In treating of the epigene action of water in geological processes it will be convenient to deal first with its operations in traversing the land, and then with those which it performs in the sea. The circulation of water from land to sea and again from sea to land constitutes the fundamental cause of most of the daily changes by which the surface of the land is affected.
1. Rain.—Rain effects two kinds of changes upon the surface of the land. It acts chemically upon soils and stones, and sinking under ground continues a great series of similar reactions there. It acts mechanically, by washing away loose materials, and thus powerfully affecting the contours of the land. Its chemical action depends mainly upon the nature and proportion of the substances which, in descending to the earth, it abstracts from the atmosphere. Rain always absorbs a little air, which, in addition to its nitrogen and oxygen, contains carbonic acid, and in minute proportions, sodium chloride, sulphuric acid and other ingredients, especially inorganic dust, organic particles and living germs. Probably the most generally efficient of these constituents are oxygen, carbonic acid and organic matter. Armed with these reagents, rain effects a chemical decomposition of the rocks on which it falls, and through which it sinks underground. The principal changes thus produced are as follows: (a) Oxidation.—Owing to the prominence of oxygen in rain-water, and its readiness to unite with any substance which can contain more of it, a thin oxidized pellicle is formed on the surface of many rocks on which rain falls, and this oxidized layer if not at once washed off, sinks deeper until a crust is formed over the stone. A familiar illustration of this action is afforded by the rust, or oxide, which forms on iron when exposed to moisture, though this iron may be kept long bright if allowed to remain screened from moist air and rain. (b) Deoxidation.—Organic matter having an affinity for more oxygen decomposes peroxides by depriving them of some part of their share of that element and reducing them to protoxides. These changes are especially noticeable among the iron oxides so abundantly diffused among rocks. Hence rain-water, in sinking through soil and obtaining such organic matter, becomes thereby a reducing agent. (c) Solution.—This may take place either by the simple action of the water, as in the solution of rock-salt, or by the influence of the carbonic acid present in the rain. (d) Formation of Carbonates.—A familiar example of the action of carbonic acid in rain is to be seen in the corrosion of exposed marble slabs. The carbonic acid dissolves some of the lime, which, as a bicarbonate, is held in solution in the carbonated water, but is deposited again when the water loses its carbonic acid or evaporates. It is not merely carbonates, however, which are liable to this kind of destruction. Even silicates of lime, potash and soda, combinations existing abundantly as constituents of rocks, are attacked; their silica is liberated, and their alkalis or alkaline earths, becoming carbonates, are removed in solution. (e) Hydration.—Some minerals, containing little or no water, and therefore called anhydrous, when exposed to the action of the atmosphere, absorb water, or become hydrous, and are then usually more prone to further change. Hence the rocks of which they form part become disintegrated.
Besides the reactions here enumerated, a considerable amount of decay may be observed as the result of the presence of sulphuric and nitric acid in the air, especially in that of large towns and manufacturing districts, where much coal is consumed. Metallic surfaces, as well as various kinds of stone, are there corroded, while the mortar of walls may often be observed to be slowly swelling out and dropping off, owing to the conversion of the lime into sulphate. Great injury is likewise done from a similar cause to marble monuments in exposed graveyards.
The general result of the disintegrating action of the air and of rain, including also that of plants and animals, to be noticed in the sequel, is denoted by the term “weathering.” The amount of decay depends partly on conditions of climate, especially the range of temperature, the abundance of moisture, height above the sea and exposure to prevalent winds. Many rocks liable to be saturated with rain and rapidly dried under a warm sun are apt to disintegrate at the surface with comparative rapidity. The nature and progress of the weathering are mainly governed by the composition and texture of the rocks exposed to it. Rocks composed of particles liable to little chemical change from the influence of moisture are best fitted to resist weathering, provided they possess sufficient cohesion to withstand the mechanical processes of disintegration. Siliceous sandstones are excellent examples of this permanence. Consisting wholly or mainly of the durable mineral quartz, they are sometimes able so to withstand decay that buildings made of them still retain, after the lapse of centuries, the chisel-marks of the builders. Some rocks, which yield with comparative rapidity to the chemical attacks of moisture, may show little or no mark of disintegration on their surface. This is particularly the case with certain calcareous rocks. Limestone when pure is wholly soluble in acidulated water. Rain falling on such a rock removes some of it in solution, and will continue to do so until the whole is dissolved away. But where a limestone is full of impurities, a weathered crust of more or less insoluble particles remains after the solution of the calcareous part of the stone. Hence the relative purity of limestones may be roughly determined by examining their weathered surfaces, where, if they contain much sand, the grains will be seen projecting from the calcareous matrix, and where, should the rock be very ferruginous, the yellow hydrous peroxide, or ochre, will be found as a powdery crust. In limestones containing abundant encrinites, shells, or other organic remains, the weathered surface commonly presents the fossils standing out in relief. The crystalline arrangement of the lime in the organic structures enables them to resist disintegration better than the general mechanically aggregated matrix of the rock. An experienced fossil collector will always search well such weathered surfaces, for he often finds there, delicately picked out by the weather, minute and frail fossils which are wholly invisible on a freshly broken surface of the stone. Many rocks weather with a thick crust, or even decay inwards for many feet or yards. Basalt, for example, often shows a yellowish-brown ferruginous layer on its surface, formed by the conversion of its felspar into kaolin, and the removal of its calcium silicate as carbonate, by the hydration of its olivine and augite and their conversion into serpentine, or some other hydrous magnesian silicate, and by the conversion of its magnetite into limonite. Granite sometimes shows in a most remarkable way the distance to which weathering can reach. It may occasionally be dug into for a depth of 20 or 30 ft., the quartz crystals and veins retaining their original positions, while the felspar is completely kaolinized. It is to the endlessly varied effects of weathering that the abundant fantastic shapes assumed by crags and other rocky masses are due. Most varieties of rock have their own characteristic modes of weathering, whereby they may be recognized even from a distance. To some of these features reference will be made in Part VIII.
