The Lavoisierian view of a salt, as a compound of a metallic oxide—or base—with a non-metallic oxide—or acid—seemed the only explanation which could be accepted by any reasonable chemist: in the early years of this century it reigned supreme.
But even during the lifetime of its founder this theory was opposed and opposed by the logic of facts. In 1787 Berthollet published an account of experiments on prussic acid,—the existence and preparation (from Prussian blue) of which acid had been demonstrated three or four years before by the Swedish chemist Scheele—which led him to conclude this compound to be a true acid, but free from oxygen. In 1796 the same chemist studied the composition and properties of sulphuretted hydrogen, and pronounced this body to be an acid containing no oxygen.
But the experiments and reasoning of Berthollet were hidden by the masses of facts and the cogency of argument of the Lavoisierian chemists.
The prevalent views regarding acids and bases were greatly strengthened by the earlier researches of Sir Humphry Davy, in which he employed the voltaic battery as an instrument in chemical investigation. Let us now consider some of the electro-chemical work of this brilliant chemist.
In the spring of the year 1800 the electrical battery, which had recently been discovered by Volta, was applied by Nicholson and Carlisle to effect the decomposition of water. The experiments of these naturalists were repeated and confirmed by Davy, then resident at Bristol, who followed up this application of electricity to effect chemical changes by a series of experiments extending from 1800 to 1806, and culminating in the Bakerian Lecture delivered before the Royal Society in the latter year.
The history of Davy's life during these years, years rich in results of the utmost importance to chemical science, will be traced in the sequel; meanwhile we are concerned only with the results of his chemical work.
The first Bakerian Lecture of Humphry Davy, "On some Chemical Agencies of Electricity," deserves the careful study of all who are interested in the methods of natural science; it is a brilliant example of the disentanglement of a complex natural problem.
Volta and others had subjected water to the action of a current of electricity, and had noticed the appearance of acid and alkali at the oppositely electrified metallic surfaces. According to some experimenters, the acid was nitrous, according to others, muriatic acid. One chemist asserted the production of a new and peculiar body which he called the electric acid. The alkali was generally said to be ammonia.
When Davy passed an electric current through distilled water contained in glass vessels, connected by pieces of moist bladder, cotton fibre, or other vegetable matters, he found that nitric and hydrochloric acids were formed in the water surrounding the positively electrified plate or pole, and soda around the negatively electrified pole, of the battery.
When the same piece of cotton fibre was repeatedly used for making connection between the glass vessels, and was washed each time in dilute nitric acid, Davy found that the production of muriatic acid gradually ceased; hence he traced the formation of this acid to the presence of the animal or vegetable substance used in the experiments.