The action of the solutions in water of metallic salts is, if the mixture is sufficiently strong, to coagulate the albumen in the sap; but the fibre is left unprotected.
Creosote has the same effect of coagulating the albumen, whilst it fills the pores of the wood with a bituminous asphaltic substance, which gives a waterproof covering to the fibre, prevents the absorption of water, and is obnoxious to animal life.
In cases where the complete preservation of timber is of vital importance, and expense not a consideration, the wood should be first subjected to Burnett’s process, and then creosoted; by which means it would be nearly indestructible; the reason for this combined process being, that the albumen or sap absorbs the creosote more readily than the heart of the timber, which can, however, be penetrated by the solution of chloride of zinc. Mr. John Bethell’s patent of 1853 recommends this in a rather improved form. He says the timber should first be injected with metallic salts, then dried in a drying-house, then creosoted. By this method, very considerable quantities both of metallic salt and creosote can be injected into timber.
It has been stated that the elasticity of wood is increased by creosoting; the heart-wood only decays by oxidation.
The wood should be dried previous to undergoing the process, as the sapwood, otherwise almost useless, can be rendered serviceable, and for piles for marine work whole round timber should be used, because the sapwood is so much more readily saturated with the oil, and this prevents the worms from making an inroad into the heart.
Mr. Bethell uses about 10 lb. of creosote per cubic foot of wood, and he does not allow a piece of timber to be sent from his works without being tested to ascertain if it has absorbed that amount, or an amount previously agreed upon. We mention the latter statement, because it is evident that all descriptions of wood cannot be made to imbibe the same amount. This process is chiefly used for pine timber: yellow pine should absorb about 11 lb. to the cubic foot, and Riga pine about 9 lb. The quantity of oil recommended by the patentee, engineers, and others, is from 8 to 10 lb. for land purposes, and about 12 lb. to the cubic foot for marine. In this country, for marine the quantity does not exceed 12 lb.; but on the Continent, in France, Belgium, and Holland, the quantity used is from 14 to 22 lb. (!) per cubic foot. The specifications frequently issued by engineers for sleepers for foreign railways describe them to be entirely of heart-wood, and then to be creosoted to the extent of 10 lb. of the oil per cubic foot: this it is impossible to do, the value of the process being in the retention of the sapwood.
It being ascertained a few years since that the centres of some sleepers were not impregnated with the fluid, after the sleeper had been creosoted to the extent of 10 lb. of creosote per cubic foot, Sir Macdonald Stephenson suggested, as a means of obviating that defect, the boring of two holes, 1 inch in diameter, through each sleeper longitudinally, and impregnating up to 12 lb. or 14 lb. per cubic foot. By that means the creosote would be sent all through the sleeper. The boring by hand would be an expensive process, but by machinery it might be effected at a comparatively small increased cost.
During the last twenty-five years an enormous quantity of creosoted railway sleepers have been sent to India and other hot climates. The native woods are generally too hard for penetration. On the great Indian Peninsula Railway the native woods were so hard and close-grained that they could not be impregnated with any preservative substance, sál wood being principally used, into which creosote would not penetrate more than one quarter of an inch. As regards creosoting wood in India, it is moreover a costly process, owing to the difficulty and expense of conveying creosote from England; iron tanks are necessary to hold the oil when on board ship, and, being unsaleable in India, add to the expense.