The mechanical action of rain, which is intimately bound up with its chemical action, consists in washing off the fine superficial particles of rocks which have been corroded and loosened by the process of weathering, and in thus laying open fresh portions to the same influences of decay. The detritus so removed is partly carried down into the soil which is thereby enriched, partly held in suspension in the little runnels into which the rain-drops gather as they begin to flow over the land, partly pushed downwards along the surface of sloping ground. A good deal of it finds its way into the nearest brooks and rivers, which are consequently made muddy by heavy rain.
It is natural that a casual consideration of the subject should lead to an impression that, though the general result of the fall of rain upon a land-surface must lead to some amount of disintegration and lowering of that surface, the process must be so slow and slight as hardly to be considered of much importance among geological operations. But further attention will show such an impression to be singularly erroneous. It loses sight of the fact that a change which may be hardly appreciable within a human lifetime, or even within the comparatively brief span of geological time embraced in the compass of human history, may nevertheless become gigantic in its results in the course of immensely protracted periods. An instructive lesson in the erosive action of rain may be found in the pitted and channelled surface of ground lying under the drip of the eaves of a cottage. The fragments of stone and pebbles of gravel that form part of the soil can there be seen sticking out of the ground, because being hard they resist the impetus of the falling drops, protecting for a time the earth beneath them, while that which surrounded and covered them is washed away. From this familiar illustration the observer may advance through every stage in the disappearance of material which once covered the surface, until he comes to examples where once continuous and thick sheets of solid rock have been reduced to a few fragments or have been entirely removed. Since the whole land surface over which rain falls is exposed to this waste, the superficial covering of decayed rock or soil, as Hutton insisted, is constantly, though imperceptibly, travelling outward and downward to the sea. In this process of transport rain is an important carrying agent, while at the same time it serves to connect the work of the other disintegrating forces, and to make it conducive to the general degradation of the land. Though this decay is general and constant, it is obviously not uniform. In some places where, from the nature of the rock, from the flatness of the ground, or from other causes, rain works under great difficulties, the rate of waste may be extremely slow. In other places it may be rapid enough to be appreciable from year to year. A survey of this department of geological activity shows how unequal wasting by rain, combined with the operations of brooks and rivers, has produced the details of the present relief of the land, those tracts where the destruction has been greatest forming hollows and valleys, others, where it has been less, rising into ridges and hills (Part VIII.).
Rain-action is not merely destructive, but is accompanied with reproductive effects, chief of which is the formation of soil. In favourable situations it has gathered together accumulations of loam and earth from neighbouring higher ground, such as the “brick-earth,” “head,” and “rain-wash” of the south of England—earthy deposits, sometimes full of angular stones, derived from the subaerial waste of the rocks of the neighbourhood.
2. Underground Water.—Of the rain which falls upon the land one portion flows off into brooks and rivers by which the water is conducted back to the ocean; the larger part, however, sinks into the ground and disappears. It is this latter part which has now to be considered. Over and above the proportion of the rainfall which is absorbed by living vegetation and by the soil, there is a continual filtering down of the water from the surface into the rocks that lie below, where it partly lodges in pores and interstices, and partly finds its way into subterranean joints and fissures, in which it performs an underground circulation, and ultimately issues once more at the surface in the form of springs (q.v.). In the course of this circulation the water performs an important geological task. Not only carrying down with it the substances which the rain has abstracted from the air, but obtaining more acids and organic matter from the soil, it is enabled to effect chemical changes in the rocks underneath, and especially to dissolve limestone and other calcareous formations. So considerable is the extent of this solution in some places that the springs which come to the surface, and begin there to evaporate and lose some of their carbonic acid, contain more dissolved lime than they can hold. They consequently deposit it in the form of calcareous tuff or sinter (q.v.). Other subterranean waters issue with a large proportion of iron-salts in solution which form deposits of ochre. The various mineral springs so largely made use of for the mitigation or cure of diseases owe their properties to the various salts which they have dissolved out of rocks underground. As the result of prolonged subterranean solution in limestone districts, passages and caves (q.v.), sometimes of great width and length, are formed. When these lie near the surface their roofs sometimes fall in and engulf brooks and rivers, which then flow for some way underground until the tunnels conduct them back again to daylight on some lower ground.
Besides its chemical activity water exerts among subterranean rocks a mechanical influence which leads to important changes in the topography of the surface. In removing the mineral matter, either in solution or as fine sediment, it sometimes loosens the support of overlying masses of rock which may ultimately give way on sloping ground, and rush down the declivities in the form of landslips. These destructive effects are specially frequent on the sides of valleys in mountainous countries and on lines of sea-cliff.
3. Brooks and Rivers.—As geological agents the running waters on the face of the land play an important part in epigene changes. Like rain and springs they have both a chemical and a mechanical action. The latter receives most attention, as it undoubtedly is the more important; but the former ought not to be omitted in any survey of the general waste of the earth’s surface. The water of rivers must possess the powers of a chemical solvent like rain and springs, though its actual work in this respect can be less easily measured, seeing that river water is directly derived from rain and springs, and necessarily contains in solution mineral substances supplied to it by them and not by its own operation. Nevertheless, it is sometimes easy to prove that streams dissolve chemically the rocks of their channels. Thus, in limestone districts the base of the cliffs of river ravines may be found eaten away into tunnels, arches, and overhanging projections, presenting in their smooth surfaces a great contrast to the angular jointed faces of the same rock, where now exposed to the influence only of the weather on the higher parts of the cliff.