is estimated at 1·028; but this density necessarily varies with the rate at which superficial evaporation takes place; the pure vapour rising, leaves a more concentrated salt solution. The effect is therefore, in some degree, to counteract the expansion of the water by warmth, for the sun-rays, being able to penetrate several feet below the surface, correspondingly raise the temperature of that portion, which expands and becomes lighter; but, simultaneously, surface evaporation tends to make the water heavier. Notwithstanding this, currents are established through the preponderance of the dilatation, and of them the Gulf Stream is to us the most striking example.
Effects of ocean streams.The physical action of the sun-rays in occasioning currents operates through the expansion of water, of which warm portions ascend to the surface, colder portions from beneath setting in to supply their place. These currents, both hot and cold, are affected by the diurnal rotation of the earth, the action being essentially the same as that for the winds. They exert so great an influence as conveyers of heat that they disturb the ordinary climate relation depending on the sun's position. In this way the Gulf Stream, a river [372] of hot water in a sea of cold, as soon as it spreads out on the surface of the Atlantic in higher latitudes, liberates into the air the heat it has brought from the torrid zone; and this, being borne by the southwest wind, which blows in those localities for the greater part of the year, to the westerly part of the European continent, raises by many degrees the mean annual temperature, thus not only regulating the distribution of animals and plants, but also influencing human life and its pursuits, making places pleasant that would otherwise be inclement, and even facilitating the progress of civilization. Whatever, therefore, can affect the heat, the volume, the velocity, the direction of such a stream, at once produces important consequences in the organic world.
Physical and chemical relations of water.The Alexandrian school had attained correct ideas respecting the mechanical properties of water as the type of liquids. This knowledge was, however, altogether lost in Europe for many ages, and not regained until the time of Stevinus and Galileo, who recovered correct views of the nature of pressure, both vertical and oblique, and placed the sciences of hydrostatics and hydrodynamics on exact foundations. The Florentine academicians, from their experiments on water inclosed in a globe of gold, concluded that it is incompressible, an error subsequently corrected, and its compressibility measured. The different states in which it occurs, as ice, water, steam, were shown to depend altogether on the amount of latent heat it contains. Out of these investigations originated the invention of the steam-engine, of which it may be said that it has revolutionized the industry of the world. Soon after the explanation of the cause of its three states followed the great discovery that the opinion of past ages respecting its elementary nature is altogether erroneous. It is not a simple element, but is composed of two ingredients, oxygen and hydrogen, as was rigorously proved by decomposing and forming it. By degrees, more correct views of the nature of evaporation were introduced; gases and vapours were found to coexist in the same space, not because of their mutual solvent power, but because of their individual and independent elasticity. The instantaneous [373] formation of vapours in a vacuum showed that the determining condition is heat, the weight of vapour capable of existing in a given space being proportional to the temperature. More scientific views of the nature of maximum density were obtained, and on these principles was effected the essential improvement of the low pressure steam-engine—the apparent paradox of condensing the steam without cooling the cylinder.
In like manner much light was cast on the meteorological functions of water. It was seen that the diurnal vaporization from the earth depends on the amount of heat received, the vapour rising invisibly in the air till it reaches a region where the temperature is sufficiently low. There condensation into vesicles of perhaps 1/50000 of an inch in diameter ensues, and of myriads of such globules a cloud is composed. Clouds and their nomenclature. Of clouds, notwithstanding their many forms and aspects, a classification was given—cirrus, cumulus, stratus, etc. It was obvious why some dissolve away and disappear when they encounter warmer or drier spaces, and why others descend as rain. It was shown that the drops can not be pure, since they come in contact with dust, soluble gases, and organic matter in the air. The return of water to the sea. Sinking into the ground, the water issues forth as springs, contaminated with whatever is in the soil, and finds its way, through streamlets and rivers, back to the sea, and thus the drainage of countries is accomplished. Through such a returning path it comes to the receptacle from which it set out; the heat of the sun raised it from the ocean, the attraction of the earth returns it thereto; and, since the heat-supply is invariable from year to year, the quantity set in motion must be the same. Collateral results of no little importance attend these movements. Every drop of rain falling on the earth disintegrates and disturbs portions of the soil; every stream carries solid matter into the sea. It is the province of geology to estimate the enormous aggregate of detritus, continents washed away and new continents formed, and the face of the earth remodelled and renewed.
Progress of chemistry.The artificial decomposition of water constitutes an epoch in chemistry. The European form of this [374] science, in contradistinction to the Arabian, arose from the doctrine of acids and alkalies, and their neutralization. This was about A.D. 1614. It was perceived that the union of bodies is connected with the possession of opposite qualities, and hence was introduced the idea of an attraction of affinity. On this the discovery of elective attraction followed. Then came the recognition that this attraction is connected with opposite electrical states, chemistry and electricity approaching each other. A train of splendid discoveries followed; metals were obtained light enough to float on water, and even apparently to accomplish the proverbial impossibility of setting it on fire. In the end it was shown that the chemical force of electricity is directly proportional to its absolute quantity. Attraction. The elements. Better views of the nature of chemical attraction were attained, better views of the intrinsic nature of bodies. The old idea of four elements was discarded, as also the Saracenic doctrine of salt, sulphur, and mercury. The elements were multiplied until at length they numbered more than sixty. Theory of phlogiston. Alchemy merged into chemistry through the theory of phlogiston, which accounted for the change that metals undergo when exposed to the fire on the principle that something was driven off from them—a something that might be restored again by the action of combustible bodies. It is remarkable how adaptive this theory was. It was found to include the cases of combustive operations, the production of acids, the breathing of animals. It maintained its ground even long after the discovery of oxygen gas, of which one of the first names was dephlogisticated air.
But a false theory always contains within itself the germ of its own destruction. The weak point of this was, that when a metal is burnt the product ought to be lighter than the metal, whereas it proves heavier. Introduction of the balance into chemistry. At length it was detected that what the metal had gained the surrounding air had lost. This discovery implied that the balance had been resorted to for the determination of weights and for the decision of physical questions. The reintroduction of that instrument—for, as we have [375] seen, it had ages before been employed by the Saracen philosophers, who used several different forms of it—marked the epoch when chemistry ceased to be exclusively a science of quality and became one of quantity.
Theory of oxygen, and the nomenclature.On the ruins of the phlogistic theory arose the theory of oxygen, which was sustained with singular ability. Its progress was greatly facilitated by the promulgation of a new nomenclature in conformity to its principles, and of remarkable elegance and power. In the course of time it became necessary, however, to modify the theory, especially by deposing oxygen from the attitude of sovereignty to which it had been elevated, and assigning to it several colleagues, such as chlorine, iodine, etc. The introduction of the balance was also followed by important consequences in theoretical chemistry, among which pre-eminently was the establishment of the laws of combinations of bodies.
Present state of chemistry.Extensive and imposing as is the structure of chemistry, it is very far from its completion. It is so surrounded by the scaffolding its builders are using, it is so deformed with the materials of their work, that its true plan can not yet be made out. In this respect it is far more backward than astronomy. It has, however, disposed of the idea of the destruction and creation of matter. Indestructibility of matter. It accepts without hesitation the doctrine of the imperishability of substance; for, though the aspect of a thing may change through decompositions and recombinations, in which its constituent parts are concerned, every atom continues to exist, and may be recovered by suitable processes, though the entire thing may have seemingly disappeared. A particle of water raised from the sea may ascend invisibly through the air, it may float above us in the cloud, it may fall in the rain-drop, sink into the earth, gush forth again in the fountain, enter the rootlets of a plant, rise up with the sap to the leaves, be there decomposed by the sunlight into its constituent elements, its oxygen and hydrogen; of these and other elements, acids and oils, and various organic compounds may be made: in these or in its undecomposed state it may be received in the food of animals, circulate in their blood, be [376] essentially concerned in acts of intellection executed by the brain, it may be expired in the breath. Though shed in the tear in moments of despair, it may give birth to the rainbow, the emblem of hope. Whatever the course through which it has passed, whatever mutations it has undergone, whatever the force it has submitted to, its elementary constituents endure. Not only have they not been annihilated, they have not even been changed; and in a period of time, long or short, they find their way as water back again to the sea from which they came.
Electrical discoveries.Discoveries in electricity not only made a profound impression on chemistry, they have taken no insignificant share in modifying human opinion on other very interesting subjects. In all ages the lightning had been looked upon with superstitious dread. The thunderbolt had long been feigned to be the especial weapon of Divinity. A like superstitious sentiment had prevailed respecting the northern lights universally regarded in those countries in which they display themselves as glimpses of the movements of the angelic host, the banners and weapons of the armies of heaven. A great blow against superstition was struck when the physical nature of these phenomena was determined. As to the connexion of electrical science with the progress of civilization, what more needs to be said than to allude to the telegraph?